公开(公告)号：US20090267482A1

公开(公告)日：2009-10-29

申请号：US12096555

申请日：2006-12-07

申请人： Naoto Hirosaki

发明人： Naoto Hirosaki

IPC分类号： H01J1/62 ,  H01J29/10 ,  C09K11/79

CPC分类号： C09K11/7734 ,  C04B35/597 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3284 ,  C04B2235/3865 ,  C04B2235/3878 ,  C04B2235/3895 ,  C04B2235/442 ,  C04B2235/445 ,  C04B2235/5409 ,  C04B2235/5445 ,  C04B2235/6562 ,  H01J29/20 ,  H01J2211/42 ,  H01J2329/20 ,  H01L33/502 ,  H01L2224/32245 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00012 ,  H01L2924/00

摘要： A blue phosphor, which has excellent durability and high brightness, and in particular a blue phosphor in a powder state, which can realize high-brightness luminescence upon exposure to an electron beam, are provided. The phosphor being characterized by comprising at least europium incorporated as a solid solution into an inorganic crystal having a crystal structure of an AlN crystal or an AlN solid solution crystal, wherein the phosphor emits divalent europium-derived fluorescence having a peak at a wavelength in the range of 430 nm to 500 nm upon exposure to an excitation source, is provided. In this case, it is more preferable that a predetermined metal element and silicon are incorporated therein. And a manufacturing method to manufacture such phosphor is also provided. Further, a lighting device comprising such blue phosphor is provided.

摘要翻译： 提供了具有优异的耐久性和高亮度的蓝色荧光体，特别是粉末状的蓝色荧光体，其可以在暴露于电子束时实现高亮度发光。 所述荧光体的特征在于至少包含以固溶体形式掺入到具有AlN晶体或AlN固溶体晶体的晶体结构的无机晶体中的铕，其中所述荧光体发射二价铕衍生的荧光，其具有波长为 提供暴露于激发源时的430nm至500nm的范围。 在这种情况下，更优选在其中引入预定的金属元素和硅。 还提供了制造这种荧光体的制造方法。 此外，提供了包括这种蓝色荧光体的照明装置。

公开(公告)号：US20090236969A1

公开(公告)日：2009-09-24

申请号：US11909375

申请日：2006-03-20

申请人： Naoto Hirosaki

发明人： Naoto Hirosaki

IPC分类号： H01J1/62 ,  C09K11/79 ,  C09K11/80 ,  H01J63/04

CPC分类号： C09K11/7721 ,  C04B35/597 ,  C04B35/6262 ,  C04B35/62675 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3229 ,  C04B2235/3865 ,  C04B2235/3878 ,  C04B2235/3895 ,  C04B2235/5409 ,  C04B2235/5445 ,  C04B2235/767 ,  C09K11/0883 ,  H01J2211/42 ,  H01L2224/32245 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

摘要： This invention provides a blue phosphor, which has higher blue brightness and larger half-value width in an emission spectrum as compared with the conventional rare earth-activated sialon phosphor and has better durability as compared with the conventional oxide phosphor. The phosphor comprises a metal element M, wherein M represents Ce, dissolved as a solid solute in a nitride or oxynitride crystal having a β-type Si3N4 crystal structure, an AlN crystal structure, or an AlN polytype structure, and emits fluorescence having a peak in a wavelength region of 450 nm to 500 nm upon exposure to light from an excitation source.

摘要翻译： 本发明提供一种蓝色荧光体，与常规的稀土激活的赛隆荧光体相比，在发光光谱中具有较高的蓝色亮度和较大的半值宽度，并且与常规的氧化物荧光体相比具有更好的耐久性。 磷光体包括金属元素M，其中M表示Ce，作为固体溶质溶解在具有β型Si 3 N 4晶体结构的氮化物或氧氮化物晶体中，AlN晶体结构或AlN多型结构，并且发射具有峰 在从激发源曝光的情况下在450nm至500nm的波长区域中。

公开(公告)号：US20080265748A1

公开(公告)日：2008-10-30

申请号：US12078822

申请日：2008-04-07

申请人： Naoto Hirosaki

发明人： Naoto Hirosaki

IPC分类号： H01J1/62 ,  C01F17/00

CPC分类号： C04B35/597 ,  C04B2235/3224 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3865 ,  C04B2235/3869 ,  C04B2235/3873 ,  C04B2235/3878 ,  C04B2235/3895 ,  C04B2235/5445 ,  C04B2235/761 ,  C04B2235/80 ,  C04B2235/9646 ,  C09K11/7774 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00012

摘要： The invention has for its object the provision of an oxynitride fluorescent material has higher emission luminance than conventional rare earth element-activated sialon fluorescent materials.To this end, an oxynitride fluorescent material is designed in such a way as comprising a JEM phase as a mother crystal and a luminescence center element M1. For instance, the luminescence center element M1 is at least one kind of an element selected from Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. And the JEM phase is expressed as a general formula MA1(Si6-zAlz) N10-zOz (where M indicates a metal element, 0.1≦z≦3).

