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公开(公告)号：US07858693B2
公开(公告)日：2010-12-28
申请号：US11388628
申请日：2006-03-24
CPC分类号： C08F297/044 , C08F297/04 , C08L53/02 , C08L2666/02 , C08L2666/24
摘要： The present invention relates to novel compositions comprising (a) anionic block copolymers having at least two blocks of a mono alkenyl arene and at least one block of a conjugated diene and mono alkenyl arene having a specific arrangement of the monomers in the copolymer block, and (b) tailored softening modifiers have a particular structure that results in a surprising improvement in properties for the composition. Also included are processes for the manufacturing such novel compositions and various end-uses and applications for such compositions.
摘要翻译： 本发明涉及新型组合物，其包含（a）阴离子嵌段共聚物，其具有至少两个单烯基芳烃嵌段和至少一个共轭二烯嵌段和共聚物嵌段中单体具体排列的单烯基芳烃;以及 （b）定制的软化改性剂具有导致组合物的性能惊人改善的特定结构。 还包括用于制造这种新型组合物和各种最终用途和用于这种组合物的方法。
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公开(公告)号：US07332542B2
公开(公告)日：2008-02-19
申请号：US11055367
申请日：2005-02-10
IPC分类号： C08F297/04 , C08L9/06
CPC分类号： C09J153/02 , C08F287/00 , C08F297/04 , C08L23/10 , C08L53/02 , C08L53/025 , C08L77/00 , C08L95/00 , C08L101/00 , C08L2666/02 , C08L2666/24 , C09D153/02 , C09D153/025 , C09J153/025 , C08L2666/04 , C08L53/00
摘要： The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.
摘要翻译： 本发明是含有共轭二烯和单烯基芳烃的受控分布共聚物嵌段的新型嵌段共聚物，其中受控分布共聚物嵌段具有富含共轭二烯单元的末端区域和富含单烯基的中心区域 别墅单位 还公开了一种制备嵌段共聚物的方法。
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公开(公告)号：USRE39559E1
公开(公告)日：2007-04-10
申请号：US10657064
申请日：2003-09-05
申请人： Dale L. Handlin, Jr. , Daniel E. Goodwin , Carl L. Willis , David J. St. Clair , John D. Wilkey , Michael J. Modic , Craig A. Stevens
发明人： Dale L. Handlin, Jr. , Daniel E. Goodwin , Carl L. Willis , David J. St. Clair , John D. Wilkey , Michael J. Modic , Craig A. Stevens
IPC分类号： C08F8/00
CPC分类号： C08L19/006 , C08C19/44 , C08F136/06 , C08G18/0823 , C08G18/6208 , C08G18/8175 , C08G63/00 , C08G64/18 , C08G69/00 , C08G81/024 , C08L15/00 , C08F4/488 , C08G18/62
摘要： Hydrogenated butadiene polymers having terminal functional groups have minimum viscosity at any molecular weight when the 1,2-addition is between 30% and 70%. Hydrogenated butadiene polymers having about two terminal hydroxyl groups per molecule have surprisingly lower viscosities at 30% to 70% 1,2-addition than similar polymers having either higher or lower amounts of 1,2-addition. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要翻译： 具有末端官能团的氢化丁二烯聚合物在1,2-加成量在30％至70％之间时具有任何分子量下的最小粘度。 每分子具有约两个末端羟基的氢化丁二烯聚合物具有比具有更高或更低量1,2-加成的类似聚合物在30％至70％1,2-加成中具有惊人的较低粘度。 聚合物可用于制备涂料，密封剂，粘合剂和与聚酯，聚酰胺和聚碳酸酯的嵌段共聚物。
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公开(公告)号：US5405911A
公开(公告)日：1995-04-11
申请号：US306552
申请日：1994-09-15
申请人： Dale L. Handlin, Jr. , Daniel E. Goodwin , Carl L. Willis , David J. St. Clair , John D. Wilkey , Michael J. Modic , Craig A. Stevens
发明人： Dale L. Handlin, Jr. , Daniel E. Goodwin , Carl L. Willis , David J. St. Clair , John D. Wilkey , Michael J. Modic , Craig A. Stevens
