Metastable hydrogen storage alloy material
    31.
    发明授权
    Metastable hydrogen storage alloy material 失效
    亚稳储氢合金材料

    公开(公告)号:US5135589A

    公开(公告)日:1992-08-04

    申请号:US509524

    申请日:1990-04-16

    IPC分类号: C01B3/00 C22C30/00

    摘要: Disclosed is an improved metastable, multi-component, multi-phase hydrogen storage alloy material formed by rapid solidifcation from a melt. The improved metastable hydrogen storage alloy is characterized by a refined grain size of Approximately 1 micron or less, and the reduction, or elimination of deleterious phases.The microstructure of the alloy is relatively disordered, and each phase of the material comprises less than 50 atomic percent vanadium and chromium combined. The nominal composition is:V.sub.y'-y Ni.sub.y Ti.sub.x'-x Zr.sub.x Cr.sub.xwherein x' is between 1.8 and 2.2; x is between 0 and 1.5; y' is between 3.6 and 4.4; y is between 0.6 and 3.5; and z is between 0 and 1.44.

    摘要翻译: 公开了一种通过从熔体快速固化形成的改进的亚稳态多组分多相储氢合金材料。 改进的亚稳态储氢合金的特征在于精细晶粒尺寸约为1微米或更小,以及有害相的还原或消除。 合金的微结构相对无序,材料的每一相都含有小于50原子%的钒和铬。 标称组成为:Vy'-yNiyTix'-xZrxCrx其中x'在1.8和2.2之间; x在0和1.5之间; y'在3.6和4.4之间; y在0.6和3.5之间; z在0和1.44之间。

    Hydrogen storage materials and methods of sizing and preparing the same
for electrochemical applications
    32.
    发明授权
    Hydrogen storage materials and methods of sizing and preparing the same for electrochemical applications 失效
    储氢材料及其电化学应用的尺寸和制备方法

    公开(公告)号:US4551400A

    公开(公告)日:1985-11-05

    申请号:US601641

    申请日:1984-04-17

    摘要: The present invention provides novel active materials which reversibly store hydrogen under conditions which make them exceptionally well-suited for elecrochemical applications. These active materials have both novel compositions and structures. A first group of active material compositions incorporate the elements of titanium, vanadium, and nickel. A second group adds zirconium to the first group of active materials. A preferred third composition group adds chromium to the first group of active materials. These materials may be single or multiphase combinations of amorphous, microcrystalline, or polycrystalline structures. Preferably, these materials have a multiphase polycrystalline structure. Methods of reducing the size or of sizing these materials, as well as other hydride-forming alloys, also are provided. Methods of preparing the inventive hydrogen storage materials and fabricating electrodes from these active materials are contemplated. Electrochemical cells and batteries assembled with the inventive electrodes provide significantly improved capacity and cycle life.

    摘要翻译: 本发明提供了在使得它们非常适合于电化学应用的条件下可逆地储存氢气的新型活性物质。 这些活性物质具有新的组成和结构。 第一组活性材料组合物包含钛,钒和镍的元素。 第二组将锆添加到第一组活性材料中。 优选的第三组合物组将铬添加到第一组活性材料中。 这些材料可以是非晶,微晶或多晶结构的单相或多相组合。 优选地,这些材料具有多相多晶结构。 还提供了减小尺寸或调整这些材料的方法,以及其它氢化物形成合金。 预期制备本发明的储氢材料并从这些活性材料制造电极的方法。 与本发明电极组装的电化学电池和电池提供显着改善的容量和循环寿命。

    Low cost, high power, high energy density, solid-state, bipolar metal hydride batteries
    33.
    发明授权
    Low cost, high power, high energy density, solid-state, bipolar metal hydride batteries 有权
    低成本,高功率,高能量密度,固态,双极金属氢化物电池

    公开(公告)号:US08974948B2

    公开(公告)日:2015-03-10

    申请号:US12930686

    申请日:2011-01-13

    IPC分类号: H01M10/0562 H01M10/34

    摘要: A solid state battery including at least one multilayered battery cell comprising: 1) a layer of negative electrode material; 2) a layer of positive electrode material; and 3) a layer of perovskite-type oxide material disposed between the layer of positive electrode material and the layer of negative electrode material, where said layer of perovskite-type oxide material is electrically insulating and capable of readily conducting or transporting protons.

