Apparatus for electrochemical treatment of water and/or water solutions
    393.
    发明授权
    Apparatus for electrochemical treatment of water and/or water solutions 失效
    水和/或水溶液的电化学处理装置

    公开(公告)号:US5985110A

    公开(公告)日:1999-11-16

    申请号:US76656

    申请日:1998-05-12

    Abstract: An apparatus for electrochemical purification of water and for regulation of acid-alkaline properties, Red-Ox characteristics and catalytic activity of water that can be used for obtaining washing and disinfecting solutions. The apparatus includes at least one electrochemical cell which contain vertical coaxial cylindrical and rod electrodes made from material nonsoluble during electrolysis and an ultrafiltration ceramic diaphragm installed between the electrodes to create inter-electrode space in the electrode chambers. Channels for the treated solution supply into and discharge from the electrode chambers. A feeding line is connected to the inlet of the negative electrode chamber and the output of the negative electrode chamber is connected to the inlet of the positive electrode chamber by a special line which has a by-pass for discharging a part of the degasified treated solution from the chamber of the negative electrode. A catalyst chamber can be installed on the special line. The catalyst chamber contains a mixture of particles of carbon and manganese dioxide. A separator with a tangential inlet is used for discharging a part of the degasified processed solution.

    Abstract translation: 用于电化学纯化水的装置,用于调节酸碱性质,Red-Ox特性和可用于获得洗涤和消毒溶液的水的催化活性。 该装置包括至少一个电化学电池,其包含由电解期间不可溶的材料制成的垂直同轴圆柱形和棒状电极,以及安装在电极之间的超滤陶瓷膜,以在电极室中产生电极间空间。 经处理溶液的通道供应入电极室并从电极室排出。 馈电线连接到负极室的入口,负极室的输出端通过专门的线路连接到正极室的入口,该专线具有用于排出部分脱气处理溶液的旁路 从负极室。 催化剂室可以安装在专线上。 催化剂室含有碳和二氧化锰颗粒的混合物。 具有切向入口的分离器用于排出部分脱气处理溶液。

    Electrode for electrolysis and electrolytic cell using the electrode
    395.
    发明授权
    Electrode for electrolysis and electrolytic cell using the electrode 失效
    用于电解的电极和使用该电极的电解槽

    公开(公告)号:US5900127A

    公开(公告)日:1999-05-04

    申请号:US825866

    申请日:1997-04-02

    Abstract: An electrode for electrolysis comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. The electrode substance having an electrically conductive diamond structure may be a diamond containing an impurity selected from boron, phosphorus and graphite. Alternatively, the electrode substance having an electrically conductive diamond structure may comprise a composite of a diamond and an electrically conductive material. In a preferred embodiment, the electrode further comprises an interlayer comprising at least one of the carbide of a valve metal and silicon carbide disposed between the electrode base material and the electrode substance having an electrically conductive diamond structure. Also disclosed is an electrolytic cell having two chambers including an anode chamber and a cathode chamber partitioned by an ion-exchange membrane. At least one of the anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. An electrolytic cell having three chambers is also disclosed, including an anode chamber, an intermediate chamber and a cathode chamber partitioned by ion-exchange membranes. At least one of an anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material.

    Abstract translation: 一种电解用电极,其特征在于,具有电极基材和覆盖所述电极基材表面的导电性金刚石结构的电极物质。 具有导电金刚石结构的电极物质可以是含有选自硼,磷和石墨的杂质的金刚石。 或者,具有导电金刚石结构的电极物质可以包括金刚石和导电材料的复合物。 在优选实施例中,电极还包括中间层,其包括设置在电极基材和具有导电金刚石结构的电极物质之间的阀金属和碳化硅的碳化物中的至少一种。 还公开了一种具有两个腔室的电解池,该腔室包括由离子交换膜隔开的阳极室和阴极室。 放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材和覆盖电极基材表面的导电金刚石结构的电极物质的电极。 还公开了一种具有三个室的电解池,包括由离子交换膜分隔的阳极室,中间室和阴极室。 放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材的电极和具有覆盖电极母材表面的导电金刚石结构的电极物质。

