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公开(公告)号：US08410437B2
公开(公告)日：2013-04-02
申请号：US12744379
申请日：2008-11-24
IPC分类号： H01J49/40
CPC分类号： H01J49/065 , H01J49/0072
摘要： An ion-ion reaction cell is provided comprising a plurality of electrodes (1) forming an ion guide (2). One or more transient DC voltage waves (8, 9) are applied to the electrodes (2). Reagent anions and analyte cations are arranged to undergo ion-ion reactions within the reaction cell and the resulting fragment ions which are formed within the reaction cell are then subsequently translated out of the reaction cell by means of one or more transient DC voltage waves (8, 9).
摘要翻译： 提供离子离子反应池，其包括形成离子导向器（2）的多个电极（1）。 一个或多个瞬态DC电压波（8,9）被施加到电极（2）。 试剂阴离子和分析物阳离子排列成在反应池内进行离子 - 离子反应，然后在反应池内形成的所得碎片离子随后通过一个或多个瞬态直流电压波（8 ，9）。
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公开(公告)号：US20100301206A1
公开(公告)日：2010-12-02
申请号：US12744379
申请日：2008-11-24
IPC分类号： H01J49/00
CPC分类号： H01J49/065 , H01J49/0072
摘要： An ion-ion reaction cell is provided comprising a plurality of electrodes (1) forming an ion guide (2). One or more transient DC voltage waves (8, 9) are applied to the electrodes (2). Reagent anions and analyte cations are arranged to undergo ion-ion reactions within the reaction cell and the resulting fragment ions which are formed within the reaction cell are then subsequently translated out of the reaction cell by means of one or more transient DC voltage waves (8, 9).
摘要翻译： 提供离子离子反应池，其包括形成离子导向器（2）的多个电极（1）。 一个或多个瞬态DC电压波（8,9）被施加到电极（2）。 试剂阴离子和分析物阳离子排列成在反应池内进行离子 - 离子反应，然后在反应池内形成的所得碎片离子随后通过一个或多个瞬态直流电压波（8 ，9）。
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公开(公告)号：US08859955B2
公开(公告)日：2014-10-14
申请号：US14113160
申请日：2012-04-20
申请人： Martin Raymond Green
发明人： Martin Raymond Green
CPC分类号： H01J49/0031 , H01J49/0036 , H01J49/401
摘要： A method of analyzing a sample is disclosed comprising transmitting a first population of ions through a mass spectrometer and switching a state or mode of the mass spectrometer to produce a second population of ions. A sequential stream of mass spectra is acquired asynchronously with respect to switching the state or mode of the mass spectrometer. The stream of mass spectral data is then post-processed to produce mass spectra corresponding predominantly to the first and second population of ions.
摘要翻译： 公开了分析样品的方法，其包括通过质谱仪传输第一离子群并切换质谱仪的状态或模式以产生第二离子群。 相对于质谱仪的状态或模式的切换，异步获取连续的质谱流。 然后对质谱数据流进行后处理，以产生主要对应于第一和第二离子群的质谱。
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公开(公告)号：US20140197308A1
公开(公告)日：2014-07-17
申请号：US14113160
申请日：2012-04-20
申请人： Martin Raymond Green
发明人： Martin Raymond Green
CPC分类号： H01J49/0031 , H01J49/0036 , H01J49/401
摘要： A method of analysing a sample is disclosed comprising transmitting a first population of ions through a mass spectrometer and switching a state or mode of the mass spectrometer to produce a second population of ions. A sequential stream of mass spectra is acquired asynchronously with respect to switching the state or mode of the mass spectrometer. The stream of mass spectral data is then post-processed to produce mass spectra corresponding predominantly to the first and second population of ions.
摘要翻译： 公开了分析样品的方法，其包括通过质谱仪传输第一离子群并切换质谱仪的状态或模式以产生第二离子群。 相对于质谱仪的状态或模式的切换，异步获取连续的质谱流。 然后对质谱数据流进行后处理，以产生主要对应于第一和第二离子群的质谱。
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公开(公告)号：US08658971B2
公开(公告)日：2014-02-25
申请号：US13375056
申请日：2010-05-28
IPC分类号： H01J49/40
CPC分类号： H01J49/0036 , G06K9/0053 , H01J49/40
摘要： A method of processing mass spectral data is disclosed comprising digitising a first signal output from an ion detector to produce a first digitised signal. A first set of peaks in the first digitised signal is detected and the arrival time To and peak area So of one or more peaks in the first set of peaks are determined thereby forming a first list of data pairs, each data pair comprising an arrival time value and a peak area value. One or more data pairs from the first list are then filtered out thereby forming a second reduced list, wherein a data pair is filtered out, attenuated or otherwise rejected from the first list if the peak area value of a data pair in the first list is determined to be less than a threshold peak area.