IPC分类号： C08C19/44 , C08F136/06 , C08G18/08 , C08G18/62 , C08G18/81 , C08G63/00 , C08G64/18 , C08G69/00 , C08G81/02 , C08L15/00 , C08L19/00 , C08F8/00
CPC分类号： C08L19/006 , C08C19/44 , C08F136/06 , C08G18/0823 , C08G18/6208 , C08G18/8175 , C08G63/00 , C08G64/18 , C08G69/00 , C08G81/024 , C08L15/00
摘要： Hydrogenated butadiene polymers having terminal functional groups have minimum viscosity at any molecular weight when the 1,2-addition is between 30% and 70% Hydrogenated butadiene polymers having about two terminal hydroxyl groups per molecule have surprisingly lower viscosities at 30% to 70% 1,2-addition than similar polymers having either higher or lower amounts of 1,2-addition. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要翻译： 具有末端官能团的氢化丁二烯聚合物在1,2-加成量为30％至70％时具有任何分子量的最小粘度。每分子具有约两个末端羟基的氢化丁二烯聚合物具有30％至70％1的令人惊奇的较低粘度 ，比具有更高或更低量的1,2-加成的类似聚合物进行2-加成。 聚合物可用于制备涂料，密封剂，粘合剂和与聚酯，聚酰胺和聚碳酸酯的嵌段共聚物。
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公开(公告)号：US07582702B2
公开(公告)日：2009-09-01
申请号：US11388909
申请日：2006-03-24
申请人： Kathryn J. Wright , Carl L. Willis , Tomomi Nishi , Norio Masuko , Dale L. Handlin, Jr. , Robert C. Bening
发明人： Kathryn J. Wright , Carl L. Willis , Tomomi Nishi , Norio Masuko , Dale L. Handlin, Jr. , Robert C. Bening
CPC分类号： C08L53/02 , C08F8/04 , C08F287/00 , C08F297/04 , C08L51/006 , C08L53/025 , C08L2666/24 , C08L2666/02
摘要： The present invention relates to novel compositions comprising (a) anionic block copolymers of mono alkenyl arenes and conjugated dienes where one of the blocks is a controlled distribution copolymer of a conjugated diene and mono alkenyl arene having a specific arrangement of the monomers in the copolymer block, and (b) tailored softening modifiers have a particular structure that results in a surprising improvement in properties for the composition. Also included are processes for the manufacturing such novel compositions and various end-uses and applications for such compositions.
摘要翻译： 本发明涉及包含（a）单烯基芳烃和共轭二烯的阴离子嵌段共聚物的新型组合物，其中一个嵌段是共聚物嵌段中具有单体特异排列的共轭二烯和单烯基芳烃的受控分布共聚物 ，和（b）定制的软化改性剂具有导致组合物性能惊人改进的特定结构。 还包括用于制造这种新型组合物和各种最终用途和用于这种组合物的方法。
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公开(公告)号：US07138456B2
公开(公告)日：2006-11-21
申请号：US11055317
申请日：2005-02-10
IPC分类号： C08F293/00 , C08F297/00 , C08L53/02
CPC分类号： C09J153/02 , C08F287/00 , C08F297/04 , C08L23/10 , C08L53/02 , C08L53/025 , C08L77/00 , C08L95/00 , C08L101/00 , C08L2666/02 , C08L2666/24 , C09D153/02 , C09D153/025 , C09J153/025 , C08L2666/04 , C08L53/00
摘要： The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.
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公开(公告)号：US5594072A
公开(公告)日：1997-01-14
申请号：US510022
申请日：1995-08-01
CPC分类号： C08G18/69 , C08C19/44 , C08F297/023 , C08F8/04 , C08G18/6208 , C08F2800/20 , C08F2810/40
摘要： Star polymers of isoprene or butadiene having terminal hydroxyl groups have reduced viscosity when the hydroxyl groups are located on polymeric arms that are grown from the core of the star molecules. The polymers are useful in making coatings, sealants, and binders.