    Apparatus for electrochemical treatment of water and/or water solutions
    396.
    发明授权
    Apparatus for electrochemical treatment of water and/or water solutions 失效
    水和/或水溶液的电化学处理装置

    公开(公告)号:US5871623A

    公开(公告)日:1999-02-16

    申请号:US820259

    申请日:1997-03-18

    Abstract: An apparatus for electrochemical purification of water and for regulation of acid-alkaline properties, Red-Ox characteristics and catalytic activity of water that can be used for obtaining washing and disinfecting solutions. The apparatus includes at least one electrochemical cell which contain vertical coaxial cylindrical and rod electrodes made from material nonsoluble during electrolysis and an ultrafiltration ceramic diaphragm installed in the bushings between the electrodes to create inter-electrode space in the electrode chambers. The lower and upper bushings have a channels for the treated solution supply into and discharge from the electrode chambers. The channels are connected to the feeding and discharging adjustment lines. There is also a metering pump on the water line for sodium chloride dosing into the water to be treated. The water line contains a flow regulator connected to the feeding and discharging adjustment lines. Poles of the power supply are connected to the electrodes. The feeding line is connected to the inlet of the negative electrode chamber and the output of the negative electrode chamber is connected to the inlet of the positive electrode chamber by a special line which has an adjustment for discharging a part of the degasified treated solution from the chamber of the negative electrode. A catalyst chamber can be installed on the special line. The catalyst chamber contains a mixture of particles of carbon and manganese dioxide. A separator with a tangential inlet is used for discharging a part of the degasified processed solution.

    Abstract translation: 用于电化学纯化水的装置,用于调节酸碱性质,Red-Ox特性和可用于获得洗涤和消毒溶液的水的催化活性。 该装置包括至少一个电化学电池,其包含由在电解过程中不相容的材料制成的垂直同轴圆柱形和棒状电极以及安装在电极之间的衬套中的超滤陶瓷膜,以在电极室中产生电极间空间。 下部和上部衬套具有用于经处理的溶液供给电极室和从电极室排出的通道。 通道连接到进给和排料调节线。 在水线上还有一个计量泵,用于将氯化钠投入到待处理的水中。 水管线包括连接到进料和排料调节管线的流量调节器。 电源极与电极连接。 馈电线连接到负极室的入口,负极室的输出端通过专用线连接到正极室的入口,该专线具有用于从一部分脱气处理溶液中排出一部分 负极室。 催化剂室可以安装在专线上。 催化剂室含有碳和二氧化锰颗粒的混合物。 具有切向入口的分离器用于排出部分脱气处理溶液。

    Apparatus and method for electrocoriolysis the separation of ionic
substances from liquids by electromigration and coriolis force
    397.
    发明授权
    Apparatus and method for electrocoriolysis the separation of ionic substances from liquids by electromigration and coriolis force 失效
    通过电迁移和科里奥利力将离子物质与液体分离的电解溶剂的装置和方法

    公开(公告)号:US5858199A

    公开(公告)日:1999-01-12

    申请号:US678892

    申请日:1996-07-12

    Inventor: Joseph J. Hanak

    Abstract: An apparatus and method for separating and removing ionizable components dissolved in fluids, such as for example, water, by separating said ionizable substances into fractions by the action of electric current and of Coriolis force. Liquid containing ionizable components is continuously fed in and the purified solvent and the solute in a concentrated solution are continuously removed while the liquid is rotated. Compound centrifugal force or Coriolis force causes the concentrated solution to move to a location where it can be effectively and continuously removed as well as causes the depleted liquid to move to a separate location where it also can be effectively and continuously removed. The invention can operate in several modes, the modes being electrolytic and electrostatic. The invention allows for almost universal application to removal of ionizable components and provides a cost effective and energy efficient continuous process to do so.

