摘要:
An improved process for the treatment and liquefaction of calcium-containing subbituminous coal and coals of lower rank to form water soluble compounds of calcium, thereby suppressing the formation of scale, made up largely of calcium carbonate which normally forms within the coal liquefaction zone, e.g. on reactor surfaces, lines, auxiliary equipment and the like. An oxide of sulfur is contacted with a coal feed sufficient to impregnate the pores of the coal. The impregnated coal is then contacted with hydrogen sulfide to produce water soluble thiosulfate. After the treated coal is liquefied in a coal liquefaction zone, the effluent is water washed to remove the water soluble thiosulfate.
摘要:
A process is disclosed for the conversion of a petroleum distillate charge stock containing mercaptan, olefinic and dienic compounds comprising the treatment of said petroleum distillate in an atmosphere of an oxygen-containing gas in a medium possessing a pH of from about a pH of 8 to about a pH of 14 in the presence of a catalyst comprising a 4,4',4",4'"-cobalt phthalocyanine tetrasulfonate.
摘要:
The invention relates to an ion-conductive polymer membrane for a fuel cell, whereby the polymer membrane is configured from a polymer-forming hydrocarbon material and to a method for producing the same. The membrane also has a metal-containing gel which has been hydrolysed and/or condensed from a metal alkoxide starting material and which is deposited in the polymer and/or is chemically bonded to the polymer. The proportion of metal alkoxide by weight, in relation to the membrane, lies between 25% and 1%.
摘要:
An outer joint part for a constant velocity universal ball joint, produced from a tubular member formed from a plate metal part and provided with substantially longitudinally extending ball tracks intended for receiving torque transmitting balls, with an axial central portion of the tubular member is reduced in cross-section relative to two axial end regions and is provided with ball tracks, with a substantially radial flange formed on at one axial end of the tubular member, with the center lines of the ball tracks extending in a non-parallel way relative to the axis A of the outer joint part and with the axial end of the tubular member positioned opposite the flange remaining undeformed.
摘要:
An antifouling compound comprising a phthalocyanine compound is disclosed for use in high temperature coke producing petroleum reactions wherein said coke is unwanted and acts as a fouling agent in the associated reaction apparatus.
摘要:
A coal liquefaction process comprising reacting coal with a hydrocarbonaceous solvent at coal liquefaction conditions in the presence of an oil shale residue catalyst comprising organic and inorganic fractions. The oil shale residue catalyst is derived by heating an oil shale in the presence of an inert gas with respect to the oil shale at a temperature of 500.degree.-825.degree. F.
摘要:
A gas treating process is disclosed. Hydrogen sulfide and carbon dioxide are removed from a hydrocarbon vapor stream by absorption into an aqueous carbonate solution. Hydrogen sulfide picked up by the circulating carbonate solution is oxidized to produce liquid sulfur, which is withdrawn. The carbonate solution is then stripped to release carbon dioxide and produce the lean carbonate solution used for absorption. By-product thiosulfate formed in the oxidation step is eliminated by reaction with hydrogen sulfide. Metal phthalocyanines are used as the catalyst for the elimination of thiosulfate and for the oxidation of hydrogen sulfide.
摘要:
A process for liquefying a calcium-containing coal which comprises contacting calcium-containing coal with an aqueous sulfur oxide solution. The resulting admixture is contacted with hydrogen sulfide to produce water soluble thiosulfate. After the treated coal is separated from the resulting aqueous phase, the coal is charged to a coal liquefaction zone.
摘要:
An improved process for removing, by absorption, sulfur dioxide from a gaseous mixture such as a flue gas by scrubbing said mixture with an aqueous scrubbing liquor to which a solution of an alkaline reagent such as sodium carbonate is added to maintain alkalinity of the scrubbing liquor. The solution also has dissolved in it a quantity of silica which tends to precipitate when the solution is added to the scrubbing liquor. The silica precipitated in this manner tends to form extremely hard solid deposits in the scrubbing device and associated equipment. The improvement to the process comprises the cyclic, intermittent, batchwise and rapid addition of the alkaline reagent solution to the scrubbing liquor, the addition beginning upon the scrubbing liquor pH reaching a certain minimum value and ending upon the scrubbing liquor reaching a certain maximum value.
摘要:
An improved process for removing, by absorption, sulfur dioxide from a gaseous mixture such as a flue gas by scrubbing said mixture with an aqueous scrubbing liquor to which a solution of an alkaline reagent such as sodium carbonate is added to maintain alkalinity of the scrubbing liquor. The solution also has dissolved in it a quantity of silica which tends to precipitate when the solution is added to the scrubbing liquor. The silica precipitated in this manner tends to form extremely hard solid deposits in the scrubbing device and associated equipment. If a water soluble salt such as ferrous or ferric sulfate is added to the alkaline reagent solution prior to its use in the process, the precipitate formed has a minimum deleterious effect. The improvement to the process comprises the lowering of the pH of the alkaline reagent solution prior to the addition of the salt, thereby minimizing the amount of salt required.