公开(公告)号：US20040054050A1

公开(公告)日：2004-03-18

申请号：US10382982

申请日：2003-03-07

申请人： ATOFINA

发明人： Thierry Pascal ,  Bruno Schlund

IPC分类号： C08K005/09 ,  C08L027/12

CPC分类号： C08F14/08 ,  C08K5/11 ,  C08K5/435 ,  C08L27/16 ,  C08L2205/02 ,  C08L2666/04

摘要： The present invention relates to a flexible and tough composition comprising: at least one vinylidene fluoride (VF2) homopolymer (A) or a copolymer (A) of VF2 and at least one other monomer copolymerizable with VF2, in which the said monomer is present in an amount of between 0 and 30 parts by weight per 100 parts by weight of VF2, at least one fluoroelastomer B, optionally a plasticizer C, in which, on the one hand, the said composition comprises from 0.5 to 10 parts by weight of B and from 0 to 10 parts by weight of C per 100 parts by weight of A, with the additional condition that the sum of B and C is from 0.5 to 10.5 parts by weight and, on the other hand, the vinylidene fluoride homopolymer or copolymer (A) is chosen in such a way that it has a melt flow index, measured according to the ISO 1133 standard at 230null C. under a load of 5 kg, of less than 5 g/10 min and a critical modulus GC, at the intersection of the melt shear moduli Gnull and Gnull measured at 190null C., of between 5 and 22 kPa. This composition is especially used for the manufacture of pipes for conveying hydrocarbons extracted from off-shore or on-shore oil deposits.

摘要翻译： 本发明涉及一种柔性和韧性组合物，其包含：至少一种偏氟乙烯（VF2）均聚物（A）或VF2的共聚物（A）和至少一种可与VF2共聚的其它单体，其中所述单体存在于 相对于每100重量份VF2为0至30重量份的量，至少一种含氟弹性体B，任选的增塑剂C，其中所述组合物一方面包含0.5至10重量份的B 和相对于每100重量份的A为0至10重量份的C，另外条件是B和C的总和为0.5至10.5重量份，另一方面，偏二氟乙烯均聚物或共聚物 （A）的选择使得其具有根据ISO 1133标准在230℃，5kg负荷下小于5g / 10min测量的熔体流动指数和临界模量GC， 在190℃下测量的熔体剪切模量G'和G“的交点处在5μA之间 d 22 kPa。 该组合物特别用于制造用于输送从离岸或岸上油沉积物中提取的烃的管道。

公开(公告)号：US20040028921A1

公开(公告)日：2004-02-12

申请号：US10408651

申请日：2003-04-08

申请人： ATOFINA

发明人： Nicolas Amouroux

IPC分类号： B32B015/00

CPC分类号： C09D177/00 ,  C08F255/02 ,  C08L23/08 ,  C08L51/06 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C09D151/06 ,  C09D177/02 ,  C09D177/06 ,  Y10T428/12799 ,  Y10T428/12972 ,  Y10T428/31681 ,  Y10T428/31685 ,  Y10T428/31725 ,  C08L2666/14 ,  C08L2666/20 ,  C08L23/00 ,  C08L51/00

摘要： A metal surface is coated with a coating comprising, in succession starting from the metal: optionally, a primer layer; optionally, a tie layer; and a polyamide-based layer consisting of a blend of a polyamide and of a polyolefin functionalized by an unsaturated carboxylic acid anhydride. Advantageously, the metal surface is the outer surface of a tube, particularly a small-diameter pipe having, for example, an outside diameter of 4 to 50 mm. The metal may be any metal, but the coating is very useful for steel and its alloys and for aluminium and its alloys. The optionally, a tie layer; aluminium may be anodized. Thus, the coated surface can comprise aluminium, the anodizing layer, the optional primer, the optional tie and the PA-based layer. The steel may be coated with zinc or a Zn-based alloy (such as, for example, a ZnnullAl or ZnnullFe mixture) or with aluminium or an Al-based alloy and/or treated by chromatizing or phosphatizing. Thus, the coated surface can comprise steel, the optional zinc or aluminium layer, the optional chromatizing or phosphatizing treatment layer, the optional primer, the optional tie and the PA-based layer. Preferably, the chromatizing is carried out with CrIII.

