公开(公告)号：US20110076736A1

公开(公告)日：2011-03-31

申请号：US12992532

申请日：2009-05-14

申请人： Ryuhei Matsumoto ,  Masaya Kakuta ,  Hideki Sakai ,  Yuichi Tokita

发明人： Ryuhei Matsumoto ,  Masaya Kakuta ,  Hideki Sakai ,  Yuichi Tokita

IPC分类号： C12N11/04 ,  H01M8/16 ,  H01M4/88 ,  H01M4/90

CPC分类号： H01M8/16 ,  H01M2300/0005 ,  Y02E60/527 ,  Y02P70/56

摘要： A fuel cell and a method for manufacturing the same are provided, wherein at least one type of enzyme and coenzyme are confined in a minute space, an enzyme reaction is effected while this space serves as a reaction field. Thereby, electrons can be taken out of the fuel efficiently to generate electrical energy, and immobilization of these enzyme and coenzyme on an electrode can be performed easily. The enzyme and the coenzyme required for an enzyme reaction are encapsulated in a liposome, and the resulting liposome is immobilized on the surface of an electrode formed from porous carbon or the like so as to form an enzyme immobilization electrode. A transporter is incorporated in the liposome, as necessary. An electron mediator is also immobilized on the surface of the electrode. The resulting enzyme immobilization electrode is used as, for example, a negative electrode of a biofuel cell.

摘要翻译： 提供燃料电池及其制造方法，其中至少一种类型的酶和辅酶被限制在微小的空间中，在该空间用作反应场的同时进行酶反应。 由此，能够有效地将电子从燃料中取出来产生电能，能够容易地将这些酶和辅酶固定在电极上。 将酶反应所需的酶和辅酶封装在脂质体中，将得到的脂质体固定在由多孔碳等形成的电极的表面上，形成酶固定化电极。 根据需要将转运体并入脂质体。 电子介体也固定在电极的表面上。 所得的酶固定电极例如用作生物燃料电池的负极。

公开(公告)号：US20120000788A1

公开(公告)日：2012-01-05

申请号：US13254518

申请日：2010-03-02

申请人： Ryuhei Matsumoto ,  Yoshio Goto ,  Hideki Sakai ,  Yuichi Tokita

发明人： Ryuhei Matsumoto ,  Yoshio Goto ,  Hideki Sakai ,  Yuichi Tokita

IPC分类号： C25B3/00

CPC分类号： H01M8/16 ,  C12Q1/004 ,  C12Q1/32 ,  Y02E60/527

摘要： An electrolytic method of a fuel capable of suppressing reverse reaction of an enzyme and improving electrolytic rate is provided. In electrolyzing a fuel such as glucose by using an enzyme/electron mediator obtained by immobilizing an enzyme such as gluconate-5-dehydrogenase, alcohol dehydrogenase, and malate dehydrogenase and an electron mediator onto a porous electrode made of a carbon material, electrode reaction is generated only in the enzyme/electron mediator electrode.

摘要翻译： 提供了能够抑制酶的逆反应并提高电解率的燃料的电解方法。 通过使用通过将诸如葡萄糖酸-5-脱氢酶，醇脱氢酶和苹果酸脱氢酶等酶等的酶/电子传递体和电子介体电解到由碳材料制成的多孔电极上来电解葡萄糖等燃料，电极反应为 仅在酶/电子介体电极中产生。

公开(公告)号：US07955741B2

公开(公告)日：2011-06-07

申请号：US11570113

申请日：2005-06-07

申请人： Hideki Sakai ,  Takashi Tomita ,  Atsushi Sato ,  Yuichi Tokita

发明人： Hideki Sakai ,  Takashi Tomita ,  Atsushi Sato ,  Yuichi Tokita

IPC分类号： H01M4/90 ,  H01M4/60

CPC分类号： H01M4/9008 ,  H01M4/8846 ,  H01M4/9083 ,  H01M8/16 ,  Y02E60/527

摘要： A fuel cell which can directly extract electric power from a polysaccharide, such as starch, is provided. A fuel electrode is formed by immobilizing with an immobilizer, on an electrode comprised of, e.g., carbon, an enzyme responsible for decomposing a polysaccharide into monosaccharides, an enzyme responsible for decomposing the monosaccharide formed, a coenzyme (e.g., NAD+ or NADP+) which forms a reductant due to the oxidation reaction in the monosaccharide decomposition process, a coenzyme oxidase (e.g., diaphorase) for oxidizing the reductant of the coenzyme (e.g., NADH or NADPH), and an electron mediator (e.g., ACNQ or vitamin K3) for receiving electrons generated due to the oxidation of the coenzyme from the coenzyme oxidase and delivering the electrons to the electrode. The fuel cell comprises the fuel electrode and the air electrode that sandwich an electrolyte layer.

