Allophanates of polymeric MDI
    41.
    发明授权
    Allophanates of polymeric MDI 失效
    聚合MDI的脲基甲酸酯

    公开(公告)号:US06528609B1

    公开(公告)日:2003-03-04

    申请号:US10017060

    申请日:2001-12-13

    CPC classification number: C08G18/7837 C08G18/003

    Abstract: This invention relates to a process for forming an allophanate-modified polymethylene poly(phenylisocyanate) comprising the steps of reacting a small amount of epoxide, along with alcohol, to polymethylene poly(phenylisocyanate) (PMDI) to form an intermediate, which is converted to allophanate upon addition of a metal divalent catalyst. This invention also relates to a process for forming an allophanate-modified PMDI comprising the steps of adding a small amount of epoxide, to PMDI to form an intermediate, which is converted to allophanate upon addition of an alcohol and a metal divalent catalyst. Both processes according to the invention of preparing allophanate-modified PMDI use mild conditions and low catalyst levels to yield viscosity stable products.

    Abstract translation: 本发明涉及形成脲基甲酸酯改性聚亚甲基聚(异氰酸苯酯)的方法,包括以下步骤:将少量环氧化物与醇反应到聚亚甲基聚(异氰酸苯酯)(PMDI)以形成中间体,将其转化为 加入金属二价催化剂。 本发明还涉及形成脲基甲酸酯改性的PMDI的方法,包括以下步骤:向PMDI中加入少量环氧化物以形成中间体,其在加入醇和金属二价催化剂时转化成脲基甲酸酯。 根据本发明制备脲基甲酸酯改性PMDI的两种方法都使用温和条件和低催化剂水平来产生粘度稳定的产物。

    Polyether polyols based on triazole group containing compounds and a
process for their production
    44.
    发明授权
    Polyether polyols based on triazole group containing compounds and a process for their production 有权
    基于含三唑基的化合物的聚醚多元醇及其制备方法

    公开(公告)号:US6022937A

    公开(公告)日:2000-02-08

    申请号:US199223

    申请日:1998-11-24

    CPC classification number: C07D249/18 C08G18/5021 C08G65/263

    Abstract: This invention relates to novel polyether polyols and to a process for their production. These polyether polyols are prepared by forming a polyhydroxyl group containing component in a first step by the reaction of a triazole-group containing compound with a compound that contains at least one functional group that is capable of reacting with the amine groups of the triazole group containing compound, and reacting the hydroxyl-group containing component with an alkylene oxide to form the polyether polyol of the invention. The present invention also relates to isocyanate-reactive compositions comprising these novel polyether polyols, and to a process for the production of a polyurethane comprising reacting a polyisocyanate with the novel polyether polyols of the present invention.

    Abstract translation: 本发明涉及新型聚醚多元醇及其生产方法。 这些聚醚多元醇通过在第一步中形成含多羟基的成分,通过使含三唑基化合物与含有至少一个能够与含三唑基的胺基反应的官能团的化合物 化合物,并使含羟基的组分与烯化氧反应形成本发明的聚醚多元醇。 本发明还涉及包含这些新型聚醚多元醇的异氰酸酯反应性组合物以及用于生产聚氨酯的方法,其包括使多异氰酸酯与本发明的新型聚醚多元醇反应。

    Process for the production of secondary amines and the amines produced
by the process
    46.
    发明授权
    Process for the production of secondary amines and the amines produced by the process 失效
    用于生产仲胺和通过该方法生产的胺的方法

    公开(公告)号:US5739397A

    公开(公告)日:1998-04-14

    申请号:US655638

    申请日:1996-05-30

    CPC classification number: C07C209/16

    Abstract: Secondary amines having a hydrocarbon backbone, a functionality of at least 1 and a molecular weight of at least 74 are produced by reacting a hydrocarbon containing a leaving group with a primary amine, primary diamine, primary polyamine or ammonia at a temperature of from about 70.degree. to 250.degree. C.

    Abstract translation: 具有烃骨架,官能度至少为1且分子量至少为74的仲胺通过使含离去基团的烃与伯胺,伯胺,伯胺或氨在约70℃的温度下反应来制备 DEG至250℃

    Color reduction of polymethylene polyphenyl polyisocyanates
    47.
    发明授权
    Color reduction of polymethylene polyphenyl polyisocyanates 失效
    聚亚甲基多苯基多异氰酸酯的着色还原

    公开(公告)号:US5312971A

    公开(公告)日:1994-05-17

    申请号:US920229

    申请日:1992-07-23

    CPC classification number: C07C263/10 C08G18/7664

    Abstract: The present invention is directed to a process for the production of polymethylene polyphenyl polyisocyanates by phosgenating the corresponding polyamines in solution in an inert organic solvent, removing excess phosgene, and stripping the solvent. The improvement resides in adding at least 0.02 parts by weight of reducing agent per 150 parts by weight of polyamine to the polyamines at any time prior to the stripping step.

