公开(公告)号：US5451701A

公开(公告)日：1995-09-19

申请号：US266820

申请日：1994-06-27

Applicant: John G. Zajacek ,  John C. Jubin ,  Guy L. Crocco

Inventor： John G. Zajacek ,  John C. Jubin ,  Guy L. Crocco

IPC: C07C249/04 ,  C07C251/44 ,  C07D201/02 ,  C07D201/04 ,  C07D201/06

CPC classification number: C07C249/04 ,  C07C251/44 ,  Y02P20/125

Abstract: An integrated process for producing cyclohexanone oxime, a caprolactam precursor, is provided wherein a secondary alcohol is utilized to generate the hydrogen peroxide oxidizing agent and as a reaction medium for ammoximation. The ketone produced as a co-product is recycled back to the secondary alcohol by hydrogenation.

Abstract translation: 提供了一种用于生产环己酮肟，己内酰胺前体的综合方法，其中使用仲醇产生过氧化氢氧化剂和作为氨肟化反应的反应介质。 作为副产物生产的酮通过氢化再循环回到仲醇中。

公开(公告)号：US4178286A

公开(公告)日：1979-12-11

申请号：US736343

申请日：1976-10-28

Applicant: Harry H. Wasserman ,  Bruce H. Lipshutz

Inventor： Harry H. Wasserman ,  Bruce H. Lipshutz

IPC: C07D223/10 ,  C07D201/02 ,  C07D205/08 ,  C07D205/095 ,  C07D207/263 ,  C07D211/76 ,  C07D409/06 ,  C07D405/06

CPC classification number: C07D201/02 ,  C07D205/08 ,  C07D205/095

Abstract: .gamma.-lactones are converted into both known and new azetidine carboxylic acids which can be transformed readily to the corresponding .beta.-lactams by oxidative decarboxylation. The .beta.-lactams and substitution products thereof are useful intermediates in the synthesis of biologically active lactams such as nocardicin.

Abstract translation: γ-内酯被转化为已知的和新的氮杂环丁烷羧酸，其可以通过氧化脱羧而容易地转化成相应的β-内酰胺。 β-内酰胺及其取代产物是合成生物活性内酰胺如诺卡霉素的有用中间体。

公开(公告)号：US3767648A

公开(公告)日：1973-10-23

申请号：US3767648D

申请日：1971-12-01

Applicant: KANEGAFUCHI SPINNING CO LTD

Inventor： FUJITA I ,  TANI H ,  DEGUCHI S

IPC: B01J21/00 ,  B01J31/00 ,  C07B61/00 ,  C07C67/00 ,  C07C239/00 ,  C07C251/46 ,  C07D201/02 ,  C07D201/04 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07D201/04 ,  Y02P20/52

Abstract: THIS INVENTION RELATES TO A PROCESS FOR SIMULTANEOUSLY PRODUCING E-CAPROLACTAM AND O - ACETYLCYCLOHEXANONEOXIME.

公开(公告)号：US3681387A

公开(公告)日：1972-08-01

申请号：US3681387D

申请日：1970-10-16

Applicant: SUN OIL CO

Inventor： HOLLSTEIN ELMER J ,  SCOTT KENNETH A

IPC: C07D201/02 ,  C07D201/08 ,  C07D27/08

CPC classification number: C07D201/02 ,  C07D201/08

Abstract: An improved process for preparing 2-pyrrolidinone at relatively low pressures which comprises reduction of succinimide in an aqueous system at temperatures of about 225* to 275* C., at a pressure in the range of about 1,200 to 1,500 p.s.i.g. and in the presence of a supported palladium catalyst.

Abstract translation: 一种用于在相对低的压力下制备2-吡咯烷酮的改进方法，其包括在约225-275℃的温度下在水性体系中还原琥珀酰亚胺，压力范围为约1,200至1,500p.s.i。 并在负载型钯催化剂存在下进行。

公开(公告)号：US3634346A

公开(公告)日：1972-01-11

申请号：US3634346D

申请日：1969-08-15

Applicant: UNION CARBIDE CORP

Inventor： MCKEON JAMES E ,  TRECKER DAVID J

IPC: C07D201/02 ,  C07D41/00

CPC classification number: C07D201/02

Abstract: A LIQUID PHASE OXIDATION REACTION WHEREBY A CYCLIC AMINE HAVING AN UNSUBSTITUTED METHYLENE MOIETY ADJACENT TO THE RING NITROGEN IS CONVERTED TO THE CORRESPONDING LACTAM BY REACTING THE AMINE WITH A HYDROPEROXIDE IN THE PRESENCE OF A METAL ION CATALYST.

公开(公告)号：US3575964A

公开(公告)日：1971-04-20

申请号：US3575964D

申请日：1968-12-09

Applicant: BP CHEM INT LTD

Inventor： HAWKINS EDWIN GEORGE EDWARD

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: IN THE CATALYTIC CLEAVAGE 1,1''-PEROXYDICYCLOHEXYLAMINE, TO GIVE CAPROLACTAM THE MAJORITY OF THE CYCLOALKANONE COPRODUCT IS CONTINUOUSLY REMOVED BY DISTILLATION FROM THE MIXTURE UNDERGOING CLEAVAGE.

公开(公告)号：US3523940A

公开(公告)日：1970-08-11

申请号：US3523940D

申请日：1967-04-06

Applicant: OLIN MATHIESON

Inventor： CHURCHILL JOHN W ,  HANFORD WILLIAM E ,  KOBER EHRENFRIED H

IPC: C07C45/00 ,  C07C45/49 ,  C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07C45/00 ,  C07C45/49 ,  C07C49/403

公开(公告)号：US3239562A

公开(公告)日：1966-03-08

申请号：US25864963

申请日：1963-02-14

Applicant: HALCON INTERNATIONAL INC

Inventor： BARKER ROBERT S

IPC: B01J21/00 ,  B01J21/12 ,  B01J23/02 ,  C07D201/02

CPC classification number: C07D201/02 ,  B01J21/00 ,  B01J21/12 ,  B01J23/02

公开(公告)号：US2702801A

公开(公告)日：1955-02-22

申请号：US42451154

申请日：1954-04-20

Applicant: DU PONT

Inventor： GUY DONARUMA LORRAINE ,  HUBER MELVIN L

IPC: C07D201/02

CPC classification number: C07D201/02

公开(公告)号：US20170095789A1

公开(公告)日：2017-04-06

申请号：US15382991

申请日：2016-12-19

Applicant: Ralf MEIER ,  Kévin Micoine ,  Peter Kreis ,  Frederik Gluth ,  Markus Priske

Inventor： Ralf MEIER ,  Kévin Micoine ,  Peter Kreis ,  Frederik Gluth ,  Markus Priske

IPC: B01J19/24 ,  B01D61/02 ,  C07D301/32 ,  C07D201/02 ,  C07D225/02 ,  C07D301/12

Abstract: An apparatus for the epoxidation of a cyclic unsaturated C12 compound with hydrogen peroxide is provided. The apparatus includes a reactor for carrying out the reaction, wherein the walls of the reactor are at least partially furnished with a separation-active layer of crosslinked silicone acrylates and/or polydimethylsiloxane.