摘要翻译： 提供了可以直接从诸如淀粉等多糖提取电力的燃料电池。 燃料电极通过固定器固定在由例如碳组成的电极上，负责将多糖分解为单糖的酶，负责分解形成的单糖的酶，辅酶（例如，NAD +或NADP +），其形成 由于单糖分解过程中的氧化反应形成还原剂，用于氧化辅酶（例如NADH或NADPH）的还原剂的辅酶氧化酶（例如，黄体酶）和电子介体（例如ACNQ或维生素K3），用于 接收由辅酶氧化辅酶产生的电子，并将电子输送到电极。 燃料电池包括燃料电极和夹着电解质层的空气电极。

公开(公告)号：US20110059374A1

公开(公告)日：2011-03-10

申请号：US12921868

申请日：2009-03-02

申请人： Hideyuki Kumita ,  Yoshio Goto ,  Takaaki Nakagawa ,  Hideki Sakai ,  Hiroki Mita ,  Ryuhei Matsumoto ,  Yuichi Tokita

发明人： Hideyuki Kumita ,  Yoshio Goto ,  Takaaki Nakagawa ,  Hideki Sakai ,  Hiroki Mita ,  Ryuhei Matsumoto ,  Yuichi Tokita

IPC分类号： H01M8/16

CPC分类号： H01M8/16 ,  Y02E60/527

摘要： A fuel cell having excellent properties is provided in which, when an enzyme is immobilized in at least one of a positive electrode and a negative electrode, a sufficient buffering capability can be provided even in a high power output operation and the inherent capability of the enzyme can be sufficiently exerted. In a biofuel cell including a structure in which a positive electrode 2 and a negative electrode 1 face each other with an electrolyte layer 3 therebetween, the electrolyte layer 3 containing a buffer material, and the biofuel cell including an enzyme immobilized in at least one of the positive electrode 2 and the negative electrode 1, the electrolyte layer 3 contains a compound including an imidazole ring as a buffer material and at least one acid selected from the group consisting of acetic acid, phosphoric acid, and sulfuric acid is further added to the electrolyte layer 3. As the compound including an imidazole ring, imidazole, 1-methylimidazole, 2-methylimidazole, 4-methylimidazole, 2-ethylimidazole, or the like is used.

摘要翻译： 提供一种具有优异特性的燃料电池，其中当酶固定在正电极和负电极中的至少一个中时，即使在高功率输出操作和酶的固有能力下也可以提供足够的缓冲能力 可以充分发挥。 在包括其间具有电解质层3的正极2和负极1彼此面对的结构的生物燃料电池中，包含缓冲材料的电解质层3和包含固定在以下的至少一个中的酶的生物燃料电池 正极2和负极1，电解质层3含有包含咪唑环作为缓冲材料的化合物，并且还将至少一种选自乙酸，磷酸和硫酸的酸加入到 作为包含咪唑环的化合物，可以使用咪唑，1-甲基咪唑，2-甲基咪唑，4-甲基咪唑，2-乙基咪唑等。

公开(公告)号：US20100310946A1

公开(公告)日：2010-12-09

申请号：US12745603

申请日：2008-11-19

申请人： Hideki Sakai ,  Takaaki Nakagawa ,  Masaya Kakuta ,  Yuichi Tokita

发明人： Hideki Sakai ,  Takaaki Nakagawa ,  Masaya Kakuta ,  Yuichi Tokita

IPC分类号： H01M8/06

CPC分类号： H01M4/86 ,  H01M8/04186 ,  H01M8/16 ,  Y02E60/527

摘要： To provide a fuel cell that can perform efficient power generation through a simple fuel supply. There is provided a fuel cell that generates electricity through progress of an oxidation-reduction reaction using an enzyme as a catalyst, the fuel cell including at least a fuel-vaporizing layer formed through vaporization of a fuel; an anode to which a vaporized fuel is supplied from the fuel-vaporizing layer; and a cathode connected to the anode in a state in which protons can be conducted. In the fuel cell, since a fuel is supplied to an electrode in a vaporized state, a vaporized fuel is supplied to an inner portion of the electrode and a reaction sufficiently proceeds at the inner surface of the electrode, which can achieve high output due to efficient power generation. Furthermore, even if an enzyme or the like is immobilized on an electrode, the enzyme or the like can be prevented from leaching out into a liquid fuel because a fuel is supplied to the electrode in a vaporized state, which can prevent a decrease in the output caused by leaching out of the enzyme or the like.

