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1.发明授权Process for the organotemplate-free synthetic production of a zeolitic material using recycled mother liquor 有权使用回收母液的沸石材料的无机无模板合成生产方法公开(公告)号：US09028795B2
公开(公告)日：2015-05-12
申请号：US13606614
申请日：2012-09-07
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Meike Pfaff , Mike Haas , Feng-Shou Xiao
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Meike Pfaff , Mike Haas , Feng-Shou Xiao
摘要： The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, and wherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.
摘要翻译： 本发明涉及一种用于生产包含YO 2和X 2 O 3的沸石材料的无有机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种的混合物，一种或多种YO2源，一种或多种 X2O3和一种或多种溶剂的来源; （2）使步骤（1）中获得的混合物结晶，得到包含YO 2和X 2 O 3作为结晶产物的沸石材料; 其中Y是四价元素，X是三价元素，并且其中步骤（2）中获得的至少一部分母液作为YO2源再循环到步骤（1），任选地在母液浓缩之后 。
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2.发明申请公开(公告)号：US20130064758A1
公开(公告)日：2013-03-14
申请号：US13606614
申请日：2012-09-07
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Meike Pfaff , Mike Haas , Feng-Shou Xiao
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Meike Pfaff , Mike Haas , Feng-Shou Xiao
IPC分类号： C01B39/00
摘要： The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, andwherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.
摘要翻译： 本发明涉及一种用于生产包含YO 2和X 2 O 3的沸石材料的无有机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种的混合物，一种或多种YO2源，一种或多种 X2O3和一种或多种溶剂的来源; （2）使步骤（1）中获得的混合物结晶，得到包含YO 2和X 2 O 3作为结晶产物的沸石材料; 其中Y是四价元素，X是三价元素，并且其中步骤（2）中获得的至少一部分母液作为YO2源再循环到步骤（1），任选地在母液浓缩之后 。
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公开(公告)号：US08710271B2
公开(公告)日：2014-04-29
申请号：US13438316
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Takashi Tatsumi , Feng-Shou Xiao , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Takashi Tatsumi , Feng-Shou Xiao , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
CPC分类号： C01B39/46 , B01J29/7007 , C01B39/026
摘要： The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.
摘要翻译： 本发明涉及一种制备具有BEA骨架结构的沸石材料的方法，包括以下步骤：（i）提供一种或多种具有BEA骨架结构的沸石材料，其中BEA骨架结构包含YO 2和X 2 O 3，其中 Y是四价元素，X是三价元素; （ii）使步骤（i）中提供的一种或多种沸石材料从BEA骨架结构中除去至少一部分X，优选四面体配位的X的步骤; 其中步骤（i）中提供的一种或多种沸石材料的Y：X摩尔比分别在1至50的范围内。
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公开(公告)号：US20120259148A1
公开(公告)日：2012-10-11
申请号：US13438408
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , C07C15/073 , C07C15/02
摘要： The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
摘要翻译： 本发明涉及一种有机化合物的烷基化方法，包括：（a）提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂，其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3，其中Y是 四价元素，X是三价元素，（b）在一个或多个烷基化剂存在下，在一个或多个烷基化剂存在下使催化剂与一种或多种可烷基化的有机化合物接触，以获得一种或多种烷基化有机化合物，其中所述一种或多种烷基化有机化合物， 更多的沸石材料可以从不使用有机模板作为结构导向剂的合成方法获得。
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公开(公告)号：US09181145B2
公开(公告)日：2015-11-10
申请号：US13438408
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Dirk de Vos , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , C07C15/073 , C07C15/02
摘要： The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
摘要翻译： 本发明涉及一种有机化合物的烷基化方法，包括：（a）提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂，其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3，其中Y是 四价元素，X是三价元素，（b）在一个或多个烷基化剂存在下，在一个或多个烷基化剂存在下使催化剂与一种或多种可烷基化的有机化合物接触，以获得一种或多种烷基化有机化合物，其中所述一种或多种烷基化有机化合物， 更多的沸石材料可以从不使用有机模板作为结构导向剂的合成方法获得。
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公开(公告)号：US20120259141A1
公开(公告)日：2012-10-11
申请号：US13438316
申请日：2012-04-03
申请人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Takashi Tatsumi , Feng-Shou Xiao , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
发明人： Bilge Yilmaz , Ulrich Müller , Faruk Özkirim , Takashi Tatsumi , Feng-Shou Xiao , Dirk de Vos , Xinhe Bao , Weiping Zhang , Hermann Gies , Hiroyuki Imai , Bart Tijsebaert
CPC分类号： C01B39/46 , B01J29/7007 , C01B39/026
摘要： The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.
摘要翻译： 本发明涉及一种制备具有BEA骨架结构的沸石材料的方法，包括以下步骤：（i）提供一种或多种具有BEA骨架结构的沸石材料，其中BEA骨架结构包含YO 2和X 2 O 3，其中 Y是四价元素，X是三价元素; （ii）使步骤（i）中提供的一种或多种沸石材料从BEA骨架结构中除去至少一部分X，优选四面体配位的X的步骤; 其中步骤（i）中提供的一种或多种沸石材料的Y：X摩尔比分别在1至50的范围内。
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7.发明授权Organotemplate-free synthetic process for the production of a zeolitic material of the LEV-type structure 有权用于生产LEV型结构的沸石材料的无机无合成工艺公开(公告)号：US09114991B2
公开(公告)日：2015-08-25
申请号：US13805092
申请日：2011-06-17
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Bin Xie , Haiyan Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Bin Xie , Haiyan Zhang
CPC分类号： C01B39/02 , B01J20/186 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J29/70 , C01B37/02 , C01B39/46
摘要： Described is an organotemplate-free synthetic process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises:(1) preparing a mixture comprising seed crystals and one or more sources for YO2; and(2) crystallizing the mixture obtained in step (1);wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the seed crystals comprise zeolitic material having an LEV-type framework structure. Also described is a zeolitic material having an LEV-type framework structure obtainable by said process, as well as an organotemplate-free zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein said zeolitic material is non-calcined.
