公开(公告)号：US08268485B2

公开(公告)日：2012-09-18

申请号：US10563126

申请日：2004-08-30

申请人： Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

发明人： Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

IPC分类号： H01M4/62 ,  H01M4/58 ,  H01M4/52

CPC分类号： H01M4/366 ,  C01G51/42 ,  C01P2002/50 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/44

摘要： A nonaqueous electrolyte secondary battery which has a positive electrode containing lithium cobalt oxide as a positive active material, a negative electrode containing a graphite material and a nonaqueous electrolyte solution containing ethylene carbonate as a solvent and which is charged with an end-of-charge voltage of at least 4.3 V. Characteristically, the battery uses, as the positive active material, lithium cobalt oxide obtained by firing a mixture of a lithium salt, tricobalt tetraoxide (Co3O4) and a zirconium compound and having particle surfaces onto which the zirconium compound adheres.

摘要翻译： 具有含有作为正极活性物质的钴酸锂的正极的非水电解质二次电池，含有石墨材料的负极和含有碳酸亚乙酯作为溶剂的非水电解液，并充入充电电压 特别地，电池使用通过焙烧锂盐，四氧化四钴（Co 3 O 4）和锆化合物并具有锆化合物附着的颗粒表面的混合物而获得的钴酸锂作为正极活性材料 。

公开(公告)号：US07655273B2

公开(公告)日：2010-02-02

申请号：US11979915

申请日：2007-11-09

申请人： Masahisa Fujimoto ,  Yasuyuki Kusumoto ,  Masahide Miyake ,  Hiroaki Ikeda ,  Shin Fujitani

发明人： Masahisa Fujimoto ,  Yasuyuki Kusumoto ,  Masahide Miyake ,  Hiroaki Ikeda ,  Shin Fujitani

IPC分类号： B05D7/00

CPC分类号： H01M4/134 ,  H01M4/364 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/626 ,  H01M10/052 ,  Y10T29/49115

摘要： A method of manufacturing an electrode active material particle for a rechargeable battery wherein a layer of an active material capable of being alloyed with Li is formed on a surface of a metal particle incapable of being alloyed with Li and then a heat treatment is conducted to diffuse the active material into the metal particle so that the resulting active material particle has a concentration profile in which a concentration of a metal element of the metal particle decreases from an interior toward the surface.

摘要翻译： 一种制造可充电电池用电极活性物质粒子的方法，其特征在于，在不能与Li合金化的金属粒子的表面上形成能够与Li合金化的活性物质层，然后进行热处理 活性物质进入金属颗粒，使得所得到的活性物质颗粒具有金属颗粒的金属元素的浓度从内部朝向表面降低的浓度分布。

公开(公告)号：US07410728B1

公开(公告)日：2008-08-12

申请号：US10111073

申请日：2000-10-20

申请人： Masahisa Fujimoto ,  Shin Fujitani ,  Masaki Shima ,  Hiromasa Yagi ,  Hisaki Tarui ,  Hiroshi Kurokawa ,  Shigeki Matsuta ,  Yoichi Domoto ,  Yoshio Kato ,  Hiroshi Nakajima ,  Hiroaki Ikeda ,  Kenji Asaoka ,  Ryuji Ohshita

发明人： Masahisa Fujimoto ,  Shin Fujitani ,  Masaki Shima ,  Hiromasa Yagi ,  Hisaki Tarui ,  Hiroshi Kurokawa ,  Shigeki Matsuta ,  Yoichi Domoto ,  Yoshio Kato ,  Hiroshi Nakajima ,  Hiroaki Ikeda ,  Kenji Asaoka ,  Ryuji Ohshita

IPC分类号： H01M4/66 ,  H01M4/58

CPC分类号： H01M4/661 ,  H01M4/131 ,  H01M4/1395 ,  H01M4/366 ,  H01M4/38 ,  H01M4/386 ,  H01M4/40 ,  H01M4/405 ,  H01M4/525 ,  H01M4/58 ,  H01M4/667 ,  H01M4/70 ,  H01M6/40 ,  H01M10/052 ,  H01M10/0587 ,  H01M10/44 ,  H01M2004/021 ,  H01M2010/4292

摘要： An electrode for lithium batteries, in which a thin film of active material capable of storage and release of lithium, such as a microcrystalline or amorphous silicon thin film, is provided, through an interlayer, on a current collector, the electrode being characterized in that the interlayer comprises a material alloyable with the thin film of active material.