摘要翻译： 提供能够通过简单的燃料供给来实现高效发电的燃料电池。 提供了一种通过使用酶作为催化剂进行氧化还原反应而发电的燃料电池，所述燃料电池至少包括通过燃料蒸发形成的燃料蒸发层; 从燃料汽化层供给汽化燃料的阳极; 以及在可以导电质子的状态下连接到阳极的阴极。 在燃料电池中，由于向蒸发状态的电极供给燃料，所以向电极的内部供给汽化燃料，在电极的内表面充分进行反应，由此可以实现高输出 高效发电。 此外，即使将酶等固定在电极上，也可以防止由于向蒸发状态的电极供给燃料而使酶等浸出到液体燃料中，从而能够防止 通过从酶等浸出而产生的输出。

公开(公告)号：US08952357B2

公开(公告)日：2015-02-10

申请号：US13148548

申请日：2010-02-08

申请人： Seiji Yamada ,  Yuichi Tokita ,  Yoshio Goto ,  Wei Luo ,  Daisuke Yamaguchi ,  Daisuke Ito ,  Jusuke Shimura

发明人： Seiji Yamada ,  Yuichi Tokita ,  Yoshio Goto ,  Wei Luo ,  Daisuke Yamaguchi ,  Daisuke Ito ,  Jusuke Shimura

IPC分类号： H01L29/08 ,  H01L51/00 ,  B82Y10/00 ,  G01J1/58 ,  H01L27/30 ,  H01L51/42

CPC分类号： H01L51/0093 ,  B82Y10/00 ,  G01J1/58 ,  H01L27/307 ,  H01L51/0012 ,  H01L51/0051 ,  H01L51/0083 ,  H01L51/0092 ,  H01L51/0098 ,  H01L51/42 ,  Y10T428/31685 ,  Y10T428/31768

摘要： A color imaging element, a photosensor and a photoelectric transducer which use a protein and are capable of being stably used for a long time, and methods of manufacturing them are provided. A zinc-substituted cytochrome c552 is immobilized on a gold electrode with a self-assembled monolayer in between to form a blue-light photoelectric transducer. Alternatively, a cytochrome c552 is immobilized on a gold electrode with a self-assembled monolayer in between, and a fluorescent protein absorbing blue light is bonded to the cytochrome c552, thereby forming a blue-light photoelectric transducer. These photoelectric transducers each are used as a color imaging element or a blue-light photoelectric transducer of a photosensor.

摘要翻译： 提供使用蛋白质并能够长期稳定使用的彩色成像元件，光传感器和光电传感器及其制造方法。 将锌取代的细胞色素c552固定在具有自组装单层的金电极之间，形成蓝光光电传感器。 或者，细胞色素c552固定在金电极上，其间具有自组装单层，吸收蓝光的荧光蛋白质结合到细胞色素c552上，从而形成蓝光光电变换器。 这些光电传感器各自用作光电传感器的彩色成像元件或蓝光光电传感器。

公开(公告)号：US08884899B2

公开(公告)日：2014-11-11

申请号：US13474197

申请日：2012-05-17

申请人： Wei Luo ,  Yuichi Tokita ,  Yoshio Goto ,  Seiji Yamada ,  Satoshi Nakamaru

发明人： Wei Luo ,  Yuichi Tokita ,  Yoshio Goto ,  Seiji Yamada ,  Satoshi Nakamaru

IPC分类号： G06F3/041 ,  G06F3/042 ,  G02B27/00 ,  G02B27/22

CPC分类号： G02B27/0093 ,  G02B27/22 ,  G06F3/0412 ,  G06F3/042 ,  G06F3/0425

摘要： Provided is a thin three-dimensional interactive display which enables multi-touch sensing and three-dimensional gesture recognition. The three-dimensional interactive display includes a light source for irradiating an object to be detected with a light, a light modulation layer, into which a scattered light generated by irradiating the object with the light from the light source enters, at least for modulating an intensity of the scattered light, a transparent light-receiving layer for receiving the light transmitted through the light modulation layer, and a display panel or a back light panel disposed on the opposite side of the transparent light-receiving layer from the light modulation layer. The transparent light-receiving layer has a two-dimensional array of light-receiving elements.

