Abstract:
Cyclopolyenic 1,3-diethers wherein the carbon atom in position 2 belongs to a particular cyclic or polycyclic structure containing two or three unsaturations, solid catalyst components and catalysts therefrom, the catalysts comprising the reaction product of: i. a solid catalyst component containing an internal donor; ii. an Al-alkyl compound, and optionally iii. an external donor; the internal donor and/or the external donor being cyclopolyenic 1,3-diethers. The catalysts are useful for the polymerization of alpha-olefins.
Abstract:
A process for preparing a diether-based catalyst component in which: a) a slurry is obtained by contacting a solid support comprising a magnesium halide or a precursor thereof, one or more 1,3-diethers and a liquid phase containing a titanium compound, and b) the obtained slurry is then subjected to a solid/liquid separation step in order to isolate a diether-based catalyst component; said separation step b) being characterized in that the ratio between the solid/liquid separation velocity and the final amount of separated solid must be higher than 0.5 liter/(min·Kg).
Abstract:
A polypropylene composition made from or containing: A) from 71 wt % to 91 wt % of a propylene homopolymer, B) from 5 wt % to 15 wt % of a copolymer of propylene and ethylene containing from 18 wt % to 32.0 wt % of ethylene derived units; and C) from 4 wt % to 15 wt % of a copolymer of propylene and ethylene containing from 75 wt % to 90.0 wt % of ethylene derived units.
Abstract:
A propylene polymer composition made from or containing: A) 65 to 95 wt % of a polypropylene composition having a MFR (230° C./2.16 kg) from 0.2 to 1.2 g/10 min, made from or containing (a) 15 to 45 wt % of a fraction made from or containing a propylene homopolymer, or a copolymer of propylene with ethylene or a CH2═CHR alpha-olefin, having a fraction insoluble in xylene at 25°° C. for at least 90 wt %; and (b) 55 to 75 wt % of a fraction made from or containing a copolymer of ethylene with propylene or CH2═CHR alpha-olefins, containing ethylene derived-units in a quantity lower than 40 wt %, and having solubility in xylene at 25° C. greater than 60 wt %, and (B) 5 to 35 wt % of recycled styrene block copolymer having a melt flow rate (190° C./2.16 Kg) from 0.5 to 15 g/10 min, wherein the propylene polymer composition having a MFR from 0.4 to 1.4 g/10 min.
Abstract:
A polypropylene-based resin composition made from or containing (A) a polypropylene-based resin including (a1) a continuous phase consisting of a propylene polymer and (a2) a rubber phase consisting of a copolymer of ethylene and an α-olefin having 3-10 carbon atoms.
Abstract:
A polyolefin composition made from or containing:
A) 5-35% by weight of a propylene ethylene copolymer; B) 20-50% by weight of an ethylene homopolymer; and C) 30-60% by weight of a terpolymer of ethylene, propylene and 1-butene derived units.
Abstract:
A catalyst for the polymerization of olefins made from or containing (a) a solid catalyst component containing Mg, Ti and optionally an internal electron donor compound (ID), (b) an aluminum alky compound, and (c) an external electron donor (ED) selected from non-aromatic diazo compounds.
Abstract:
A mixture made from or containing T1) from 99 wt % to 75 wt % of bitumen, and T2) from 1 wt % to 25 wt % of a polymer composition made from or containing A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 20-50% by weight of a copolymer of ethylene and a C3-C8 alpha-olefin containing from 1.0% to 20.0% by weight of alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene containing from 25.0% to 75.0% by weight of ethylene derived units.
Abstract:
A Ziegler-Natta catalyst component precursor made from or containing a mechanical mixture of (a) distinct particles of adducts of formula MgCl2(R1OH)n where R is a C1-C8 alkyl group and n is from 0.2 to 6 having average particle size (P50a) ranging from 5 to 100 μm; and (b) from 0.2 to 5.0% by weight of distinct particles of a solid compound containing more than 50% by weight of Sift units and having average particle size (P50b), wherein the ratio P50b/P50a ranges from 0.4 to 1.5.
Abstract:
Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The catalytic compositions are mixed metal oxides demonstrating equal or higher conversion than noncatalytic pyrolysis. These mixed metal oxide catalysts and a polyolefin-based material are heated in the presence of oxygen to form a product comprising one or more olefin monomers.