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    Catalyst compounds with beta-diiminate anionic ligands and processes for polymerizing olefins
    31.
    发明申请
    Catalyst compounds with beta-diiminate anionic ligands and processes for polymerizing olefins 失效
    具有β-二亚胺阴离子配位体的催化剂化合物和烯烃聚合方法

    公开(公告)号：US20040063574A1

    公开(公告)日：2004-04-01

    申请号：US10319818

    申请日：2002-12-16

    Inventor： Klaus H. Theopold ,  Woo-Kyu Kim ,  Leonard A. MacAdams ,  John M. Power ,  Javier M. Mora ,  Albert P. Masino

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F10/00 ,  C07F7/003 ,  C07F9/00 ,  C07F9/005 ,  C07F11/005 ,  C08F10/02 ,  C08F110/02 ,  C08F110/14 ,  C08F210/16 ,  C08F2410/03 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/01 ,  C08F210/06 ,  C08F2500/10 ,  C08F210/14 ,  C08F4/64044 ,  C08F4/69112 ,  C08F4/68112

    Abstract: The present invention relates to catalyst systems, processes for making such catalysts, intermediates for such catalysts, and olefin polymerization processes using such catalysts wherein such catalyst includes a component represented by the following formula IA: 1 wherein R and Rnull independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl or organosilyl radical; R1, R2, and R3 independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl radical; M is a group IIIB, IVB, VB, VIB, VIIB or VIII transition metal; T independently represents a univalent anionic ligand such as a hydrogen atom, or a substituted or unsubstituted hydrocarbyl, halogeno, aryloxido, arylorganosilyl, alkylorganosilyl, amido, arylamido, phosphido, or arylphosphido group, or two T groups taken together represent an alkylidene or a cyclometallated hydrocarbyl bidentate ligand; L independently represents a sigma donor stabilizing ligand; X, which is optional, represents a relatively weakly coordinated anion; and anull0 to 4 inclusive, bnull0 to 4 inclusive, provided anullbnull4.

    Abstract translation: 本发明涉及催化剂体系，制备这种催化剂的方法，这种催化剂的中间体和使用这种催化剂的烯烃聚合方法，其中这种催化剂包括由下式IA表示的组分：其中R和R'独立地表示氢原子， 或取代或未取代的支链或非支链烃基或有机甲硅烷基; R 1，R 2和R 3独立地表示氢原子，或取代或未取代的支链或非支链烃基; M是IIIB，IVB，VB，VIB，VIIB或VIII族过渡金属; T独立地表示一价阴离子配体，例如氢原子，或取代或未取代的烃基，卤代，芳氧基，芳基有机甲硅烷基，烷基有机甲硅烷基，酰胺基，芳基酰氨基，磷酰基或芳基磷酰基，或两个T基团一起表示亚烷基或环金属化 烃基二齿配体; L独立地表示σ供体稳定配体; 任选的X表示相对弱配位的阴离子; a = 0〜4，b = 0〜4，其中a + b <= 4。

    Chelate catalyst for olefin polymerization and olefin polymerization method using the same
    32.
    发明申请
    Chelate catalyst for olefin polymerization and olefin polymerization method using the same 有权
    用于烯烃聚合的螯合催化剂和使用其的烯烃聚合方法

    公开(公告)号：US20040063573A1

    公开(公告)日：2004-04-01

    申请号：US10451289

    申请日：2003-11-03

    Inventor： Gap-Goung Kong

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/651 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14

    Abstract: The present invention provides a novel chelated catalyst for olefin polymerization and an olefin polymerization method using the chelated catalyst. The catalyst of the invention is a liquid titanium compound chelated with an imidazole ligand. The method for olefin polymerization of the present invention is performed using the liquid titanium compound as a main catalyst component.

    Abstract translation: 本发明提供一种用于烯烃聚合的新型螯合催化剂和使用该螯合催化剂的烯烃聚合方法。 本发明的催化剂是与咪唑配体螯合的液体钛化合物。 使用液体钛化合物作为主要催化剂成分进行本发明的烯烃聚合方法。

    Polymerization process with mixed catalyst compositions
    33.
    发明申请
    Polymerization process with mixed catalyst compositions 失效
    混合催化剂组合物的聚合方法

    公开(公告)号：US20040048990A1

    公开(公告)日：2004-03-11

    申请号：US10250926

    申请日：2003-07-07

    Inventor： Jeffrey L. Brinen ,  Charles Cozewith

    IPC: C08F004/44 ,  B01J031/00

    CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F2420/02 ,  Y10S526/943 ,  C08F4/65904

    Abstract: The application describes a mixed olefin polymerization catalyst composition comprising a support, a reaction product of at least one first organometallic compound and a first activator capable of rendering the first organometallic compound active for insertion polymerization, and at least one second organometallic compound, the activator incapable of rendering the second organometallic compound active for polymerization of the monomers. The mixed catalyst composition can be used to prepare a first polymer component in a first polymerization reactor stage and then, when an effective activator is added for the second organometallic compound, the catalyst composition can be used to prepare a second polymer composition that is homogeneously blended with the first polymer component.