摘要翻译： 公开了一种处理质谱数据的方法，包括数字化从离子检测器输出的第一信号以产生第一数字化信号。 检测第一数字化信号中的第一组峰值，并确定第一组峰值中的一个或多个峰值的到达时间To和峰值面积So，从而形成第一数据对列表，每个数据对包括到达时间 值和峰面积值。 然后将来自第一列表的一个或多个数据对过滤掉，从而形成第二缩减列表，其中如果第一列表中的数据对的峰值面积值是第一列表中的峰值面积值，则数据对被滤除，衰减或以其他方式从第一列表中被拒绝 确定为小于阈值峰面积。
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公开(公告)号：US08283626B2
公开(公告)日：2012-10-09
申请号：US12937806
申请日：2009-04-03
IPC分类号： H01J49/26
CPC分类号： H01J49/28 , H01J49/0072 , H01J49/065
摘要： A mass spectrometer is disclosed comprising an Electron Transfer Dissociation device comprising an ion guide. A control system determines the degree of fragmentation and charge reduction of precursor ions within the ion guide and varies the speed at which ions are transmitted through the ion guide in order to optimise the fragmentation and charge reduction process.
摘要翻译： 公开了一种质谱仪，其包括电子转移离解装置，其包括离子导向器。 控制系统确定离子导向器内的前体离子的碎裂和电荷减少的程度，并且改变离子通过离子导向器传输的速度，以便优化碎裂和电荷还原过程。
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公开(公告)号：US08362424B2
公开(公告)日：2013-01-29
申请号：US12744384
申请日：2008-11-24
IPC分类号： H01J49/40
CPC分类号： H01J49/065 , H01J49/0072
摘要： An ion-ion reaction cell is provided comprising a plurality of electrodes forming an ion guide. A transient DC voltage wave is applied to the electrodes in order to load reagent anions into the ion guide. Analyte cations are then subsequently transmitted through the ion-ion reaction cell by a subsequent transient DC voltage wave. Ion are arranged to undergo ion-ion reactions within the reaction cell and the resulting fragment ions which are formed within the reaction cell are then subsequently translated out of the reaction cell by means of a transient DC voltage wave.
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公开(公告)号：US20110062323A1
公开(公告)日：2011-03-17
申请号：US12937806
申请日：2009-04-03
CPC分类号： H01J49/28 , H01J49/0072 , H01J49/065
摘要： A mass spectrometer is disclosed comprising an Electron Transfer Dissociation device comprising an ion guide. A control system determines the degree of fragmentation and charge reduction of precursor ions within the ion guide and varies the speed at which ions are transmitted through the ion guide in order to optimise the fragmentation and charge reduction process.
摘要翻译： 公开了一种质谱仪，其包括电子转移离解装置，其包括离子导向器。 控制系统确定离子导向器内的前体离子的碎裂和电荷减少的程度，并且改变离子通过离子导向器传输的速度，以便优化碎裂和电荷还原过程。
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公开(公告)号：US20110024618A1
公开(公告)日：2011-02-03
申请号：US12744384
申请日：2008-11-24
CPC分类号： H01J49/065 , H01J49/0072
摘要： An ion-ion reaction cell is provided comprising a plurality of electrodes (1) forming an ion guide (2). A transient DC voltage wave is applied to the electrodes (2) in order to load reagent anions into the ion guide (2). Analyte cations are then subsequently transmitted through the ion-ion reaction cell by a subsequent transient DC voltage wave. Ion are arranged to undergo ion-ion reactions within the reaction cell and the resulting fragment ions which are formed within the reaction cell are then subsequently translated out of the reaction cell by means of a transient DC voltage wave.
摘要翻译： 提供离子离子反应池，其包括形成离子导向器（2）的多个电极（1）。 向电极（2）施加瞬态直流电压波，以便将试剂阴离子负载到离子导向器（2）中。 分析物阳离子然后随后通过离子离子反应池通过随后的瞬态DC电压波传输。 离子被布置为在反应池内进行离子 - 离子反应，然后在反应池内形成的所得碎片离子随后通过瞬态DC电压波转移出反应池。
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公开(公告)号：US08975578B2
公开(公告)日：2015-03-10
申请号：US13881840
申请日：2011-10-26
CPC分类号： H01J49/04 , G01N27/622 , H01J49/0031 , H01J49/36 , H01J49/422
摘要： A linear ion trap is disclosed wherein an asymmetric voltage waveform is applied to electrodes forming the ion trap which causes ions to become radially separated according to their differential ion mobility. An axial potential barrier is arranged at the exit of the ion trap such that ions having a first differential ion mobility and a first radial displacement are retained axially within the ion trap but ions having a second differential ion mobility and a second radial displacement are ejected axially from the ion trap.
摘要翻译： 公开了一种线性离子阱，其中对形成离子阱的电极施加不对称电压波形，这导致离子根据其离子迁移率的差异而径向分离。 轴向势垒布置在离子阱的出口处，使得具有第一差分离子迁移率和第一径向位移的离子轴向保留在离子阱内，但具有第二差分离子迁移率和第二径向位移的离子被轴向地排出 离子阱。
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