Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
    41.
    发明授权
    Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof 失效
    清洁产品,包括通过亚乙烯基烯烃制备的改进的烷基芳基磺酸盐表面活性剂及其制备方法

    公开(公告)号:US06566319B1

    公开(公告)日:2003-05-20

    申请号:US09478906

    申请日:2000-01-07

    IPC分类号: C11D1700

    摘要: Cleaning compositions, especially laundry detergents and the like, comprising (i) modified alkylarylsulfonate surfactants, e.g., modified alkylbenzenesulfonates, which are the product of particular processes and (ii) cleaning adjuncts such as enzymes and bleaches. Processes for making the cleaning products, including processes comprising vinylidene olefin production, alkylation of arenes, sulfonation and domestic cleaning product formulation. VO production is used to introduce particular limited branching into an alpha-olefinic feedstock which, converted to dimer form, has from about 10 to about 16, preferably from about 12 to about 14 carbon atoms. Preferred processes maximize the amount of vinylidene olefin useful for detergent manufacture, and minimize deep internal olefin production. Further, an alkylation step, preferably having an internal isomer selectivity of from 0 to no more than about 40 is used, in which the VO monoalkylates arenes such as benzene, in presence of an alkylation catalyst preferably comprising an at least partially crystalline, porous zeolite-containing solid, the zeolite being at least partially acidic and having intermediate pore size. Preferred alkylation catalysts include at least partially dealuminized acidic mordenites.

    摘要翻译: 清洁组合物,特别是衣物洗涤剂等,其包含(i)改性的烷基芳基磺酸盐表面活性剂,例如改性烷基苯磺酸盐,其是特定方法的产物和(ii)清洁助剂如酶和漂白剂。 用于制造清洁产品的方法,包括包含亚乙烯基烯烃生产,芳烃烷基化,磺化和家用清洁产品配方的方法。 VO生产用于将特定有限的支化物引入α-烯烃原料中,其转化为二聚体形式具有约10至约16个,优选约12至约14个碳原子。 优选的方法使用于洗涤剂制造的亚乙烯基烯烃的量最大化,并使内部烯烃的生产最小化。 此外,使用优选具有0至不大于约40的内部异构体选择性的烷基化步骤,其中在烷基化催化剂存在下,优选包含至少部分结晶的多孔沸石的VO单烷基化物芳烃如苯 所述沸石至少部分为酸性且具有中等孔径。 优选的烷基化催化剂包括至少部分脱铝的酸性丝光沸石。

    FABRIC SOFTENING LAUNDRY DETERGENTS WITH GOOD STABILITY
    46.
    发明申请
    FABRIC SOFTENING LAUNDRY DETERGENTS WITH GOOD STABILITY 有权
    织物清洁洗涤剂具有良好的稳定性

    公开(公告)号:US20090293207A1

    公开(公告)日:2009-12-03

    申请号:US12473483

    申请日:2009-05-28

    IPC分类号: C11D17/00 D06F23/00

    摘要: An aqueous laundry detergent composition in the form of a liquid or gel, having a pH of from about 6 to about 11 in a 1% water solution and containing a non-soap anionic surfactant; soap; nonionic surfactant; fabric softening cationic cosurfactant having a molecular weight of less than about 1000; fabric softening quaternized polymer having a molecular weight of at least 100,000; non-quaternized, non polyamine thickener; perfume microcapsules; wherein at least one of the following is true; i) the ratio by weight of nonionic surfactant to anionic surfactant is greater than 1 and the total percentage, by weight of the composition, of the total of anionic surfactant, nonionic surfactant and soap is from 10% to 30%; and/or ii) the aqueous laundry detergent composition further comprises from about 0.5% to about 5% of a hydrotrope. Methods of laundering with such compositions.

    摘要翻译: 一种液体或凝胶形式的含水衣物洗涤剂组合物,其在1%水溶液中的pH为约6至约11,并含有非皂阴离子表面活性剂; 肥皂; 非离子表面活性剂 织物柔软的阳离子辅助表面活性剂,其分子量小于约1000; 织物软化季铵化聚合物,其分子量至少为100,000; 非季铵化,非多胺增稠剂; 香水微胶囊; 其中以下中的至少一个是真实的; i)非离子表面活性剂与阴离子表面活性剂的重量比大于1,阴离子表面活性剂,非离子表面活性剂和皂的总量占组合物总重量的百分比为10%至30%。 和/或ii)水性衣物洗涤剂组合物还包含约0.5%至约5%的水溶助长剂。 用这种组合物洗涤的方法。

    Liquid laundry detergent compositions with silicone blends as fabric care agents
    48.
    发明授权
    Liquid laundry detergent compositions with silicone blends as fabric care agents 有权
    具有硅酮共混物作为织物护理剂的液体衣物洗涤剂组合物

    公开(公告)号:US07335630B2

    公开(公告)日:2008-02-26

    申请号:US11107177

    申请日:2005-04-15

    IPC分类号: C11D9/36

    摘要: The invention is directed to aqueous liquid laundry detergent compositions for cleaning and imparting fabric care benefits to fabrics laundered therewith. Such compositions comprise (A) at least one detersive surfactant; (B) droplets of a silicone blend comprising a nitrogen-containing amino or ammonium functionalized polysiloxane and a nitrogen-free non-functionalized polysiloxane; and (C) at least one additional non-silicone laundry adjunct selected from detersive enzymes, dye transfer inhibiting agents, optical brighteners, suds suppressors and combinations thereof. The functionalized polysiloxane component of the silicone blend has a relatively low, i.e., less than 30 mol %, content of reactive/curable groups, a nitrogen content which ranges from 0.05% to 0.30% by weight and a viscosity which ranges from 0.00002 m2/s to 0.2 m2/s. The nitrogen-free non-functionalized polysiloxane material ranges in viscosity from 0.01 m2/sec to 2.0 m2/sec. The silicone blend is preferably used in a pre-formed emulsion which can be added to the balance of the detergent composition to form the droplets of the silicone blend which are dispersed in the detergent composition.

    摘要翻译: 本发明涉及用于清洗并赋予织物洗涤织物护理益处的含水液体衣物洗涤剂组合物。 这样的组合物包含(A)至少一种去污表面活性剂; (B)包含含氮氨基或铵官能化聚硅氧烷和无氮非官能化聚硅氧烷的硅氧烷共混物的液滴; 和(C)至少一种选自除虫酶,染料转移抑制剂,荧光增白剂,抑泡剂及其组合的非硅氧烷洗衣助剂。 硅氧烷共混物的官能化聚硅氧烷组分具有相对低的,即小于30mol%的反应性/可固化基团的含量,氮含量为0.05-0.30%(重量),粘度范围为0.00002m 2, SUP> 2 / s至0.2m 2 / s。 无氮非官能化聚硅氧烷材料的粘度范围为0.01m 2 / sec至2.0m 2 / sec。 硅氧烷共混物优选用于预先形成的乳液中,其可以加入到洗涤剂组合物的余量中以形成分散在洗涤剂组合物中的硅氧烷共混物的液滴。