    Abstract translation: 本发明涉及通过在惰性有机溶剂中将溶液中相应的多胺光气化,除去过量的光气和汽提溶剂来生产多亚甲基多苯基多异氰酸酯的方法。 改进之处在于在汽提步骤之前的任何时间将至少0.02重量份的还原剂每150重量份的多胺添加到多胺中。

    Hybrid PHD/PMPO polyols for polyurethane foam applications
    48.
    发明授权
    Hybrid PHD/PMPO polyols for polyurethane foam applications 有权
    用于聚氨酯泡沫塑料应用的混合PHD / PMPO多元醇

    公开(公告)号:US08946313B2

    公开(公告)日:2015-02-03

    申请号:US13327879

    申请日:2011-12-16

    Abstract: This invention relates to hybrid polymer polyols. These hybrid polymer polyols comprise the free-radical polymerization product of (A) a base polyol comprising (1) a polymer modified polyol selected from (a) dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl group containing compound and (b) polyisocyanate polyaddition polyols, and (2) optionally, a polyol having a functionality of 2 to 6 and an OH number of from 20 to 500; (B) optionally, a preformed stabilizer; and (C) one or more ethylenically unsaturated monomers, in the presence of (D) a free-radical polymerization initiator, and (E) optionally, a polymer control agent. The present invention also relates to a process for the preparation of these hybrid polymer polyols, foams prepared from these hybrid polymer polyols and to a process for the preparation of these foams.

    Abstract translation: 本发明涉及杂化聚合物多元醇。 这些杂化聚合物多元醇包含(A)基础多元醇的自由基聚合产物,其包含(1)聚合物改性的多元醇,其选自(a)在含羟基的化合物中的聚脲和/或聚二氢二碳酰胺的分散体和(b)聚异氰酸酯加聚 多元醇,和(2)任选的官能度为2至6且OH数为20至500的多元醇; (B)任选的预成型稳定剂; 和(C)一种或多种烯属不饱和单体,在(D)自由基聚合引发剂存在下,和(E)任选的聚合物控制剂。 本发明还涉及制备这些杂化聚合物多元醇的方法,由这些杂化聚合物多元醇制备的泡沫以及制备这些泡沫的方法。

    Polyether polyols with increased functionality
    50.
    发明授权
    Polyether polyols with increased functionality 失效
    具有增加功能性的聚醚多元醇

    公开(公告)号:US06548564B1

    公开(公告)日:2003-04-15

    申请号:US10016846

    申请日:2001-12-13

    CPC classification number: C08G65/337 C08G18/5063 C08G65/33317

    Abstract: This invention relates to a process for the preparation of a polyether polyol having a functionality of at least about 3, a molecular weight of from about 560 to about 35,000 and an OH number of from about 10 to about 1,100. This process comprises reacting (a) a polyether polyol containing one or more ether groups, having a functionality of about 2 to about 8, a molecular weight of about 106 to about 12,000, and an OH number of about 28 to about 1,400, with (b) cyanuric chloride, optionally, in the presence of (c) one or more catalysts; wherein the functionality of the resultant polyether polyols equals three times the functionality of (a) said polyether polyol, minus three. This invention also relates to the process of reacting a polyether polyol, formed by the stated reaction with cyanuric chloride, with an alkylene oxide, optionally in the presence of a catalyst, to form a polyether polyol that has a higher molecular weight and a functionality greater than or equal to the functionality of the polyether polyol used as the starter in this process.

    Abstract translation: 本发明涉及制备具有至少约3,分子量约560至约35,000和OH数约10至约1,100的官能度的聚醚多元醇的方法。 该方法包括使(a)包含一个或多个醚基的聚醚多元醇,其官能度为约2-约8,分子量为约106至约12,000,OH数为约28至约1400,与( b)氰尿酰氯,任选地,在(c)一种或多种催化剂的存在下; 其中所得聚醚多元醇的官能度等于(a)所述聚醚多元醇的官能度的三倍,减去三倍。 本发明还涉及通过所述反应形成的聚醚多元醇与氰尿酰氯与烯化氧反应的方法,任选在催化剂存在下,形成具有较高分子量和更大官能度的聚醚多元醇 大于或等于在该方法中用作起始剂的聚醚多元醇的官能度。

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