Abstract:
A nonaqueous electrolyte secondary battery includes a flat wound electrode assembly and a ease that houses the wound electrode assembly and a nonaqueous electrolyte, the wound electrode assembly including a positive electrode plate, a negative electrode plate, and a separator, the positive electrode plate and the negative electrode plate being wound with the separator provided therebetween. The wound electrode assembly has a width-to-height ratio of 2 or more. The nonaqueous electrolyte contains lithium bis(oxalato)borate and lithium fluorosulfonate.
Abstract:
A nonaqueous electrolyte secondary battery includes a pressure-sensitive current interrupt mechanism, and a flat wound electrode body that is inserted in an outer casing with a winding axis of the flat wound electrode body arranged to extend in a horizontal direction. A positive electrode plate, a negative electrode plate, and a separator in a winding end portion of the flat wound electrode body are all directed toward a top side.
Abstract:
To provide with high productivity a non-aqueous electrolyte secondary battery having high capacity.The present invention is a non-aqueous electrolyte secondary battery provided with an electrode assembly and a non-aqueous electrolyte including a non-aqueous solvent, the electrode assembly including a positive electrode and a negative electrode. In the positive electrode, a positive electrode active material layer is formed on a positive electrode core. In the non-aqueous electrolyte secondary battery, the non-aqueous solvent includes 30 to 70 vol % ethylene carbonate at 25° C. and 1 atm, the non-aqueous electrolyte includes lithium bis(oxalato)borate, and the packing density of the positive electrode active material layer is from 2.0 to 2.8 g/ml.
Abstract:
A nonaqueous electrolyte secondary battery includes: a stacked electrode assembly formed by stacking a plurality of layers of a positive electrode plate and a plurality of layers of a negative electrode plate with a separator interposed therebetween; a nonaqueous electrolyte; and an aluminum laminated outer body that stores the stacked electrode assembly and into which the electrolyte is poured. The positive electrode plate contains a positive electrode active material. The negative electrode plate contains a negative electrode active material. The nonaqueous electrolyte contains LiBOB (lithium bis(oxalato)borate) and/or a boron-containing substance derived from the LiBOB. The aluminum laminated outer body has an outer surface area of 300 cm2 or larger. The battery has a capacity of 10 Ah or more.
Abstract:
A nonaqueous electrolyte secondary battery according to an embodiment of the present invention includes an electrode assembly, a nonaqueous electrolyte, and a container. The electrode assembly has a positive electrode, a negative electrode, and a separator. The positive electrode contains particles of a lithium transition metal compound as a positive electrode active material. The negative electrode is opposed to the positive electrode. The separator is disposed between the positive electrode and the negative electrode. The nonaqueous electrolyte contains lithium difluorophosphate. The container houses the electrode assembly and the nonaqueous electrolyte. The battery capacity is not less than 21 Ah. The mean particle diameter (D50) of the particles of the lithium transition metal compound is not less than 5 μm and not more than 15 μm. The (D90−D10)/D50 of the particles of the lithium transition metal compound is under 1.1.
Abstract:
A nonaqueous electrolyte secondary battery includes: a stacked electrode assembly formed by stacking a plurality of layers of a positive electrode plate and a plurality of layers of a negative electrode plate with a separator interposed therebetween; a nonaqueous electrolyte formed by dissolving LiPF6 at 1.5 mol/L into a mixed solvent of EC, EMC, and DMC; and an aluminum laminated outer body that stores the stacked electrode assembly and into which the electrolyte is poured. The ratio of the EC, the EMC, and the DMC is 36% by volume, 31% by volume, and 33% by volume, respectively, to the total amount of the mixed solvent. The nonaqueous electrolyte contains LiPF2O2.
Abstract:
A nonaqueous electrolyte secondary battery includes: a stacked electrode assembly formed by stacking a plurality of layers of a positive electrode plate and a plurality of layers of a negative electrode plate with a separator interposed therebetween; a nonaqueous electrolyte formed by dissolving LiPF6 into a mixed solvent; and an aluminum laminated outer body that stores the stacked electrode assembly and into which the electrolyte is poured. The nonaqueous electrolyte contains LiBOB and LiPF2O2. Each of the positive electrode plate and the negative electrode plate has an area of 100 cm2 or larger. The stacked electrode assembly has a thickness in the stacking direction of 10 mm or smaller.
Abstract:
To provide a non-aqueous electrolyte secondary battery having high capacity and superior safety.The present invention is a non-aqueous electrolyte secondary including having a wound electrode assembly of a positive electrode, negative electrode and separator housed in an outer can having both a bottom and an opening, the opening being sealed by a sealing plate. This non-aqueous electrolyte secondary battery is characterized in that the battery further comprises a current interrupt device activated by rising pressure inside the battery, the bottom surface of the outer can is parallel to the direction of the winding axis of the wound electrode assembly, the thickness of the negative electrode at a state of charge of 100% is equal to or less than 130% of the thickness of the negative electrode at the time of battery assembly, the maximum width of the wound electrode assembly perpendicular to the winding axis direction during assembly is from 90 to 98% of the distance from the bottom surface of the outer can to the current interrupt device, and the battery capacity of the non-aqueous electrolyte secondary battery is equal to or greater than 4 Ah.
Abstract:
A method for manufacturing a nonaqueous electrolyte secondary battery including a current interruption mechanism that interrupts electric current includes disposing, in the outer body, an electrode assembly and a nonaqueous electrolyte containing a compound having at least one of a cyclohexyl group and a phenyl group, adjusting the nonaqueous electrolyte to contain the compound having at least one of a cyclohexyl group and a phenyl group in an amount of from 2.5 g/m2 to 5.0 g/m2 with respect to a formation area of a positive electrode active material layer on a positive electrode substrate surface, and thereafter performing aging treatment at 60° C. or more at a state of charge of 60% or more. This battery exhibits excellent output characteristics in a low temperature condition and can sufficiently ensure reliability even when the battery is overcharged through two-step charging in a low temperature condition.
Abstract translation:包括具有中断电流的电流中断机构的非水电解质二次电池的制造方法包括在外体中设置电极组件和含有具有环己基和苯基中的至少一个的化合物的非水电解质,调整 含有相对于正极上的正极活性物质层的形成面积为2.5g / m 2〜5.0g / m 2的环己基和苯基中的至少一种的化合物的非水电解质 基板表面,然后在60%以上的电荷下进行60℃以上的时效处理。 该电池在低温条件下表现出优异的输出特性,并且即使当在低温条件下通过两步充电来对电池进行过充电时也可充分确保可靠性。