摘要翻译： 一种用于锂电池的电极，其中通过中间层，在集电器上提供能够储存和释放锂的活性材料的薄膜，例如微晶或非晶硅薄膜，所述电极的特征在于： 中间层包括可与活性材料薄膜合金化的材料。

公开(公告)号：US20070202406A1

公开(公告)日：2007-08-30

申请号：US11699000

申请日：2007-01-29

申请人： Yasufumi Takahashi ,  Akira Kinoshita ,  Shingo Tode ,  Tatsuyuki Kuwahara ,  Kazuhiro Hasegawa ,  Hiroyuki Fujimoto ,  Shin Fujitani

发明人： Yasufumi Takahashi ,  Akira Kinoshita ,  Shingo Tode ,  Tatsuyuki Kuwahara ,  Kazuhiro Hasegawa ,  Hiroyuki Fujimoto ,  Shin Fujitani

IPC分类号： H01M4/52 ,  H01M10/40

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/1391 ,  H01M6/162 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M10/0566 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/028 ,  H01M2010/4292 ,  H01M2300/0025

摘要： The storage characteristics in a charged state are improved in a non-aqueous electrolyte secondary battery containing a lithium cobalt oxide as a positive electrode active material. The non-aqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material other than metallic lithium; and a non-aqueous electrolyte. The positive electrode active material contains a lithium cobalt oxide as its main component. The non-aqueous electrolyte contains 0.1 to 10 volume % of a compound having an ether group. The positive electrode active material and the negative electrode active material are contained so that the charge capacity ratio of the negative electrode to the positive electrode is from 1.0 to 1.2 when the battery is charged until the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li+)

摘要翻译： 在含有钴酸锂作为正极活性物质的非水电解质二次电池中，充电状态下的储存特性得到改善。 非水电解质二次电池包括含有正极活性物质的正极; 含有金属锂以外的负极活性物质的负极; 和非水电解质。 正极活性物质以钴酸锂为主要成分。 非水电解质含有0.1〜10体积％的具有醚基的化合物。 包含正极活性物质和负极活性物质，使得当电池充电直到正极的电位达到4.4至4.5V（负极）时，负极与正极的充电容量比为1.0至1.2 与Li / Li + + /

公开(公告)号：US07258950B2

公开(公告)日：2007-08-21

申请号：US10380801

申请日：2001-09-19

申请人： Noriyuki Tamura ,  Shiori Nakamizo ,  Daizo Jito ,  Ryuji Ohshita ,  Masahisa Fujimoto ,  Shin Fujitani ,  Maruo Kamino

发明人： Noriyuki Tamura ,  Shiori Nakamizo ,  Daizo Jito ,  Ryuji Ohshita ,  Masahisa Fujimoto ,  Shin Fujitani ,  Maruo Kamino

IPC分类号： H01M4/72 ,  H01M4/58

CPC分类号： H01M4/134 ,  H01M4/661 ,  H01M4/667 ,  H01M10/052

摘要： An electrode having a current collector and, formed thereon, a thin film comprising an active material, characterized in that a thin alloy film (such as Sn—Co) comprising a metal which can form an alloy with lithium (such as Sn) and a metal which can not form an alloy with lithium (such as Co) is formed on a current collector such as a copper foil. It is preferred that the above metal which can form an alloy with lithium and the above metal which can not form an alloy with lithium can not form an intermetallic compound with each other.

摘要翻译： 一种具有集电体并且在其上形成包含活性材料的薄膜的电极，其特征在于，包含可以与锂（例如Sn）形成合金的金属的薄合金膜（例如Sn-Co）和 在诸如铜箔的集电体上形成不能与锂（例如Co）形成合金的金属。 优选与锂形成合金的上述金属和不能与锂形成合金的上述金属彼此不能形成金属间化合物。

公开(公告)号：US20060105240A1

公开(公告)日：2006-05-18

申请号：US11140064

申请日：2005-05-31

申请人： Akira Kinoshita ,  Hiroyuki Fujimoto ,  Yasufumi Takahashi ,  Shingo Tode ,  Kazuhiro Hasegawa ,  Shin Fujitani

发明人： Akira Kinoshita ,  Hiroyuki Fujimoto ,  Yasufumi Takahashi ,  Shingo Tode ,  Kazuhiro Hasegawa ,  Shin Fujitani