摘要翻译： 提供了一种薄的三维交互式显示器，其实现多点触摸感测和三维手势识别。 三维交互式显示器包括用于用光照射待检测物体的光源，光调制层，其中通过用来自光源的光进入的物体照射物体而产生的散射光至少用于调制 散射光的强度，用于接收透过光调制层的光的透明光接收层和从光调制层设置在透明光接收层的相反侧的显示面板或背光面板。 透明光接收层具有受光元件的二维阵列。

公开(公告)号：US08178872B2

公开(公告)日：2012-05-15

申请号：US12756555

申请日：2010-04-08

申请人： Yuichi Tokita ,  Yoshio Goto ,  Jusuke Shimura ,  Seiji Yamada ,  Wei Luo ,  Daisuke Yamaguchi ,  Daisuke Ito

发明人： Yuichi Tokita ,  Yoshio Goto ,  Jusuke Shimura ,  Seiji Yamada ,  Wei Luo ,  Daisuke Yamaguchi ,  Daisuke Ito

IPC分类号： H01L29/08 ,  H01L35/24 ,  H01L51/00

CPC分类号： H01L51/0595 ,  B82Y10/00 ,  H01L51/0093 ,  H01L51/4206

摘要： A molecular device includes a gold electrode, cytochrome c552 or a derivative or variant thereof immobilized on the gold electrode, and an electron transfer protein coupled to the cytochrome c552 or the derivative or variant thereof. Electrons or holes, or both, are transferred through the electron transfer protein by transition of electrons between molecular orbitals of the electron transfer protein.

摘要翻译： 分子装置包括固定在金电极上的金电极，细胞色素c552或其衍生物或变体，以及与细胞色素c552或其衍生物或变体偶联的电子转移蛋白。 通过电子在电子转移蛋白的分子轨道之间的转变，电子或空穴或两者通过电子转移蛋白转移。

公开(公告)号：US20090117638A1

公开(公告)日：2009-05-07

申请号：US11946543

申请日：2007-11-28

申请人： Hideyuki Kumita ,  Yuichi Tokita ,  Yoshio Goto

发明人： Hideyuki Kumita ,  Yuichi Tokita ,  Yoshio Goto

IPC分类号： C12N9/02

CPC分类号： C12N9/001 ,  C12Y103/03005

摘要： A heat-resistant bilirubin oxidase mutant is disclosed. The bilirubin oxidase is obtained by deletion, replacement, addition or insertion of at least one amino acid residue of a wild type amino sequence of SEQ. ID. No. 1 of a bilirubin oxidase derived from an imperfect filamentous fungus, Myrothecium verrucaria.

摘要翻译： 公开了一种耐热性胆红素氧化酶突变体。 通过SEQ ID NO：1的野生型氨基酸序列的至少一个氨基酸残基的缺失，置换，添加或插入获得胆红素氧化酶。 ID。 来自不完美丝状真菌的红霉素氧化酶的1号。

公开(公告)号：US20050276748A1

公开(公告)日：2005-12-15

申请号：US10524514

申请日：2003-08-22

申请人： Hiroyuki Morioka ,  Atsuo Yamada ,  Go Sudo ,  Koji Inomata ,  Yuichi Tokita

发明人： Hiroyuki Morioka ,  Atsuo Yamada ,  Go Sudo ,  Koji Inomata ,  Yuichi Tokita

IPC分类号： C01B3/06 ,  H01M8/06

CPC分类号： C01B3/065 ,  H01M8/065 ,  Y02E60/362

摘要： A method for generating hydrogen gas, an apparatus for producing hydrogen gas, and an energy conversion system, which are so designed as to generate hydrogen extremely efficiently without the help of catalyst are provided. The hydrogen gas is generated by decomposing a metal hydride in a mixture composed of said metal hydride, water, and a second solution which has a pH value lower than that of the aqueous solution of said metal hydride wherein the metal hydride is represented by a formula: αz(1-x)βzx[BHy], where α and β are mutually different elements selected from Groups 1A, 2A, and 2B of the periodic table; and x, y, and z are defined respectively by 0≦x≦1, 3

摘要翻译： 本发明提供一种生成氢气的方法，氢气的制造装置和能量转换系统，其特征在于能够非常有效地在无需催化剂的帮助下产生氢气。 通过在由所述金属氢化物，水和pH值低于所述金属氢化物的水溶液的第二溶液组成的混合物中分解金属氢化物而产生氢气，其中金属氢化物由式 其中α和β是选自1A，2A组中的相互不同的元素，其中α和β是相互不同的元素，其选自1A，2A， ，和2B的周期表; x，y和z分别由0 <= x <= 1,3，