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91 条记录 (耗时 0.027 秒)

    Functionalized polymers and process for modifying unsaturated polymers
    32.
    发明授权
    Functionalized polymers and process for modifying unsaturated polymers 失效
    官能化聚合物和改性不饱和聚合物的方法

    公开(公告)号：US4851476A

    公开(公告)日：1989-07-25

    申请号：US77827

    申请日：1987-07-27

    申请人： Carl L. Willis

    发明人： Carl L. Willis

    IPC分类号： C08G8/00 ,  C08F8/00 ,  C08F8/04

    CPC分类号： C08F8/00 ,  C08F8/04

    摘要： Unsaturated hydrocarbon polymers are hydrogenated in the presence of a catalyst obtained by combining a Group VIII-A metal alkoxide or carboxylate and an alkyl or hydride of a metal selected from Groups I-A, II-A and III-B and then functionalized by contacting the hydrogenated polymer with a functionalizing agent before the hydrogenation catalyst is quenched or otherwise deactivated. The hydrogenation is, generally, accomplished at relatively mild conditions to avoid degradation of the polymer and, in the case of unsaturated copolymers comprising aromatic unsaturation, to avoid any significant hydrogenation of the aromatic unsaturation. Generally, the hydrogen partial pressure employed will be below about 1000 psig and the hydrogenation temperature will be below about 125.degree. C. The hydrogenated polymer may be functionalized by reaction with functionalizing agent select from the group carbon dioxide, ethylene oxide, aldehydes, ketones, carboxylic acid salts and esters, halides, epoxides, sulfur, boron alkoxides, isocyanates, various silicon compounds and the like. Carbon dioxide is a particularly preferred functionalizing agent since the thus functionalized polymer is useful as a modifier in sheet and bulk molding compositions and readily responds to the presence of thickening agents.

    Hydrogenation of polymers having ketone groups
    36.
    发明授权
    Hydrogenation of polymers having ketone groups 失效
    具有酮基的聚合物的氢化

    公开(公告)号：US5597872A

    公开(公告)日：1997-01-28

    申请号：US529304

    申请日：1990-05-29

    申请人： Carl L. Willis

    发明人： Carl L. Willis

    IPC分类号： C08C19/02 ,  C08F8/04 ,  C08F297/04

    CPC分类号： C08C19/02 ,  C08F8/04 ,  Y10S525/94

    摘要： Polymers containing ketone groups such as hydroesterified 1,3-butadiene polymers, including styrenic block copolymers, are hydrogenated with a cobalt/aluminum catalyst which substantially converts ketone groups to alcohol groups and improves polymer stability.

    摘要翻译： 含有酮基的聚合物如加氢酯化的1,3-丁二烯聚合物（包括苯乙烯嵌段共聚物）用钴/铝催化剂氢化，钴/铝催化剂基本上将酮基转化为醇基并提高聚合物的稳定性。

    Hydroesterification of polymerized conjugated dienes
    39.
    发明授权
    Hydroesterification of polymerized conjugated dienes 失效
    聚合共轭二烯的加氢酯化

    公开(公告)号：US4981916A

    公开(公告)日：1991-01-01

    申请号：US357451

    申请日：1989-05-26

    申请人： Carl L. Willis

    发明人： Carl L. Willis

    IPC分类号： C08C19/00 ,  C08C19/10

    CPC分类号： C08C19/10 ,  C08C19/00

    摘要： Polymerized 1,3-butadiene, including styrenic block copolymers, are functionalized with both carboxylic ester groups and ketone linking groups by reaction with carbon monoxide and an alcohol. Such conjugated diene polymers can be reacted in the presence of a catalyst composition that includes a cobalt compound and an amine ligand. The functionalized 1,3-butadiene polymers may be hydrogenated with a nickel/aluminum catalyst which removes olefinically unsaturated carbon-carbon bonds without substantially hydrogenating the ketone linking groups and carboxylic ester groups.

    摘要翻译： 包括苯乙烯嵌段共聚物在内的聚合的1,3-丁二烯通过与一氧化碳和醇反应而被羧酸酯基和酮连接基官能化。 这样的共轭二烯聚合物可以在包括钴化合物和胺配体的催化剂组合物的存在下反应。 官能化的1,3-丁二烯聚合物可以用镍/铝催化剂氢化，镍/铝催化剂除去烯键不饱和碳 - 碳键，而基本上不使酮连接基团和羧酸酯基团氢化。

    Method for hydrogenating functionalized polymer and products thereof
    40.
    发明授权
    Method for hydrogenating functionalized polymer and products thereof 失效
    氢化官能化聚合物及其制品的方法

    公开(公告)号：US4970254A

    公开(公告)日：1990-11-13

    申请号：US247835

    申请日：1988-09-22

    申请人： Carl L. Willis ,  Lorelle A. Pottick ,  Dan E. Goodwin

    发明人： Carl L. Willis ,  Lorelle A. Pottick ,  Dan E. Goodwin

    IPC分类号： C08C19/00 ,  C08C19/02 ,  C08F8/00 ,  C08F8/04 ,  C08F8/46

    CPC分类号： C08F8/04

    摘要： A method for preparing hydrogenated polymers containing acidic functionality in a portion thereof initially containing ethylenic unsaturation from a polymer containing ethylenic unsaturation or both aromatic and ethylenic unsaturation comprising the steps of first incorporating an acidic functional group precursor radical into the polymer, hydrogenating at least a portion of the ethylenic unsaturation contained in the polymer containing the acidic functional group precursor radicals and then converting at least a portion of the acidic functional group precursor radicals to the corresponding acidic functional group. In general, any acidic functional group precursor radical which will have less of an impact upon the hydrogenation reaction than the corresponding acidic functional group may be used. Best results are, however, achieved when acidic functional group precursors are used which are relatively neutral and which do not react or complex with the metal compounds used to prepare the catalyst or resulting from the combination of such metal compounds. The catalyst used to effect the hydrogenation will be prepared by combining a compound, preferably an alkoxide or carboxylate, of an iron group metal with an alkyl or a hydride containing a Group I-A, II-A or III-B metal. Preparation of the catalyst is preferably accomplished in the presence of water. Best results are achieved when the acidic functional group precursor is a metal salt and the metal salt and the reducing component used to prepare the catalyst contain the same metal. Depending upon the particular catalyst employed and the acidic functional group precursor radical used, up to about 90-95% of the ethylenic unsaturation initially contained in the polymer can be converted or hydrogenated.