摘要翻译： 金属表面涂覆有涂层，其从金属开始连续地包括：任选的底漆层; 可选地，连接层; 以及由聚酰胺和由不饱和羧酸酐官能化的聚烯烃的共混物构成的聚酰胺类层。 有利地，金属表面是管的外表面，特别是具有例如外径为4至50mm的小直径管。 金属可以是任何金属，但涂层对于钢及其合金以及铝及其合金非常有用。 可选地，连接层; 铝可以被阳极氧化。 因此，涂覆的表面可以包括铝，阳极氧化层，任选的底漆，可选的连接和基于PA的层。 钢可以用锌或Zn基合金（例如Zn-Al或Zn-Fe混合物）或铝或Al-基合金涂覆和/或通过色化或磷化处理。 因此，涂覆的表面可以包括钢，任选的锌或铝层，任选的着色或磷化处理层，任选的底漆，可选的连接和基于PA的层。 优选地，用Cr 进行染色。

公开(公告)号：US20040001954A1

公开(公告)日：2004-01-01

申请号：US10608149

申请日：2003-06-30

申请人： ATOFINA

发明人： Alexander Korzhenko ,  Emmanuel Rastelletti ,  R.G Sharpe-Hill

IPC分类号： B32B009/04

CPC分类号： C08K3/08 ,  C08K3/01 ,  C08K3/04 ,  C08K3/22 ,  Y10T428/30 ,  Y10T428/31504 ,  Y10T428/3154 ,  C08L27/16

摘要： The present invention relates to a composite material comprising, by weight, the total being 100% : A) 40 to 90% of PVDF homopolymer or copolymer crystallized essentially in the null form, B) 10 to 60% of a conductive filler, C) 0 to 40% of a crystalline or semi-crystalline polymer, D) 0 to 40% of a filler other than C, such that the crystals in the null form are nucleated on the surface of the particles of the conductive filler. This material is conductive with a resistance which is self-regulated by the temperature. It shows an increase in the resistance as a function of the temperature (PTC or nullPositive Temperature Coefficientnull effect), so that the intensity stabilizes at an equilibrium temperature.

公开(公告)号：US20030225165A1

公开(公告)日：2003-12-04

申请号：US10253242

申请日：2002-09-24

申请人： ATOFINA Chemicals, Inc.

发明人： Jinhuang Wu ,  Douglas R. Dillon

IPC分类号： C08J009/00 ,  C08G018/00

CPC分类号： C08J9/149 ,  C08G18/42 ,  C08G2101/0025 ,  C08J2203/14 ,  C08J2203/142

摘要： Foam blowing agent blends of trans-1,2-dichloroethylene and one or more pentanes are provided, as are polyol premixes and foam compositions containing such blends. The resulting foams exhibit dramatic improvement in fire resistance.

摘要翻译： 提供反式1,2-二氯乙烯和一种或多种戊烷的泡沫发泡剂共混物，以及含有这种共混物的多元醇预混物和泡沫组合物。 所产生的泡沫在耐火性方面表现出显着的改善。

公开(公告)号：US20030220519A1

公开(公告)日：2003-11-27

申请号：US10411379

申请日：2003-04-11

申请人： ATOFINA

发明人： Alain Riondel ,  Jacqueline Bessalem

IPC分类号： C07C069/52

CPC分类号： C07C67/08 ,  C07C69/54

摘要： Butyl acrylate is prepared by reacting acrylic acid and butanol in a reactor in the presence of an esterification catalyst the water formed being entrained by distillation in a column (2) in the form of a heteroazeotropic mixture with butanol mixture following condensation, being separated in a decanter (3) to give an upper, organic phase which is recycled to the top of the distillation column (2) and a lower, aqueous phase which is drawn off. The reaction is conducted with deferred introduction of part of the butanol at the top of the distillation column (2) or to the decanter (3) or to the reactor (1), the butanol/acrylic acid molar ratio being initially between 0.5 and 1 before rising to between 1 and 1.5 following the completion of the deferred introduction of the butanol.