摘要翻译： 描述了一种用于生产具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的合成方法，其中所述方法包括：（1）制备包含晶种和一种或多种YO2源的混合物 ; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述晶种包含具有LEV型框架结构的沸石材料。 还描述了具有通过所述方法可获得的LEV型骨架结构的沸石材料，以及具有无机无模板的沸石材料，其具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构，其中Y是四价元素，X 是三价元素，其中沸石材料任选地包含一种或多种碱金属M，其中所述沸石材料是未煅烧的。
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8.发明申请公开(公告)号：US20130090234A1
公开(公告)日：2013-04-11
申请号：US13805092
申请日：2011-06-17
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Bin Xie , Haiyan Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Bin Xie , Haiyan Zhang
CPC分类号： C01B39/02 , B01J20/186 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J29/70 , C01B37/02 , C01B39/46
摘要： Described is an organotemplate-free synthetic process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises:(1) preparing a mixture comprising seed crystals and one or more sources for YO2; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the seed crystals comprise zeolitic material having an LEV-type framework structure. Also described is a zeolitic material having an LEV-type framework structure obtainable by said process, as well as an organotemplate-free zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein said zeolitic material is non-calcined.
摘要翻译： 描述了一种用于生产具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的合成方法，其中所述方法包括：（1）制备包含晶种和一种或多种YO2源的混合物 ; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述晶种包含具有LEV型框架结构的沸石材料。 还描述了具有通过所述方法可获得的LEV型骨架结构的沸石材料，以及具有无机无模板的沸石材料，其具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构，其中Y是四价元素，X 是三价元素，其中沸石材料任选地包含一种或多种碱金属M，其中所述沸石材料是未煅烧的。
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公开(公告)号：US20120004465A1
公开(公告)日：2012-01-05
申请号：US13254015
申请日：2010-03-03
申请人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Hermann Gies , Dirk de Vos , Xinhe Bao , Weiping Zhang , Takashi Tatsumi
发明人： Bilge Yilmaz , Ulrich Müller , Meike Pfaff , Feng-Shou Xiao , Hermann Gies , Dirk de Vos , Xinhe Bao , Weiping Zhang , Takashi Tatsumi
IPC分类号： C07C209/00 , C01B33/26 , C01B35/10 , C01B33/20
CPC分类号： C01B33/20 , B01J21/16 , B01J29/061 , B01J29/70 , B01J35/002 , C01B33/38 , C01B37/00 , C01B39/02 , C01B39/04 , C07C1/20 , C07C209/16 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C211/04
摘要： A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.
摘要翻译： 一种制备同晶取代的层状硅酸盐的方法，包括（1）提供含有二氧化硅或其前体的混合物，至少一种允许层状硅酸盐结晶的结构导向剂（SDA）和水; （2）在水热条件下加热根据（1）获得的混合物; （3）至少一种源至少一种适用于同晶取代的元素; （4）在水热条件下加热根据（3）获得的混合物。
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10.发明申请Zeolitic Materials of the LEV-Type Structure And Methods For Their Production 审中-公开LEV型结构的沸石材料及其生产方法公开(公告)号：US20110313226A1
公开(公告)日：2011-12-22
申请号：US13163430
申请日：2011-06-17
申请人： Bilge Yilmaz , Ulrich Müller , Bibiana Andrea Betancur Moreno , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Meike Pfaff , Bin Xie , Haiyan Zhang
发明人： Bilge Yilmaz , Ulrich Müller , Bibiana Andrea Betancur Moreno , Hermann Gies , Feng-Shou Xiao , Takashi Tatsumi , Xinhe Bao , Weiping Zhang , Dirk de Vos , Meike Pfaff , Bin Xie , Haiyan Zhang
CPC分类号： C01B39/48 , B01D2253/108 , B01D2255/50 , B01J20/186 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J20/3042 , B01J29/70 , C01B37/02 , C01B39/46 , C10G3/49 , C10G11/18 , C10G25/03 , C10G2300/405 , C10G2300/70 , Y02P30/20
摘要： Described is a process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises: (1) preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and (2) crystallizing the mixture obtained in step (1);wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein the molar ratio of the total amount of the one or more solvents to the total amount of the one or more sources for YO2 based on YO2 is 9.5 or less, and wherein for crystallization temperatures of 175° C. or higher in step (2), the duration of crystallization at those temperatures is less than 14 d, as well as to a zeolitic material, preferably being obtainable or obtained according to the inventive process, said zeolitic material having an LEV-type framework structure comprising YO2 and X2O3, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the zeolitic material displays an Y:X atomic ratio of from 1 to 9.4.
摘要翻译： 描述了一种生产具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括：（1）制备包含一种或多种YO 2，一种或多种溶剂的来源的混合物，以及 任选地包含晶种; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中沸石材料任选地包含一种或多种碱金属M，其中一种或多种溶剂的总量与一种或多种溶剂的总量的摩尔比 基于YO 2的YO 2的来源为9.5或更低，并且其中对于步骤（2）中的结晶温度为175℃或更高的温度，在这些温度下的结晶持续时间小于14天，以及沸石材料， 所述沸石材料具有包含YO 2和X 2 O 3的LEV型骨架结构，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述沸石材料显示Y：X原子 比例为1〜9.4。
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