IPC分类号： H01M4/52 ,  H01M4/50 ,  H01M10/40

CPC分类号： H01M4/485 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2010/4292 ,  H01M2300/0025

摘要： A non-aqueous electrolyte secondary battery including a positive electrode containing a positive active material, a negative electrode containing a negative active material and a non-aqueous electrolyte, characterized in that lithium transition metal complex oxide A formed by allowing LiCoO2 to contain at least both of Zr and Mg and lithium transition metal complex oxide B having a layered structure and containing at least both of Mn and Ni as transition metals are mixed and used as said positive active material, and vinylene carbonate and divinyl sulfone are contained in said non-aqueous electrolyte.

摘要翻译： 一种非水电解质二次电池，其包含含有正极活性物质的正极，含有负极活性物质的负极和非水电解质，其特征在于，通过使LiCoO 2 / SUB>至少包含Zr和Mg两者以及具有层状结构并且至少包含Mn和Ni两者的过渡金属的锂过渡金属络合物B混合并用作所述正极活性物质，并且碳酸亚乙烯酯和二乙烯基 所述非水电解质中含有砜。

公开(公告)号：US20060024587A1

公开(公告)日：2006-02-02

申请号：US11234239

申请日：2005-09-26

申请人： Noriyuki Tamura ,  Toshikazu Yoshida ,  Maruo Kamino ,  Shin Fujitani ,  Masahiro Takehara ,  Makoto Ue

发明人： Noriyuki Tamura ,  Toshikazu Yoshida ,  Maruo Kamino ,  Shin Fujitani ,  Masahiro Takehara ,  Makoto Ue

IPC分类号： H01M4/58

CPC分类号： H01M4/139 ,  H01M4/045 ,  H01M4/134 ,  H01M4/525 ,  H01M4/661 ,  H01M4/70 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025

摘要： A nonaqueous electrolyte secondary battery in which the decomposition of an electrolyte solution is reduced exhibits high coulombic efficiency and excellent charge and discharge cycle performance, and has high energy density. This nonaqueous electrolyte secondary battery includes a negative electrode that is formed by depositing a thin film of active material on a collector by a CVD method, sputtering, evaporation, thermal spraying, or plating, wherein the thin film of the active material can lithiate and delithiate and is divided into columns by cracks formed in the thickness direction, and the bottom of each column is adhered to the collector; a positive electrode that can lithiate and delithiate; and a nonaqueous electrolyte solution containing a lithium salt in a nonaqueous solvent. The electrolyte solution contains a compound expressed by a general formula (I). Rn-M=0   (I) (wherein, Rs are alkyl groups optionally having a substituent, may be identical or different from one another, may be independent substituents, or may be bound together to form a ring; M is S or P; and n is 2 when M is S and is 3 when M is P.)

摘要翻译： 其中电解液的分解降低的非水电解质二次电池显示出高的库仑效率和优异的充放电循环性能，并且具有高的能量密度。 该非水电解质二次电池包括通过CVD法，溅射法，蒸镀法，热喷镀法或电镀法将活性物质薄膜沉积在集电体上形成的负极，其中活性物质的薄膜可以锂化和脱锂 并通过在厚度方向上形成的裂纹分成列，并且每列的底部粘附到集电体; 可以锂化和脱锂的正极; 以及在非水溶剂中含有锂盐的非水电解液。 电解质溶液含有由通式（I）表示的化合物。 <？in-line-formula description =“In-line Formulas”end =“lead”？> R -M = 0（I）<？in-line-formula description =“In- （其中，R 5为任选具有取代基的烷基可以相同或不同）可以是独立的取代基，或者可以结合在一起形成环; M是S或 P;当M为S时n为2，M为P时为3）

公开(公告)号：US06764791B2

公开(公告)日：2004-07-20

申请号：US09904514

申请日：2001-07-16

申请人： Noriyuki Tamura ,  Masahisa Fujimoto ,  Maruo Kamino ,  Shin Fujitani ,  Hiromasa Yagi ,  Yoichi Domoto ,  Hisaki Tarui ,  Ryuji Ohshita ,  Ikuo Yonezu

发明人： Noriyuki Tamura ,  Masahisa Fujimoto ,  Maruo Kamino ,  Shin Fujitani ,  Hiromasa Yagi ,  Yoichi Domoto ,  Hisaki Tarui ,  Ryuji Ohshita ,  Ikuo Yonezu

IPC分类号： H01M448

CPC分类号： H01M4/134 ,  H01M4/131 ,  H01M4/366 ,  H01M4/40 ,  H01M4/405 ,  H01M4/525 ,  H01M4/62 ,  H01M4/625 ,  H01M10/052 ,  H01M2004/021

摘要： A rechargeable lithium battery using an Li alloying metal as the active material of at least one of its positive and negative electrodes. The metal active material is covered with a thin film which is nonreactive with Li ions, permits passage of Li ions but does not have an Li ion conductivity.