摘要翻译： 本发明的目的是提供氮氧化物荧光材料具有比常规稀土元素激活的赛隆荧光材料更高的发光亮度。 为此，氮氧化物荧光材料被设计成包括JEM相作为母体晶体和发光中心元件M 1。 例如，发光中心元素M 1是选自Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb中的至少一种元素， 和卢。 并且JEM相以通式MA1（Si 6-z）Al z Z z表示为N 10-z O z， / SUB>（其中M表示金属元素，0.1 <= z <= 3）。

公开(公告)号：US20070210284A1

公开(公告)日：2007-09-13

申请号：US11578783

申请日：2005-04-21

申请人： Naoto Hirosaki ,  Takayoshi Ezuhara ,  Susumu Miyazaki

发明人： Naoto Hirosaki ,  Takayoshi Ezuhara ,  Susumu Miyazaki

IPC分类号： H01L33/00 ,  C09K11/77

CPC分类号： C09K11/7774 ,  C09K11/0883 ,  H01L33/502

摘要： Disclosed is a phosphor containing a nitrogen atom, a compound having a garnet structure and an activating agent. The activating agent is composed of at least one element selected from the group consisting of Ce, Pr, Nd, Eu, Tb, Dy, Ho, Er, Tm, Yb and Mn.

摘要翻译： 公开了含有氮原子的荧光体，具有石榴石结构的化合物和活化剂。 活化剂由选自Ce，Pr，Nd，Eu，Tb，Dy，Ho，Er，Tm，Yb和Mn中的至少一种元素组成。

公开(公告)号：US20060226764A1

公开(公告)日：2006-10-12

申请号：US11402580

申请日：2006-04-10

申请人： Kiyoshi Tamura ,  Naoto Hirosaki

发明人： Kiyoshi Tamura ,  Naoto Hirosaki

IPC分类号： H01J1/62

CPC分类号： C09K11/0883 ,  C09K11/642 ,  C09K11/7734 ,  C09K11/7774 ,  H01J29/20

摘要： A fluorescence emitting device is provided using a phosphor emitting a light by bombardment of an electron beam and having excellent luminance lifetime. The electron beam excited phosphor comprises a solid solution prepared by an AIN crystal or AIN solid solution crystal formed with at least Eu, Si and oxygen represented by the composition formula Eua AIb Sic Nd Oe[Wherein a+b+c+d+e=1, and a, b, c, d and e satisfy the following conditions: 0.00001≦a≦0.1 0.4≦b≦0.55 0.001≦c≦0.1 0.4≦d≦0.55 0.001≦e≦0.1]

摘要翻译： 使用通过轰击电子束发射光并且具有优异的亮度寿命的荧光体来提供荧光发射装置。 电子束激发的荧光体包括通过由至少由Eu，Si和氧组成的AlN晶体或AIN固溶体晶体制备的固溶体，其由组成式Eua Alb Sic Nd Oe表示[其中a + b + c + d + e = 1，a，b，c，d和e满足以下条件：0.00001 <= a <= 0.1 0.4 <= b <= 0.55 0.001 <= c <= 0.1 0.4 <= d <= 0.55 0.001 <= e < = 0.1]

公开(公告)号：US09512358B2

公开(公告)日：2016-12-06

申请号：US13983762

申请日：2012-02-03

申请人： Naoto Hirosaki ,  Ryo Yoshimatsu ,  Shintaro Watanabe

发明人： Naoto Hirosaki ,  Ryo Yoshimatsu ,  Shintaro Watanabe

IPC分类号： C09K11/64 ,  C09K11/77 ,  C09K11/08 ,  F21V9/16 ,  H01L33/50

CPC分类号： C09K11/7731 ,  C09K11/0883 ,  C09K11/7734 ,  F21V9/30 ,  H01L33/502

摘要： A phosphor with a high light-emitting intensity and indicated by general formula MeaRebSicAldNeOf. Me has Sr as an essential element thereof and can include one or more types of element selected from Na, Li, Mg, Ca, Ba, Sc, Y, and La. Re has Eu as an essential element thereof and can include one or more types of element selected from Mn, Ce, Tb, Yb, and Sm. When composition ratios a, b, c, d, e, and f fulfill a=1−x, b=x, c=(2+2p)×(1−y), d=(2+2p)×y, e=(1+4p)×(1−z), and f=(1+4p)×z, parameters p, x, y, and z fulfill the following: 1.630

