公开(公告)号：US09096616B2

公开(公告)日：2015-08-04

申请号：US13542971

申请日：2012-07-06

Applicant: Natalia Trukhan ,  Ulrich Müller

Inventor： Natalia Trukhan ,  Ulrich Müller

IPC: C07F3/06

CPC classification number: C07F3/06

Abstract: Described is a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is a zinc ion and the at least one at least bidentate organic compound is based on 2-methylimidazole, which comprises the steps (a) addition of a first water-based solution comprising zinc ions to a second water-based solution comprising 2-methylimidazole, with a suspension being formed after addition of the second solution; (b) addition of a third solution comprising a strong base to the suspension formed in step (a).

Abstract translation: 描述了一种制备多孔金属 - 有机骨架的方法，所述多孔金属 - 有机骨架包含至少一种与至少一种金属离子配位的至少二齿有机化合物，其中所述至少一种金属离子是锌离子，并且所述至少一种至少二齿有机化合物 是基于2-甲基咪唑，其包括以下步骤：（a）在包含2-甲基咪唑的第二水性溶液中加入包含锌离子的第一水性溶液，在加入第二溶液后形成悬浮液; （b）向步骤（a）中形成的悬浮液中加入包含强碱的第三溶液。

公开(公告)号：US08609879B2

公开(公告)日：2013-12-17

申请号：US12837962

申请日：2010-07-16

Applicant: Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baβler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

Inventor： Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baβler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

IPC: C07C255/00

CPC classification number: C07D301/12 ,  B01D17/0208 ,  B01D17/047 ,  Y02P20/582

Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.

Abstract translation: 一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯 ：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

公开(公告)号：US08524932B2

公开(公告)日：2013-09-03

申请号：US13249943

申请日：2011-09-30

Applicant: Emi Leung ,  Ulrich Müller ,  Natalia Trukhan ,  Hendrick Mattenheimer ,  Gerhard Cox ,  Stefan Blei

Inventor： Emi Leung ,  Ulrich Müller ,  Natalia Trukhan ,  Hendrick Mattenheimer ,  Gerhard Cox ,  Stefan Blei

IPC: C07F5/06

CPC classification number: C07F5/069

Abstract: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

Abstract translation: 本发明涉及一种制备多孔金属 - 有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其中所述至少一种金属离子基于铝离子，并且所述至少一种 至少二齿有机化合物是基于富马酸，在至少一种碱的存在下，在至少一种碱的存在下，在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。 至100℃，绝对压力不超过2巴0.2至4小时。

公开(公告)号：US20130064758A1

公开(公告)日：2013-03-14

申请号：US13606614

申请日：2012-09-07

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Meike Pfaff ,  Mike Haas ,  Feng-Shou Xiao

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Meike Pfaff ,  Mike Haas ,  Feng-Shou Xiao

IPC: C01B39/00

CPC classification number: C01B39/46 ,  C01B39/02 ,  C01B39/30

Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, andwherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.

Abstract translation: 本发明涉及一种用于生产包含YO 2和X 2 O 3的沸石材料的无有机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种的混合物，一种或多种YO2源，一种或多种 X2O3和一种或多种溶剂的来源; （2）使步骤（1）中获得的混合物结晶，得到包含YO 2和X 2 O 3作为结晶产物的沸石材料; 其中Y是四价元素，X是三价元素，并且其中步骤（2）中获得的至少一部分母液作为YO2源再循环到步骤（1），任选地在母液浓缩之后 。

公开(公告)号：US20120259141A1

公开(公告)日：2012-10-11

申请号：US13438316

申请日：2012-04-03

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Takashi Tatsumi ,  Feng-Shou Xiao ,  Dirk de Vos ,  Xinhe Bao ,  Weiping Zhang ,  Hermann Gies ,  Hiroyuki Imai ,  Bart Tijsebaert

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Takashi Tatsumi ,  Feng-Shou Xiao ,  Dirk de Vos ,  Xinhe Bao ,  Weiping Zhang ,  Hermann Gies ,  Hiroyuki Imai ,  Bart Tijsebaert

IPC: C01B39/02 ,  C01B39/46 ,  C07C45/41

CPC classification number: C01B39/46 ,  B01J29/7007 ,  C01B39/026

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.

Abstract translation: 本发明涉及一种制备具有BEA骨架结构的沸石材料的方法，包括以下步骤：（i）提供一种或多种具有BEA骨架结构的沸石材料，其中BEA骨架结构包含YO 2和X 2 O 3，其中 Y是四价元素，X是三价元素; （ii）使步骤（i）中提供的一种或多种沸石材料从BEA骨架结构中除去至少一部分X，优选四面体配位的X的步骤; 其中步骤（i）中提供的一种或多种沸石材料的Y：X摩尔比分别在1至50的范围内。

公开(公告)号：US20120082864A1

公开(公告)日：2012-04-05

申请号：US13249943

申请日：2011-09-30

Applicant: Emi Leung ,  Ulrich Müller ,  Natalia Trukhan ,  Hendrick Mattenheimer ,  Gerhard Cox ,  Stefan Blei