摘要翻译： 使用Li合金金属作为其正极和负极中的至少一个的活性材料的可再充电锂电池。 该金属活性材料用与Li离子无反应的薄膜覆盖，允许Li离子通过但不具有Li离子传导性。

公开(公告)号：US06716556B2

公开(公告)日：2004-04-06

申请号：US09897758

申请日：2001-07-03

申请人： Takuya Sunagawa ,  Yoichi Domoto ,  Ryuji Ohshita ,  Hisaki Tarui ,  Shin Fujitani ,  Ikuo Yonezu

发明人： Takuya Sunagawa ,  Yoichi Domoto ,  Ryuji Ohshita ,  Hisaki Tarui ,  Shin Fujitani ,  Ikuo Yonezu

IPC分类号： H01M448

CPC分类号： H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/661 ,  H01M10/052 ,  H01M2004/028

摘要： A nonaqueous electrolyte rechargeable battery including a positive electrode comprising a molybdenum metal oxide deposited, in the form of a thin film, on an aluminum-containing substrate and represented by the formula Mo1−xMxO2+y (where M is at least one element selected from the group consisting of Ni, Co, Mn, Fe, Cu, Al, Mg, W, Sc, Ti, Zn, Ga, Ge, Nb, Rh, Pd and Sn, x satisfies the relationship 0.005≦x≦0.5, and y satisfies the relationship 0.6≦y≦1.2).

摘要翻译： 一种非水电解质可再充电电池，包括正极，该正极包含以薄膜形式沉积在含铝衬底上并由式Mo1-xMxO2 + y表示的钼金属氧化物（其中M是至少一种选自 由Ni，Co，Mn，Fe，Cu，Al，Mg，W，Sc，Ti，Zn，Ga，Ge，Nb，Rh，Pd和Sn组成的组x满足0.005 <= x <= 0.5， y满足关系0.6 <= Y＆LE; 1.2）。

公开(公告)号：US06677081B2

公开(公告)日：2004-01-13

申请号：US09863820

申请日：2001-05-24

申请人： Takuya Sunagawa ,  Ryuji Ohshita ,  Shin Fujitani

发明人： Takuya Sunagawa ,  Ryuji Ohshita ,  Shin Fujitani

IPC分类号： H01M450

CPC分类号： H01M4/0497 ,  C01G45/00 ,  C01G45/02 ,  C01G49/0072 ,  C01G53/00 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/04 ,  H01M4/0402 ,  H01M4/043 ,  H01M4/131 ,  H01M4/505 ,  H01M10/0525 ,  H01M2004/028

摘要： The present invention provides a positive electrode active material for a non-aqueous electrolyte secondary battery and a non-aqueous electrolyte secondary battery having the positive electrode active material. The positive electrode active material includes a complex oxide wherein said complex oxide is substantially amorphous and comprises Mn and M; where M is selected from the group consisting of Ni, Co, Fe, Cu, Al, Mg, Si, Sc, Ti, Zn, Ga, Ge, Nb, Rh, Pd and Sn; and the molar weighted sum of oxidation states of elements except for oxygen is more than 3.8 and not greater than 4.2. More preferably, a mole ratio of Mn and M (Mn:M) is in a range of 99:1˜70:30.

摘要翻译： 本发明提供一种非水电解质二次电池用正极活性物质和具有正极活性物质的非水电解质二次电池。 正极活性物质包括复合氧化物，其中所述复合氧化物基本上是无定形的并且包括Mn和M; 其中M选自Ni，Co，Fe，Cu，Al，Mg，Si，Sc，Ti，Zn，Ga，Ge，Nb，Rh，Pd和Sn; 除氧以外的元素的氧化态摩尔加权总和大于3.8且不大于4.2。 更优选Mn和M（Mn：M）的摩尔比在99:1〜70:30的范围内。