    Abstract translation: 本申请描述了一种混合烯烃聚合催化剂组合物，其包含载体，至少一种第一有机金属化合物的反应产物和能够使第一有机金属化合物具有活性的插入聚合的第一活化剂和至少一种第二有机金属化合物，该活化剂不能 使第二有机金属化合物活化用于单体的聚合。 混合催化剂组合物可用于在第一聚合反应器阶段中制备第一聚合物组分，然后当为第二有机金属化合物加入有效的活化剂时，催化剂组合物可用于制备均匀混合的第二聚合物组合物 与第一聚合物组分。

    Coordination compounds and their use for the polymerization of olefins
    35.
    发明申请
    Coordination compounds and their use for the polymerization of olefins 失效
    配位化合物及其在烯烃聚合中的应用

    公开(公告)号：US20040030069A1

    公开(公告)日：2004-02-12

    申请号：US10467792

    申请日：2003-08-12

    Inventor： Marc Oliver Kristen ,  Benno Bildstein ,  Alexander Krajete

    IPC: C08F004/44 ,  C07F011/00

    CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F110/02 ,  C08F210/16 ,  C08F4/64048 ,  C08F2500/17 ,  C08F210/14 ,  C08F4/6411

    Abstract: The invention relates to coordination compounds of the general formulae (1a) to (1b), wherein MnullTi, Zr, Hf, V, Nb or Ta. The invention also relates to a method for producing the metal complexes and to the use of the complexes so obtained for the polymerization and copolymerization of olefins. For example in suspension polymerization methods, gas phase polymerization methods and bulk polymerization methods.

    Abstract translation: 本发明涉及通式（1a）至（1b）的配位化合物，其中M = Ti，Zr，Hf，V，Nb或Ta。 本发明还涉及制备金属络合物的方法以及如此获得的用于烯烃聚合和共聚合的络合物的用途。 例如悬浮聚合法，气相聚合法和本体聚合法。

    Multimodal polyethylene obtained with multilayered chromium catalyst
    36.
    发明申请
    Multimodal polyethylene obtained with multilayered chromium catalyst 失效
    用多层铬催化剂得到的多峰聚乙烯

    公开(公告)号：US20040029727A1

    公开(公告)日：2004-02-12

    申请号：US10297710

    申请日：2003-06-16

    Inventor： Philippe Bodart ,  Nicodeme Lonfils ,  Guy Debras

    IPC: B01J023/26 ,  B01J021/08 ,  C08F004/44

    CPC classification number: C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/69 ,  C08F4/025 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/14 ,  C08F2500/13 ,  C08F2500/07 ,  C08F210/08 ,  C08F210/14 ,  C08F210/06 ,  C08F4/24

    Abstract: The present invention concerns a catalyst for the production of high density polyethylene, by homopolymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising 3 to 10 carbon atoms, prepared by the steps of: a) selecting a silica support with a specific surface area larger than 300 m2/g; b) treating the silica support with a titanium compound, in order to introduce titanium into the support, or with an aluminium compound, in order to introduce aluminium into the support; c) either treating the titanated silica support with an aluminum compound, in order to introduce aluminum into the titanated silica support, or treating the aluminated silica support with a titanium compound, in order to introduce titanium into the aluminated silica support; d) depositing a chromium compound on the titanated and aluminated silica support to form a catalyst; e) activating the catalyst of step d) under air in a fluidised bed at a temperature of from 600 to 800null C.

    Abstract translation: 本发明涉及用于生产高密度聚乙烯的催化剂，通过均聚乙烯或共聚乙烯和包含3至10个碳原子的α-烯烃共聚单体，其步骤为：a）选择具有比表面积的二氧化硅载体 大于300 m2 / g; b）用钛化合物处理二氧化硅载体，以便将钛引入载体或用铝化合物，以便将铝​​引入载体中; c）用铝化合物处理钛酸二氧化硅载体，以便将铝​​引入钛酸二氧化硅载体中，或用钛化合物处理铝化二氧化硅载体，以便将钛引入到铝化硅载体中; d）在钛酸化和镀铝的二氧化硅载体上沉积铬化合物以形成催化剂; e）在600至800℃的温度下在流化床中在空气下活化步骤d）的催化剂。

    Components and catalysts for the polymerization of olefins
    38.
    发明申请
    Components and catalysts for the polymerization of olefins 有权
    用于烯烃聚合的组分和催化剂

    公开(公告)号：US20040014595A1

    公开(公告)日：2004-01-22

    申请号：US10415025

    申请日：2003-04-24

    Inventor： Giampiero Morini ,  Giulio Balbontin ,  Yuri V. Gulevich ,  Gianni Vitale

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F4/651 ,  C08F110/06 ,  C08F2500/15

    Abstract: The present invention relates to a solid catalyst component for the polymerization of olefins CH2nullCHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from maleates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

    Abstract translation: 本发明涉及用于烯烃CH 2 = CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自马来酸酯的电子给体 。 当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

    Spray-dried polymerization catalyst and polymerization processes employing same
    40.
    发明申请
    Spray-dried polymerization catalyst and polymerization processes employing same 失效
    喷雾干燥聚合催化剂和采用其的聚合方法

    公开(公告)号：US20040010100A1

    公开(公告)日：2004-01-15

    申请号：US10196663

    申请日：2002-07-15

    Inventor： Burkhard Eric Wagner ,  Robert James Jorgensen ,  Mark Wilton Smale

    IPC: C08F004/44

    CPC classification number: C08F10/02 ,  C08F110/02 ,  C08F2410/01 ,  Y02P20/582 ,  C08F4/6367 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    Abstract: A spray-dried composition comprising an inert porous filler and a reaction product of 1) a mixture or reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound. The filler is substantially spherical and has an average particle size ranging from about 1 nullm to about 12 nullm. Methods of making spray-dried compositions, catalysts and polymerization processes employing such are also described.

    Abstract translation: 一种喷雾干燥的组合物，其包含惰性多孔填料和1）卤化镁，溶剂，电子给体化合物和过渡金属化合物的混合物或反应产物的反应产物。 填料基本上是球形的，其平均粒度范围为约1μm至约12μm。 还描述了制备喷雾干燥组合物的方法，催化剂和使用其的聚合方法。

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