摘要:
A method of preparing a polyester resin composition laminate, which method comprises spraying an unsaturated polyester resin composition with an acrylic-urethane prepolymer onto a substrate, like a glass fiber, and curing the sprayed composition by radiant light.
摘要:
A modified acrylic urethane prepolymer composition and an unsaturated polyester resin composition to which the prepolymer has been added. The prepolymer composition includes an acrylic urethane prepolymer prepared by the reaction of diisocyanate, like MDI, with an hydroxyl-containing acrylate monomer, such as a pentaerythritol triacrylate, which prepolymer composition may contain a styrene monomer and an inhibitor, such as benzoquinone, to retard the reaction of the prepolymer and styrene monomer prior to the addition of the prepolymer composition into the polyester resin composition. The employment of the modified urethane prepolymer composition provides for the reduction in the amount of styrene monomer used in the unsaturated resin composition and also provides for improved chemical and physical properties of the cured, unsaturated resin composition, such as a reduction in glass roll-out when the resin composition is employed with fiberglass.
摘要:
Spray polyurea elastomer systems have improved adhesion to a substrate with the incorporation of a functional alkoxy silane and water. Such systems typically also include a quasi-prepolymer of an isocyanate and an active hydrogen-containing material, and at least one amine resin, and preferably an amine-terminated chain extender. The system may also benefit from the incorporation of a higher than usual proportion of 2,4'-isomer methylene diisocyanate (MDI). The viscosity of the various components, as well as various processing characteristics, may be improved by the addition of an alkylene carbonate. The spray polyurea elastomer systems of this invention also have improved abrasion and impact resistance.
摘要:
A method for producing a modified polyisocyanurate foam by reacting an organic polyisocyanate, polyol and water in the presence of a trimerization catalyst composed of a salt of 1,8-diaza-bicyclo[5.4.0] undecene-7, and a carbodiimidation catalyst composed of a certain phosphorene oxide. The method enables production of low density modified polyisocyanurate foams with ease and rapidly without using volatile blowing agents such as CFC, HCF, HFC pentane and methylene chloride.
摘要:
A method for producing a modified polyisocyanurate foam by reacting an organic polyisocyanate, polyol and water in the presence of a trimerizing catalyst composed of a certain hydroxyalkyl quaternary ammonium compound, and a carbodiimidizing catalyst composed of a certain phosphorene oxide. The method enables production of low density modified polyisocyanurate foams with ease and rapidly without using volatile blowing agents such as CFC, HCFC, HFC and methylene chloride.
摘要:
A method for producing a modified polyisocyanurate foam by reacting an organic polyisocyanate, polyol and water in the presence of a trimerization catalyst composed of a salt of 1,8-diaza-bicyclo[5.4.0]undecene-7, and a carbodiimidation catalyst composed of a certain phosphorene oxide. The method enables production of low density modified polyisocyanurate foams with ease and rapidly without using volatile blowing agents such as CFC, HCF, HFC pentane and methylene chloride.
摘要:
Rigid foams characterized by carbodiimide and isocyanurate linkages are prepared by catalytically condensing an organic polyisocyanate in the presence of certain quaternary boron salts.
摘要:
Polymers comprising polyoxazolidone and carbodiimide recurring units of the formula: ##STR1## are prepared from polyisocyanates and polyepoxides. Non-friable, low density fire resistant foams are prepared directly from the polymers of the invention without the equisite addition of pore-forming agents.
摘要:
Rigid cellular foam compositions characterized by carbodiimide, isocyanurate and urethane linkages are prepared by the reaction of an organic polyisocyanate with certain oxyalkylated Mannich polyols employing an NCO/OH equivalent ratio of from about 2:1 to 10:1. The use of the oxyalkylated Mannich polyols in the amounts stated eliminates the need for carbodiimide and isocyanurate promoting catalysts.
摘要:
RIGID CELLULAR FOAM COMPOSITIONS CHARACTERIZED BY CARBODIIMIDE LINKAGES ARE PREPARED BY CATALYTICALLY CONDENSING AN ORGANIC POLYISOCYANATE IN THE PRESENCE OF 2,4, 6-TRIS(N-METHYLETHANOLAMINO)-S-TRIAZINE OR, ALTERNATIVELY, IN THE PRESENCE OF A CO-CATALYST SYSTEM OF (A) 2,4,6TRIS(N-METHYLETHANOLAMINO)-S-TRIAZINE AND (B) CATALYST SELECTED FROM THE GROUP CONSISTING OF (1) 1,3,5-TRIS(N, N-DIALKYLAMINOALKYL)-S-HEXAHYDROTRIAZINE, (2) 2,4,6-TRIS (DIMETHYLAMINOETHYL) PHENOL, (3) O-, P-, AND A MIXTURE OF O- AND P-DIMETHYLAMINOMETHYLPHENOL, AND (4) AN ORGANOTIN COMPOUND.