Inventor： Emi Leung ,  Ulrich Müller ,  Natalia Trukhan ,  Hendrick Mattenheimer ,  Gerhard Cox ,  Stefan Blei

IPC: C07F5/06 ,  B32B9/00

CPC classification number: C07F5/069

Abstract: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

Abstract translation: 本发明涉及一种制备多孔金属 - 有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其中所述至少一种金属离子基于铝离子，并且所述至少一种 至少二齿有机化合物是基于富马酸，在至少一种碱的存在下，在至少一种碱的存在下，在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。 至100℃，绝对压力不超过2巴0.2至4小时。

公开(公告)号：US20120016160A1

公开(公告)日：2012-01-19

申请号：US13257348

申请日：2010-03-18

Applicant: Emi Leung ,  Ulrich Müller ,  Gerhard Cox

Inventor： Emi Leung ,  Ulrich Müller ,  Gerhard Cox

IPC: C07F3/02

CPC classification number: C07F3/003 ,  C07C51/412 ,  C07C53/06

Abstract: The present invention relates to a process for preparing a magnesium formate-based porous metal-organic framework, which comprises the steps (a) addition of magnesium or magnesium oxide to formic acid; (b) stirring of the reaction mixture at at least 75° C.; (c) isolation of the solid from the resulting suspension by filtration.

Abstract translation: 本发明涉及一种制备甲酸镁基多孔金属 - 有机骨架的方法，其包括步骤（a）向甲酸中加入镁或氧化镁; （b）在至少75℃下搅拌反应混合物。 （c）通过过滤从所得悬浮液中分离固体。

公开(公告)号：US20110309912A1

公开(公告)日：2011-12-22

申请号：US12674383

申请日：2008-08-08

Applicant: Ulrich Müller

Inventor： Ulrich Müller

IPC: B60R25/00 ,  G08B29/00 ,  E05B3/00

CPC classification number: B60R25/246 ,  G07C9/00309 ,  G07C2209/64 ,  Y10T292/57

Abstract: The invention relates to a handle unit (10) to trigger the function of a lock (19) for opening and/or for closing a moving part (42), in particular a door, a tailgate or similar of a motor vehicle (40), with one electronic unit (20, 20′) and one actuating element, wherein the electronic unit (20, 20′) is used for data communication with a vehicle part, in particular with a security system; the actuating element monitors an actuation zone (60) and a signal is triggered by means of the actuating element by a movement of an object (100) within the actuation zone (60). The invention provides that the actuating element optically monitors the actuation zone (60) so that the detection of a specified motion pattern (30) due to movement of the object (100) will cause a triggering of the signal.

Abstract translation: 本发明涉及一种用于触发用于打开和/或关闭机动车辆（40）的移动部件（42），特别是门，后挡板或类似物的锁（19）的功能的手柄单元（10） ，具有一个电子单元（20,20'）和一个致动元件，其中所述电子单元（20,20'）用于与车辆部件，特别是与安全系统的数据通信; 所述致动元件监视致动区域（60），并且通过所述致动区域（60）内的物体（100）的运动，通过所述致动元件触发信号。 本发明提供了致动元件光学地监视致动区域（60），使得由于物体（100）的移动而对特定运动模式（30）的检测将引起信号的触发。

公开(公告)号：US07879221B2

公开(公告)日：2011-02-01

申请号：US12300902

申请日：2007-05-11

Applicant: Hermann Pütter ,  Markus Schubert ,  Ingo Richter ,  Ulrich Müller ,  Natalia Trukhan

Inventor： Hermann Pütter ,  Markus Schubert ,  Ingo Richter ,  Ulrich Müller ,  Natalia Trukhan

IPC: C25B3/12 ,  C07F15/00 ,  C07F3/00

CPC classification number: C25B3/12

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

Abstract translation: 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物，其包括以下步骤：（a）至少一个阳极的氧化，所述至少一个阳极包含对应于至少一种金属 在至少一种第一有机化合物存在下的反应介质中，所述第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳已经被选自N，O 和S形成包含所述至少一种金属离子和所述第一有机化合物的反应中间体; 和（b）将反应中间体在规定温度下与至少一种与至少一种金属离子配位的第二有机化合物反应，第二有机化合物衍生自二羧酸，三羧酸或四羧酸。

公开(公告)号：US07661510B2

公开(公告)日：2010-02-16

申请号：US11452120

申请日：2006-06-13

Applicant: Ulrich Müller

Inventor： Ulrich Müller

IPC: E04B1/82 ,  F01N1/24 ,  F02K1/00 ,  F02K1/82

CPC classification number: G10K11/168 ,  F02C7/24 ,  F05D2230/60 ,  F05D2250/71 ,  Y02T50/671

Abstract: The invention is directed to a method for manufacturing a sandwich like constructed light weight sheet with sound absorption characteristics, by which an acoustically absorbing cover layer, a substantially grid shape configured first intermediate layer and a bottom layer are bound together, wherein the light weight sheet has a defined surface.

Abstract translation: 本发明涉及一种制造具有吸声特性的夹层结构的轻质薄片的方法，通过该方法将吸声覆盖层，基本上为网格形状的第一中间层和底层结合在一起，其中轻质薄片 有一个定义的表面。