摘要翻译： 具有高发光强度并由通式MeaRebSicAldNeOf表示的荧光体。 Me具有Sr作为其必需元素，可以包括选自Na，Li，Mg，Ca，Ba，Sc，Y和La中的一种或多种元素，Re具有Eu作为其必需元素，并且可以包括一种或多种 选自Mn，Ce，Tb，Yb和Sm的元素类型。 当组成比a，b，c，d，e和f满足a = 1-x，b = x，c =（2 + 2p）×（1-y），d =（2 + 2p） e =（1 + 4p）×（1-z），f =（1 + 4p）×z，参数p，x，y和z满足以下要求：1.630

公开(公告)号：US08946981B2

公开(公告)日：2015-02-03

申请号：US13818975

申请日：2011-08-26

申请人： Naoto Hirosaki ,  Takahashi Takeda ,  Tatsuya Horie

发明人： Naoto Hirosaki ,  Takahashi Takeda ,  Tatsuya Horie

IPC分类号： C09K11/77 ,  C09K11/08 ,  H01J1/63

CPC分类号： C09K11/7787 ,  C09K11/0883 ,  C09K11/7706 ,  H01J1/63

摘要： A phosphor substituting the conventional sialon phosphor or oxide phosphor activated by rare earth and an application thereof are provided. The phosphor of the present invention comprises an inorganic crystal including at least La, Si, Al, N (nitrogen), M element (M is at least one kind of element selected from the group consisting of Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb), and O (oxygen) if necessary and the inorganic crystal is a host crystal, which is LaSi9Al19N32 crystal or a solid-solution crystal thereof, activated by the M element.

摘要翻译： 提供了替代由稀土活化的传统赛隆荧光体或氧化物荧光体的荧光体及其应用。 本发明的荧光体包括至少包含La，Si，Al，N（氮），M元素的无机晶体（M是选自Ce，Pr，Nd，Sm，Eu中的至少一种元素 ，Gd，Tb，Dy，Ho，Er，Tm和Yb）和O（氧），无机晶体是由M元素活化的LaSi9Al19N32晶体或其固溶体晶体的主晶体。

公开(公告)号：US08928005B2

公开(公告)日：2015-01-06

申请号：US13381348

申请日：2010-07-02

申请人： Kenichi Yoshimura ,  Kohsei Takahashi ,  Hiroshi Fukunaga ,  Naoto Hirosaki

发明人： Kenichi Yoshimura ,  Kohsei Takahashi ,  Hiroshi Fukunaga ,  Naoto Hirosaki

IPC分类号： H01L33/00

CPC分类号： H01L33/504 ,  C09K11/7721 ,  C09K11/7734 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00012 ,  H01L2924/00014

摘要： A semiconductor light-emitting device that is high in luminous efficiency and that emits light which is high in color rendering property includes a semiconductor light-emitting element that emits blue light; a green fluorescent substance that absorbs the blue light and emits green light; and an orange fluorescent substance that absorbs the blue light and emits orange light, fluorescence emitted by the green fluorescent substance and the orange fluorescent substance having an emission spectrum that has a peak wavelength of not less than 540 nm and not more than 565 nm and that satisfies the relation of 0.70>PI(90)/PI(MAX)>0.55, where PI(MAX) represents an emission intensity at the peak wavelength, and PI(90) represents an emission intensity at a wavelength 90 nm longer than the peak wavelength.

