Process for preparing porous metal-organic frameworks based on aluminum fumarate
    1.
    发明授权
    Process for preparing porous metal-organic frameworks based on aluminum fumarate 有权
    基于富马酸铝制备多孔金属 - 有机骨架的方法

    公开(公告)号:US08524932B2

    公开(公告)日:2013-09-03

    申请号:US13249943

    申请日:2011-09-30

    IPC分类号: C07F5/06

    CPC分类号: C07F5/069

    摘要: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

    摘要翻译: 本发明涉及一种制备多孔金属 - 有机骨架的方法,其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物,其中所述至少一种金属离子基于铝离子,并且所述至少一种 至少二齿有机化合物是基于富马酸,在至少一种碱的存在下,在至少一种碱的存在下,在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。 至100℃,绝对压力不超过2巴0.2至4小时。

    Process For Preparing Porous Metal-Organic Frameworks Based On Aluminum Fumarate
    2.
    发明申请
    Process For Preparing Porous Metal-Organic Frameworks Based On Aluminum Fumarate 有权
    基于富铝酸铝制备多孔金属有机骨架的方法

    公开(公告)号:US20120082864A1

    公开(公告)日:2012-04-05

    申请号:US13249943

    申请日:2011-09-30

    IPC分类号: C07F5/06 B32B9/00

    CPC分类号: C07F5/069

    摘要: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

    摘要翻译: 本发明涉及一种制备多孔金属 - 有机骨架的方法,其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物,其中所述至少一种金属离子基于铝离子,并且所述至少一种 至少二齿有机化合物是基于富马酸,在至少一种碱的存在下,在至少一种碱的存在下,在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。 至100℃,绝对压力不超过2巴0.2至4小时。

    Solvent-Free Preparation Of Magnesium Formate-Based Porous Metal-Organic Framework
    3.
    发明申请
    Solvent-Free Preparation Of Magnesium Formate-Based Porous Metal-Organic Framework 有权
    无溶剂制备基于甲酸镁的多孔金属有机骨架

    公开(公告)号:US20120016160A1

    公开(公告)日:2012-01-19

    申请号:US13257348

    申请日:2010-03-18

    IPC分类号: C07F3/02

    摘要: The present invention relates to a process for preparing a magnesium formate-based porous metal-organic framework, which comprises the steps (a) addition of magnesium or magnesium oxide to formic acid; (b) stirring of the reaction mixture at at least 75° C.; (c) isolation of the solid from the resulting suspension by filtration.

    摘要翻译: 本发明涉及一种制备甲酸镁基多孔金属 - 有机骨架的方法,其包括步骤(a)向甲酸中加入镁或氧化镁; (b)在至少75℃下搅拌反应混合物。 (c)通过过滤从所得悬浮液中分离固体。

    Solvent-free preparation of magnesium formate-based porous metal-organic framework
    5.
    发明授权
    Solvent-free preparation of magnesium formate-based porous metal-organic framework 有权
    无甲酸镁基多孔金属有机骨架的制备

    公开(公告)号:US08431744B2

    公开(公告)日:2013-04-30

    申请号:US13257348

    申请日:2010-03-18

    IPC分类号: C07C53/00

    摘要: The present invention relates to a process for preparing a magnesium formate-based porous metal-organic framework, which comprises the steps (a) addition of magnesium or magnesium oxide to formic acid; (b) stirring of the reaction mixture at at least 75° C.; (c) isolation of the solid from the resulting suspension by filtration.

    摘要翻译: 本发明涉及一种制备甲酸镁基多孔金属 - 有机骨架的方法,其包括步骤(a)向甲酸中加入镁或氧化镁; (b)在至少75℃下搅拌反应混合物。 (c)通过过滤从所得悬浮液中分离固体。

    Use of formate-based porous metal organic frameworks for methane storage
    6.
    发明授权
    Use of formate-based porous metal organic frameworks for methane storage 失效
    使用甲酸基多孔金属有机骨架进行甲烷储存

    公开(公告)号:US08343261B2

    公开(公告)日:2013-01-01

    申请号:US12921505

    申请日:2009-03-17

    IPC分类号: B01D53/02

    摘要: The present invention relates to the use of a porous metal organic framework comprising at least a first organic compound and, if appropriate, a second organic compound, in which at least the first organic compound is at least partially coordinated in a bidentate fashion to at least one metal ion, where the at least one metal ion is Mg(II) and the first organic compound is derived from formic acid and the second organic compound is derived from acetic acid, for storing or isolating methane. Furthermore, the invention relates to a porous metal organic framework based on magnesium formate and acetate and also its preparation.

    摘要翻译: 本发明涉及多孔金属有机骨架的用途,所述多孔金属有机骨架包含至少第一有机化合物和(如果合适的话)第二有机化合物,其中至少第一有机化合物至少部分地以双齿形式协调至少至少 一种金属离子,其中至少一种金属离子是Mg(II),第一种有机化合物衍生自甲酸,第二种有机化合物衍生自乙酸,用于储存或分离甲烷。 此外,本发明涉及一种基于甲酸镁和乙酸盐的多孔金属有机骨架及其制备方法。

    Lithium-based metal organic frameworks
    8.
    发明授权
    Lithium-based metal organic frameworks 有权
    锂基金属有机骨架

    公开(公告)号:US08829239B2

    公开(公告)日:2014-09-09

    申请号:US13002612

    申请日:2009-07-28

    摘要: An object of the present invention relates to a porous metal organic framework comprising at least one first organic compound and ions of at least one metal, with the skeleton of the framework being formed at least partly by the at least one first organic compound coordinating at least partly in a bidentate fashion to at least two ions of the at least one metal, where the at least one metal is lithium and the at least one first compound is derived from formic acid or acetic acid. Also provided a process for preparing the porous metal organic framework and its use for gas storage or separation.

    摘要翻译: 本发明的目的涉及一种多孔金属有机骨架,其包含至少一种第一有机化合物和至少一种金属的离子,骨架的骨架至少部分由至少一种至少配位的第一有机化合物形成 部分地以至少一种金属的至少两种离子的二齿形式,其中所述至少一种金属是锂,并且所述至少一种第一化合物衍生自甲酸或乙酸。 还提供了一种制备多孔金属有机骨架及其用于储气或分离的方法。

    VACUUM INSULATION UNITS COMPRISING GETTER MATERIALS
    10.
    发明申请
    VACUUM INSULATION UNITS COMPRISING GETTER MATERIALS 失效
    真空绝缘单元包含材料

    公开(公告)号:US20110265654A1

    公开(公告)日:2011-11-03

    申请号:US13144234

    申请日:2010-01-12

    IPC分类号: B01D53/02 B01J20/00

    摘要: The present invention relates to vacuum insulation units comprising at least one thermally insulating, evacuatable porous core material which is sealed in an airtight manner and a sorption medium, wherein the sorption medium comprises at least one porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, and also shaped bodies comprising such a vacuum insulation unit.Furthermore, the present invention relates to the use of a porous metal-organic framework as getter material in a vacuum insulation unit.

    摘要翻译: 本发明涉及真空绝热单元,其包括至少一种以气密方式密封的绝热可抽空的多孔芯材料和吸附介质,其中所述吸附介质包括至少一个多孔金属 - 有机骨架,其至少包括至少一个 与至少一种金属离子配位的双齿有机化合物,以及包括这种真空绝热单元的成型体。 此外,本发明涉及多孔金属 - 有机骨架在真空绝热单元中作为吸气材料的用途。