    摘要翻译: 一种固态电池,包括至少一个多层电池单元,包括:1)负极材料层; 2)一层正极材料; 以及3)设置在所述正极材料层和所述负极材料层之间的钙钛矿型氧化物层,其中所述钙钛矿型氧化物层是电绝缘的并且能够容易地导电或输送质子。

    NdNi5 alloys for hydrogen storage and Ni-MH batteries
    34.
    发明授权
    NdNi5 alloys for hydrogen storage and Ni-MH batteries 有权
    用于氢存储的NdNi5合金和Ni-MH电池

    公开(公告)号:US08968644B2

    公开(公告)日:2015-03-03

    申请号:US12928109

    申请日:2010-12-02

    摘要: A hydrogen storage alloy having the atomic formula AB4.75-5.25. Where A may comprise at least 85 atomic percent Nd and less than 15 atomic percent other rare earth elements and Mg and B may comprise Ni, Co, and at least one element selected from the group consisting of Mn and Al. The atomic percentages of Mn and Al may be governed by the following formulas where Mn and Al are in atomic percent: 1) Mn+1.5 Al≧6 atomic percent; and 2) Mn+Al≦12 atomic percent. The total percent of Mn and Al may provide the alloy with a 20° C. plateau pressure of between 4 and 25 psi, preferably between 6 and 20 psi. The hydrogen storage alloy allows a nickel metal hydride battery into which it is incorporated to maintain a voltage of at least 1.2 V at a depth of discharge of 90%.

    摘要翻译: 具有原子化学式AB4.75-5.25的储氢合金。 其中A可以包含至少85原子%的Nd和小于15原子%的其它稀土元素,并且Mg和B可以包含Ni,Co和至少一种选自Mn和Al的元素。 Mn和Al的原子百分比可以由下式表示:Mn和Al的原子百分比:1)Mn +1.5Al≥6原子% 和2)Mn + Al≦̸ 12原子%。 Mn和Al的总百分比可以为合金提供在4和25psi之间,优选在6和20psi之间的20℃平台压力。 储氢合金允许其中所掺入的镍金属氢化物电池在放电深度为90%时保持至少1.2V的电压。

    Method of activating metal hydride material and electrode
    37.
    发明授权
    Method of activating metal hydride material and electrode 有权
    激活金属氢化物材料和电极的方法

    公开(公告)号:US06569567B1

    公开(公告)日:2003-05-27

    申请号:US09395391

    申请日:1999-09-13

    IPC分类号: H01M404

    摘要: A method of activating a hydrogen storage alloy or a hydrogen storage alloy electrode. The method includes the step of contacting the hydrogen storage alloy or hydrogen storage alloy electrode with an aqueous solution of an alkali metal hydroxide where the concentration of the alkali metal hydroxide is at least about 40 weight percent. The method produces a hydrogen storage alloy and hydrogen storage alloy electrode with increased surface area.

    摘要翻译: 一种活化储氢合金或储氢合金电极的方法。 该方法包括使储氢合金或储氢合金电极与碱金属氢氧化物的水溶液接触的步骤,其中碱金属氢氧化物的浓度为至少约40重量%。 该方法产生具有增加的表面积的储氢合金和储氢合金电极。

    Method for powder formation of a hydrogen storage alloy
    39.
    发明授权
    Method for powder formation of a hydrogen storage alloy 失效
    储氢合金粉末形成方法

    公开(公告)号:US6120936A

    公开(公告)日:2000-09-19

    申请号:US141668

    申请日:1998-08-27

    摘要: A novel method for forming powder of a hydrogen storage alloy without the need for further mechanical processing. The alloy powder may be adapted for use as the negative electrode material of rechargeable electrochemical, hydrogen storage cells. The method includes the step of controlling the hydrogen concentration within the hydrogen storage alloy to form powder where 90% of the particles are less than 250 microns in average dimension.

    摘要翻译: 一种用于形成储氢合金粉末的新方法,而不需要进一步的机械加工。 合金粉末可适用于可再充电电化学储氢电池的负极材料。 该方法包括控制储氢合金中的氢浓度形成粉末的步骤,其中90%的颗粒平均尺寸小于250微米。