摘要翻译： 发光效率高，发光性高的半导体发光元件包括：发出蓝色光的半导体发光元件; 吸收蓝光并发出绿光的绿色荧光物质; 以及吸收蓝色光并发出橙色光的橙色荧光物质，由绿色荧光物质发出的荧光和具有峰值波长不低于540nm且不大于565nm的发射光谱的橙色荧光物质，并且 满足0.70> PI（90）/ PI（MAX）> 0.55的关系，其中PI（MAX）表示峰值波长处的发射强度，PI（90）表示比峰值长90nm的发射强度 波长。

公开(公告)号：US08508119B2

公开(公告)日：2013-08-13

申请号：US11178363

申请日：2005-07-12

申请人： Ken Sakuma ,  Koji Omichi ,  Naoki Kimura ,  Masakazu Ohashi ,  Daiichiro Tanaka ,  Naoto Hirosaki

发明人： Ken Sakuma ,  Koji Omichi ,  Naoki Kimura ,  Masakazu Ohashi ,  Daiichiro Tanaka ,  Naoto Hirosaki

IPC分类号： H01J1/62 ,  C09K11/02

CPC分类号： C09K11/7734 ,  C04B35/597 ,  C04B35/6261 ,  C04B35/6262 ,  C04B35/62695 ,  C04B35/645 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3865 ,  C04B2235/3878 ,  C04B2235/442 ,  C04B2235/5427 ,  C09K11/0883 ,  H01L33/502 ,  H01L2224/32245 ,  H01L2224/32257 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2224/8592 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

摘要： An incandescent lamp color light emitting diode lamp comprises a semiconductor blue light emitting diode chip having a center emission wavelength in a range of from 400 nm to 480 nm and a phosphor that absorbs light emitted from the diode chip to emit light having a different wavelength than the light emitted from the diode chip. The phosphor is represented by a general formula of Mp(Si, Al)12(O, N)16:Eu2+q. The main phase is an α-SiAlON phosphor having an α SiAlON structure, wherein M is at least one element of Ca, Y, Mg, Li, Sc, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Sr and p is from 0.75 to 1.0; and q is between 0.02 and 0.09. The diode lamp emits light having an emission color produced by a mixture of the light emitted from the semiconductor blue light emitting and the light emitted from the α-SiAlON. The chromaticity range thereof falls within the range defined by chromaticity coordinates (x, y) of (0.4775, 0.4283), (0.4594, 0.3971), (0.4348, 0.4185), and (0.4214, 0.3887) on the XYZ chromaticity diagram.

摘要翻译： 白炽灯彩色发光二极管灯包括具有400nm至480nm范围内的中心发射波长的半导体蓝色发光二极管芯片和吸收从二极管芯片发射的光以发射具有不同波长的光的荧光体 从二极管芯片发出的光。 荧光体由通式Mp（Si，Al）12（O，N）16：Eu 2+ +表示。 主相是具有αSiAlON结构的α-SiAlON荧光体，其中M是Ca，Y，Mg，Li，Sc，Pr，Nd，Pm，Sm，Gd，Tb，Dy，Ho，Er中的至少一种元素 ，Tm，Yb，Lu和Sr，p为0.75〜1.0; q在0.02和0.09之间。 二极管灯发射具有由半导体蓝光发射的光和从α-SiAlON发射的光的混合产生的发射颜色的光。 其色度范围落在由XYZ色度图上的（0.4775,0.4283），（0.4594,0.3971），（0.4348,0.4185）和（0.4214,0.3887）的色度坐标（x，y）定义的范围内。

公开(公告)号：US20130147341A1

公开(公告)日：2013-06-13

申请号：US13818975

申请日：2011-08-26

申请人： Naoto Hirosaki ,  Takahashi Takeda ,  Tatsuya Horie

发明人： Naoto Hirosaki ,  Takahashi Takeda ,  Tatsuya Horie

IPC分类号： C09K11/77 ,  H01J1/63

CPC分类号： C09K11/7787 ,  C09K11/0883 ,  C09K11/7706 ,  H01J1/63

摘要： A phosphor substituting the conventional sialon phosphor or oxide phosphor activated by rare earth and an application thereof are provided. The phosphor of the present invention comprises an inorganic crystal including at least La, Si, Al, N (nitrogen), M element (M is at least one kind of element selected from the group consisting of Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb), and O (oxygen) if necessary and the inorganic crystal is a host crystal, which is LaSi9Al19N32 crystal or a solid-solution crystal thereof, activated by the M element.

摘要翻译： 提供了替代由稀土活化的传统赛隆荧光体或氧化物荧光体的荧光体及其应用。 本发明的荧光体包括至少包含La，Si，Al，N（氮），M元素的无机晶体（M是选自Ce，Pr，Nd，Sm，Eu中的至少一种元素 ，Gd，Tb，Dy，Ho，Er，Tm和Yb）和O（氧），无机晶体是由M元素活化的LaSi9Al19N32晶体或其固溶体晶体的主晶体。