    Abstract translation: 一种用于分离和去除溶解在流体(例如水)中的可离子化组分的装置和方法,通过电流和科里奥利力的作用将所述可离子化物质分离成馏分。 连续送入含有可电离成分的液体,同时在液体旋转的同时,将浓缩溶液中的纯化溶剂和溶质连续地除去。 复合离心力或科里奥利力使浓缩溶液移动到可以有效和连续地移除的位置,并且使耗尽的液体移动到可以被有效且连续地移除的单独位置。 本发明可以在多种模式下工作,这些模式是电解和静电的。 本发明允许几乎普遍的应用去除可离子化组分并提供成本效益和节能的连续过程来实现。

    Electrochemically assisted ion exchange
    398.
    发明授权
    Electrochemically assisted ion exchange 失效
    电化学辅助离子交换

    公开(公告)号:US5788826A

    公开(公告)日:1998-08-04

    申请号:US790710

    申请日:1997-01-28

    Applicant: Eric D. Nyberg

    Inventor: Eric D. Nyberg

    Abstract: A electrochemical cell for removing ions from a solution stream comprises a housing having first and second electrodes. At least one water-splitting ion exchange membrane is positioned between the electrodes, the water-splitting membrane comprising (i) a cation exchange surface facing the first electrode, and (ii) an anion exchange surface facing the second electrode. A solution stream pathway is defined by the water-splitting membrane. The solution stream pathway comprises (i) an inlet for influent solution stream, (ii) at least one channel that allows influent solution stream to flow past at least one surface of the water-splitting membrane to form one or more treated solution streams, and (iii) a single outlet that combines the treated solution streams to form a single effluent solution. Preferably, the solution stream pathway comprises a unitary and contiguous channel that flows past both the cation and anion exchange surfaces of the water-splitting membrane, and more preferably is connected throughout in an unbroken sequence and extends substantially continuously from the inlet to the outlet.

    Abstract translation: 用于从溶液流中除去离子的电化学电池包括具有第一和第二电极的壳体。 至少一个水分解离子交换膜位于电极之间,水分解膜包括(i)面向第一电极的阳离子交换表面,和(ii)面对第二电极的阴离子交换表面。 溶液流通道由水分解膜限定。 溶液流路径包括(i)流入溶液流的入口,(ii)允许流入溶液流流过水分解膜的至少一个表面以形成一个或多个处理的溶液流的至少一个通道,以及 (iii)将处理的溶液流组合以形成单一流出物溶液的单个出口。 优选地,溶液流路径包括流过水分解膜的阳离子和阴离子交换表面的整体和连续的通道,并且更优选地以不间断的顺序连接并且从入口到出口基本连续地延伸。

    Cylindrical electrolyzer assembly and method
    400.
    发明授权
    Cylindrical electrolyzer assembly and method 失效
    圆柱电解槽总成及方法

    公开(公告)号:US5753098A

    公开(公告)日:1998-05-19

    申请号:US635823

    申请日:1996-04-22

    Abstract: An electrolyzer assembly has an outer, cylindrical dielectric electrolyzer housing member having a top, bottom, and cylindrical side wall. In one embodiment, the housing member has a sealed top, an open bottom for electrolyte entry, and apertures through the side wall near the sealed top permitting flow of electrolyte through the apertures. A cylindrical anode and cathode pair is situated inside the housing member. The cathode is positioned concentrically within the anode. Electrolyte flows in the space between anode and cathode. The anode is spaced apart from the side wall, providing an electrolyte flow path through the resulting cylindrically-shaped space. Electrical connections through the top of the housing member extend downwardly therein to electrical connection elements projecting upwardly from the electrode pair. The assembly provides for ease of cleaning, as well as ease of refurbishing, and operates efficiently and economically in both forced and unforced flow conditions.

    Abstract translation: 电解器组件具有外圆柱形介电电解器壳体构件,其具有顶部,底部和圆柱形侧壁。 在一个实施例中,壳体构件具有密封的顶部,用于电解质进入的开口底部,以及通过密封顶部附近的侧壁的孔,允许电解液通过孔流动。 圆柱形阳极和阴极对位于壳体内。 阴极同心地位于阳极内。 电解液在阳极和阴极之间的空间中流动。 阳极与侧壁间隔开,提供通过所得到的圆柱形空间的电解质流动路径。 通过壳体构件的顶部的电气连接向下延伸到从电极对向上突出的电连接元件。 该组件提供易于清洁以及易于翻新,并且在强制和非强制流动条件下有效和经济地操作。

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