摘要翻译： 当羟基位于从星形分子的核心生长的聚合物臂上时，具有末端羟基的异戊二烯或丁二烯的星形聚合物具有降低的粘度。 聚合物可用于制备涂料，密封剂和粘合剂。
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公开(公告)号：US5428114A
公开(公告)日：1995-06-27
申请号：US237497
申请日：1994-05-03
申请人： James R. Erickson , Steven H. Dillman , Dale L. Handlin, Jr. , Carl L. Willis , Robert J. Sutherland
发明人： James R. Erickson , Steven H. Dillman , Dale L. Handlin, Jr. , Carl L. Willis , Robert J. Sutherland
IPC分类号： C09K3/10 , C08C19/06 , C08C19/44 , C08F8/08 , C08F297/02 , C08F297/04 , C08G59/20 , C08G59/34 , C09D153/00 , C09D153/02 , C09D163/00 , C09D163/08 , C09J153/00 , C09J153/02 , C09J163/00 , C08F36/06 , C08F236/06
CPC分类号： C08C19/06 , C08C19/44 , Y10S525/901
摘要： An epoxidized diene star polymer having greater than 4 arms and comprising from 0.05 to 5 Meq of di-, tri- and tetra-substituted olefinic epoxides and the molecular weights of the arms are from 1,500 to 15,000.
摘要翻译： 具有大于4个臂并且包含0.05-5Meq二取代，三取代和四取代烯属环氧化物的环氧化二烯星形聚合物和臂的分子量为1500至15,000。
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公开(公告)号：US5393843A
公开(公告)日：1995-02-28
申请号：US938917
申请日：1992-08-31
申请人： Dale L. Handlin, Jr. , Daniel E. Goodwin , Carl L. Willis , David J. St. Clair , John D. Wilkey , Michael J. Modic , Craig A. Stevens
发明人： Dale L. Handlin, Jr. , Daniel E. Goodwin , Carl L. Willis , David J. St. Clair , John D. Wilkey , Michael J. Modic , Craig A. Stevens
IPC分类号： C08C19/44 , C08F136/06 , C08G18/08 , C08G18/62 , C08G18/81 , C08G63/00 , C08G64/18 , C08G69/00 , C08G81/02 , C08L15/00 , C08L19/00 , C08F8/00
CPC分类号： C08L19/006 , C08C19/44 , C08F136/06 , C08G18/0823 , C08G18/6208 , C08G18/8175 , C08G63/00 , C08G64/18 , C08G69/00 , C08G81/024 , C08L15/00
摘要： Hydrogenated butadiene polymers having terminal functional groups have minimum viscosity at any molecular weight when the 1,2-addition is between 30% and 70%. Hydrogenated butadiene polymers having about two terminal hydroxyl groups per molecule have surprisingly lower viscosities at 30% to 70% 1,2-addition than similar polymers having either higher or lower amounts of 1,2-addition. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要翻译： 具有末端官能团的氢化丁二烯聚合物在1,2-加成量在30％至70％之间时具有任何分子量下的最小粘度。 每分子具有约两个末端羟基的氢化丁二烯聚合物具有比具有更高或更低量1,2-加成的类似聚合物在30％至70％1,2-加成中具有惊人的较低粘度。 聚合物可用于制备涂料，密封剂，粘合剂和与聚酯，聚酰胺和聚碳酸酯的嵌段共聚物。
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公开(公告)号：US5376745A
公开(公告)日：1994-12-27
申请号：US160341
申请日：1993-12-01
IPC分类号： C08F8/04 , C08F36/00 , C08F136/06 , C08F136/08 , C08F4/58 , C08F4/48
CPC分类号： C08F136/06
摘要： The anionic polymerization of isoprene with monolithium initiators and functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--O--A'--Li wherein R.sup.1, R.sup.2, and R.sup.3 are preferably alkyl, alkoxy, aryl, or alkaryl groups having from 1 to 10 carbon atoms, and A' is preferably a branched or straight chain bridging group having at least 2 carbon atoms produces unsaturated and hydrogenated isoprene polymers having high 1,4-addition of the isoprene, from about one to two terminal functional groups per molecule, and low viscosity.
摘要翻译： 具有单键引发剂的异戊二烯和具有结构R1R2R3Si-O-A'-Li的官能化引发剂的异戊二烯的阴离子聚合，其中R1，R2和R3优选为具有1至10个碳原子的烷基，烷氧基，芳基或烷芳基，A 优选具有至少2个碳原子的支链或直链桥连基产生具有异戊二烯高1,4-加成，每分子约1至2个末端官能团和低粘度的不饱和和氢化异戊二烯聚合物。
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