摘要翻译： 丙烯酸丁酯通过在反应器中在酯化催化剂存在下使反应器中的丙烯酸和丁醇反应来制备，所形成的水通过蒸馏在柱（2）中以与冷凝后的丁醇混合物的混合物形式的蒸馏夹带，在 滗析器（3），得到上部有机相，再循环到蒸馏塔（2）的顶部，并将较低的水相排出。 反应是在蒸馏塔（2）的顶部或蒸馏塔（3）或反应器（1）中延迟引入部分丁醇进行的，丁醇/丙烯酸摩尔比最初在0.5和1之间 在丁醇延迟引入完成后升至1至1.5之间。

公开(公告)号：US20030088010A1

公开(公告)日：2003-05-08

申请号：US10268934

申请日：2002-10-11

申请人： Atofina

发明人： Thierry Senninger

IPC分类号： C08K003/34

CPC分类号： C08K3/34 ,  C08F6/006 ,  C08K7/26 ,  C08L23/08

摘要： The invention relates to a process for trapping a free monomer which has not reacted by copolymerization or by grafting comprising at least one epoxide functional group in a thermoplastic composition based on ethylene and/or on propylene and based on at least one monomer comprising at least one epoxide functional group, the said process comprising the following stages: preparation of the said thermoplastic composition, addition of a sufficient amount of a solid trapping additive exhibiting, at its surface, sites with a basic nature within the Lewis or Brnullnsted meaning. The trapping additive is a porous zeolite, the diameter of the pores of which is between 5 and 15 angrstrnullms, preferably between 6 and 13 angrstrnullms. The invention also relates to the composition obtained by such a process and to the blends comprising such a composition.

摘要翻译： 本发明涉及一种捕获未在基于乙烯和/或丙烯的热塑性组合物中通过共聚或通过接枝包含至少一个环氧官能团的游离单体的方法，并且基于至少一种包含至少一种 环氧官能团，所述方法包括以下步骤：制备所述热塑性组合物，加入足量的固体捕获添加剂，其表面具有在路易斯或布朗斯台德含义内具有碱性的位点。 捕集添加剂是一种多孔沸石，孔的直径为5至15埃，优选6至13埃。 本发明还涉及通过这种方法获得的组合物和包含这种组合物的共混物。

公开(公告)号：US20030032836A1

公开(公告)日：2003-02-13

申请号：US10173567

申请日：2002-06-18

申请人： ATOFINA

发明人： Gilles Drivon ,  Jean-Philippe Gillet ,  Christophe Ruppin

IPC分类号： C07C069/63 ,  C07C051/16

CPC分类号： C07C51/58 ,  C07C67/00 ,  C07C69/63

摘要： The invention relates to a method for preparing bromodifluoroacetic compounds which comprises converting a 1,1-diflouro-1,2-dibromodihaloethane with oleum having 50-70% SO3 to a bromodifluoroacetyl halide (bromide or chloride) and then in reacting the latter directly with either an alcohol, or with water.

摘要翻译： 本发明涉及一种制备溴二氟乙酸化合物的方法，其包括将具有50-70％SO 3的发烟硫酸的1,1-二溴-1,2,2-二溴二卤代乙烷与溴二氟乙酰卤（溴化物或氯化物）反应，然后将其与 不管是酒精还是用水。

公开(公告)号：US20020193545A1

公开(公告)日：2002-12-19

申请号：US10132691

申请日：2002-04-26

申请人： ATOFINA

发明人： Alain Riondel

IPC分类号： C07C229/30

CPC分类号： C07C213/08 ,  C08F20/34 ,  C07C219/08

摘要： A compound of formula (I) is prepared alone or in combination with at least one monomer of formula (II): the quaternizing agents benzyl chloride is introduced into a solution, in a solvent selected from compounds of the formulae (I) and (II) and mixtures of these, of the compound of formula (III) at a temperature of from 35 to 60null C., and then water is added and the reaction is allowed to proceed to complete or substantially complete conversion of the compound (III), an aqueous solution of desired compound (I) is isolated where appropriate with at least one compound (II), if this or these have/has been used as solvent, and the water is removed where appropriate. 1

摘要翻译： 式（I）化合物单独或与至少一种式（II）单体组合制备：将季铵化剂苄基氯引入溶液中，在选自式（I）和（II）的化合物的溶剂中 ）和这些的混合物，式（III）的化合物在35至60℃的温度下，然后加入水，并使反应进行以完成或基本上完全转化化合物（III） 如果这些或这些已经/已经被用作溶剂，则在适当的时候用至少一种化合物（II）分离所需化合物（I）的水溶液，并在适当的情况下除去水。

