摘要:
Rhenium-free nickel based alloys are provided. More particularly, the alloys comprise preferred levels and ratios of elements so as to achieve good high temperature strength of both gamma matrix phase and gamma prime precipitates, as well as good environmental resistance, without using rhenium. When cast and directionally solidified into single crystal form, the alloys exhibit creep resistance substantially equivalent to rhenium-bearing single-crystal alloys. Further, the alloys can be processed by directional solidification into articles in single crystal form or columnar structure comprising fine dendrite arm spacing, e.g., less than 400 μm, if need be, so that further improvements in mechanical properties in the articles can be seen.
摘要:
Rhenium-free nickel based alloys are provided. More particularly, the alloys comprise preferred levels and ratios of elements so as to achieve good high temperature strength of both gamma matrix phase and gamma prime precipitates, as well as good environmental resistance, without using rhenium. When cast and directionally solidified into single crystal form, the alloys exhibit oxidation resistance better than or comparable to rhenium-bearing single-crystal alloys, and creep rupture life comparable to rhenium-bearing single-crystal alloys. Further, the alloys can be processed by directional solidification into articles in single crystal form or columnar structure comprising fine dendrite arm spacing, e.g., less than 400 μm, if need be, so that further improvements in mechanical properties in the articles can be seen.
摘要:
A method of making nano/sub-micron sized grains in a work piece material having a lateral side has the steps of providing a die. The die has an entrance channel with a longitudinal axis and an exit channel. The entrance channel and the exit channel are connected to one another to form an angle. The method has the step of providing a first sacrificial material with a complementary size to the work piece and placing the sacrificial first material and the work piece in an entrance channel. The first sacrificial material and the work piece are aligned with the longitudinal axis. The method has the step of extruding the combination of the first sacrificial material, and the work piece through the intersection of the entrance and the exit channels. The resulting shear deformation forms the nano/sub-micron sized grains in the work piece. This configuration reduces frictional effects thereby producing homogenous nano grain structure. This configuration reduces applied load and enables equal channel angular extrusion of thin sheets.
摘要:
A method and apparatus for casting a near-net-shape article from a high temperature material, such as a refractory metal intermetallic composite material. The apparatus includes: a means for forming a molten material comprising at least one of a metal and an alloy; a means for pouring the molten material; a mold assembly comprising a solid shell having a face coat interposed between the solid shell and molten material; and a heater assembly for maintaining the solid shell at a temperature. The molten material solidifies within the solid shell to form a near-net shape of the article. The near-net shape article may be a turbine assembly component, such as, but not limited to, a vane or airfoil.
摘要:
Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases maybe: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.
摘要翻译:适用于暴露于高温和氧化环境的Nb基基底上的保护性氧化物形成涂层的涂料。 涂层含有铬和/或钼,优选含有硅,并且任选地包含铌,钛,铪,铁,铼,钽和/或钨,其组合形成多个金属间相,其组合形成一个或多个金属间相 促进形成缓慢生长的氧化皮。 根据具体的涂层组成,金属间化合物相可以是硅改性的Cr 2 Nb Laves相和任选的铬固溶体相,CrNbSi金属间相和/或M3Si金属间相,其中M是铌,钛和/或铬 ; 或M5Si3,MSi2和/或M3Si2,其中M是钼,铌,钛,铬,铪,铁,铼,钽和/或钨。
摘要:
Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases may be: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.
摘要翻译:适用于暴露于高温和氧化环境的Nb基基底上的保护性氧化物形成涂层的涂料。 涂层含有铬和/或钼,优选含有硅,并且任选地包含铌,钛,铪,铁,铼,钽和/或钨,其组合形成多个金属间相,其组合形成一个或多个金属间相 促进形成缓慢生长的氧化皮。 根据特定的涂料组合物,金属间相可以是:硅改性的Cr 2 Nb Laves相和任选的铬固溶相,CrNbSi金属间相和/或M3Si金属间相,其中M是铌,钛和/或 铬; 或M5Si3,MSi2和/或M3Si2,其中M是钼,铌,钛,铬,铪,铁,铼,钽和/或钨。
摘要:
Articles suitable for use in high temperature applications, such as turbomachinery components, and methods for making such articles, are provided. One embodiment is an article. The article comprises a material comprising a plurality of L12-structured gamma-prime phase precipitates distributed within a matrix phase at a concentration of at least 20% by volume, wherein the gamma-prime phase precipitates are less than 1 micrometer in size, and a plurality of A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The solvus temperature of the eta phase is higher than the solvus temperature of the gamma-prime phase. Moreover, the material has a median grain size less than 10 micrometers. The method comprises providing a workpiece, the workpiece comprising at least about 40% nickel, from about 1.5% to about 8% titanium, and from about 1.5% to about 4.5% aluminum. A weight ratio of titanium to aluminum is in the range from about 1 to about 4, and the workpiece further comprises a plurality of A3-structured ordered eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The method further comprises mechanically working the workpiece at a temperature below a solvus temperature of the eta phase; and heat treating the workpiece at a temperature sufficiently high to dissolve any gamma prime phase present in the workpiece but below the solvus temperature of the eta phase.
摘要:
A system, in certain embodiments, includes a backing plate, a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface, and the tungsten-based member comprises curved grooves configured to secure the tungsten-based member to the backing plate. The system also includes a drive. The system includes a pin tool movable by the drive to create friction along one or more workpieces disposed on the welding work surface, wherein the frictional heating and mechanical stirring is configured to create a stir weld along the one or more workpieces. The system, in some embodiments, also may include a backing plate comprising liquid passages and gas passages and a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface.
摘要:
A system, in certain embodiments, includes a backing plate, a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface, and the tungsten-based member comprises curved grooves configured to secure the tungsten-based member to the backing plate. The system also includes a drive. The system includes a pin tool movable by the drive to create friction along one or more workpieces disposed on the welding work surface, wherein the frictional heating and mechanical stirring is configured to create a stir weld along the one or more workpieces. The system, in some embodiments, also may include a backing plate comprising liquid passages and gas passages and a tungsten-based member disposed along the backing plate, wherein the tungsten-based member defines a welding work surface.
摘要:
An article is presented where the article comprises an alloy having a minor phase dispersed within a matrix phase and a plurality of substantially equiaxed grains. The article further comprises a continuous gradient in grain size from a first grain size at an outer surface of the article to a second grain size at an inner portion of the article, wherein the first grain size is less than the second grain size. Methods for forming the article using high deformation processing are also presented, where the processing includes extruding the feedstock material through a die having a twist channel configured to apply a torsional strain to the feedstock material as it passes through the die to form an extruded billet.