Abstract:
Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by hydrotreating the feed under mild conditions, and separating the hydrotreated effluent into an aromatic-rich fraction which contains a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds, and an aromatic-lean fraction. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction is recycled to the mild hydrotreating process.
Abstract:
Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatic-rich and aromatic-lean fractions separately, the hydrocracking operating severity and/or catalyst reactor volume requirement decreases.
Abstract:
Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatic-rich and aromatic-lean fractions separately, the hydrocracking operating severity and/or catalyst reactor volume requirement decreases.
Abstract:
An improved process for the delayed coking of a heavy residual hydrocarbon feedstock to reduce the coking induction period and to enhance the coking process relative to the processes of the prior art is achieved by mixing a sufficient volume of a paraffinic solvent having the formula CnH2n+2, where n=3 to 8 with the heavy feedstock to disturb the equilibrium of asphaltenes in the solution of maltenes in order to flocculate substantially all of the solid asphaltenes particles to thereby increase the yield and quality of valuable liquid products and minimize undesirable cracking reactions that result in high molecular weight polymers and the formation of coke.
Abstract translation:通过混合足够体积的具有式C n H 2n + 2的链烷烃溶剂来实现重质残留烃原料的延迟焦化以减少焦化诱导期并改进与现有技术方法相关的焦化方法的改进方法 ,其中n = 3至8,其中重质原料扰乱麦芽糖溶液中沥青质的平衡,以便基本上絮凝所有固体沥青质颗粒,从而提高有价值的液体产物的产率和质量,并使不合需要的开裂反应最小化 导致高分子量聚合物和焦炭的形成。
Abstract:
Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur-containing and nitrogen-containing hydrocarbon compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed.
Abstract:
A system and process are provided for integrated deasphalting and desulfurization of hydrocarbon feedstock in which the hydrocarbon feedstock, an oxidant, and an oxidation catalyst are mixed prior to passage into a primary settler of a solvent deasphalting unit. Oxidation products, including oxidized organosulfur compounds, are discharged with the asphalt phase.