公开(公告)号：US20020168569A1

公开(公告)日：2002-11-14

申请号：US10100181

申请日：2002-03-19

申请人： ATOFINA

发明人： Benoit Barriere ,  Philippe Bussi

IPC分类号： H01M004/62 ,  H01M004/66 ,  H01M002/16 ,  H01M004/48

CPC分类号： H01M4/621 ,  H01M2/164 ,  H01M4/623

摘要： The present invention relates to a lithium-ion battery element which is chosen from the separator and the electroactive layers and which results from the forming of a microcomposite powder comprising a fluoropolymer in the form of particles between 0.1 and 0.5 nullm in size and fillers. The present invention also relates to a lithium-ion battery electrode comprising the above electroactive layer combined with a metal layer. The present invention also relates to a lithium-ion battery comprising at least one element such as the separator, the electroactive layer or the electrode defined above. This microcomposite powder can be prepared by coatomization of an aqueous solution containing the fluoropolymer particles between 0.1 and 0.5 nullm in size and of an aqueous solution of the fillers. It can also be prepared by flocculation or coagulation of an aqueous solution containing the fluoropolymer particles between 0.1 and 0.5 nullm in size and of an aqueous solution of the fillers. The forming of this microcomposite powder consists in preferably forming a film in order to obtain an electrode film or a separator film. Next, these films are joined together to form a battery. This step (assembly, electrolyte filling, packaging, etc.) is known per se.

摘要翻译： 本发明涉及从隔板和电活性层中选择的锂离子电池元件，其由微粒复合材料粉末形成，该微复合材料粉末的尺寸为0.1至0.5μm之间的颗粒形式的含氟聚合物和填料。 本发明还涉及包含与金属层组合的上述电活性层的锂离子电池电极。 本发明还涉及一种锂离子电池，其包含至少一种元件，例如隔膜，电活性层或上述定义的电极。 该微复合粉末可以通过将包含0.1至0.5μm的含氟聚合物颗粒的水溶液和填料的水溶液进行共解聚来制备。 也可以通过使含有0.1〜0.5μm的含氟聚合物粒子的水溶液和填料的水溶液的絮凝或凝结来制备。 这种微复合粉末的形成在于优选形成膜以获得电极膜或隔膜。 接下来，将这些膜连接在一起形成电池。 本步骤（组装，电解液填充，包装等）本身是已知的。

公开(公告)号：US20020136941A1

公开(公告)日：2002-09-26

申请号：US09988801

申请日：2001-11-20

申请人： ATOFINA

发明人： Anthony Bonnet ,  Karine Triballier ,  Philippe Bussi ,  Michael Burchill ,  Michel Foure

IPC分类号： H01M008/02 ,  H01M004/58 ,  H01M004/62 ,  H01B001/24

CPC分类号： H01M4/96 ,  B82Y30/00 ,  H01B1/24 ,  H01M4/8605 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/1007 ,  Y02P70/56 ,  Y10T428/2982 ,  Y10T428/2998

摘要： The present invention relates to a microcomposite powder comprising particles from 1 um to 300 um of an electrically conductive product, which are coated with particles from 0.1 nullm to 0.5 nullm of a fluoropolymer. According to one advantageous form of the invention the microcomposite powder comprises a product (A) which is a polymer or an oligomer which can be dissolved with a solvent which is not a solvent for the fluoropolymer or for the electrically conductive product. The present invention also relates to objects consisting of this powder. These objects may be bipolar plates for fuel cells, or supercapacitor components.

摘要翻译： 本发明涉及一种微复合粉末，其包含1μm至300μm的导电产品的颗粒，其涂覆有0.1至0.5μm的含氟聚合物的颗粒。 根据本发明的一个有利形式，微复合粉末包含产物（A），其是聚合物或低聚物，其可以与不是氟聚合物或导电产物的溶剂的溶剂一起溶解。 本发明还涉及由该粉末组成的物体。 这些物体可以是用于燃料电池或超级电容器部件的双极板。