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公开(公告)号：US08323832B2
公开(公告)日：2012-12-04
申请号：US11672931
申请日：2007-02-08
CPC分类号： C01B25/45 , H01M4/136 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02T10/7011
摘要： Nanoscale ion storage materials are provided that exhibit unique properties measurably distinct from their larger scale counterparts. For example, the nanoscale materials can exhibit increased electronic conductivity, improved electromechanical stability, increased rate of intercalation, and/or an extended range of solid solution. Useful nanoscale materials include alkaline transition metal phosphates, such as LiMPO4, where M is one or more transition metals. The nanoscale ion storage materials are useful for producing devices such as high energy and high power storage batteries, battery-capacitor hybrid devices, and high rate electrochromic devices.
摘要翻译： 提供纳米级离子存储材料，其显示出与其较大规模的对应物可测量不同的独特性质。 例如，纳米尺度材料可以表现出增加的电子导电性，改善的机电稳定性，增加的嵌入速率和/或扩展的固溶体范围。 有用的纳米尺度材料包括碱金属过渡金属磷酸盐，例如LiMPO4，其中M是一种或多种过渡金属。 纳米级离子存储材料可用于制造诸如高能量和高功率蓄电池，电池 - 电容器混合器件和高速率电致变色器件的器件。
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公开(公告)号：US08088512B2
公开(公告)日：2012-01-03
申请号：US12140058
申请日：2008-06-16
CPC分类号： H01M10/0565 , H01G11/06 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/0525 , Y02E60/13
摘要： An electrochemical device includes a first electrode in electrical communication with a first current collector, a second electrode in electrical communication with a second current collector and a crosslinked solid polymer in contact with the first and second electrodes. At least one of the first and second electrodes includes a network of electrically connected particles comprising an electroactive material, and the particles of one electrode exert a repelling force on the other electrode when the first and second electrodes are combined with an uncrosslinked precursor to the solid polymer.
摘要翻译： 电化学装置包括与第一集电器电连通的第一电极，与第二集电器电连通的第二电极和与第一和第二电极接触的交联固体聚合物。 第一和第二电极中的至少一个包括包含电活性材料的电连接的颗粒的网络，并且当第一和第二电极与未交联的前体与固体组合时，一个电极的颗粒在另一个电极上施加排斥力 聚合物。
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公开(公告)号：US08057936B2
公开(公告)日：2011-11-15
申请号：US13086883
申请日：2011-04-14
IPC分类号： H01M4/58
CPC分类号： C01B25/45 , H01M4/136 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02P70/54
摘要： Nanoscale ion storage materials are provided that exhibit unique properties measurably distinct from their larger scale counterparts. For example, the nanoscale materials can exhibit increased electronic conductivity, improved electromechanical stability, increased rate of intercalation, and/or an extended range of solid solution. Useful nanoscale materials include alkaline transition metal phosphates, such as LiMPO4, where M is one or more transition metals. The nanoscale ion storage materials are useful for producing devices such as high energy and high power storage batteries, battery-capacitor hybrid devices, and high rate electrochromic devices.
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44.发明授权Self-organizing battery structure with electrode particles that exert a repelling force on the opposite electrode 有权具有在相对电极上施加排斥力的电极颗粒的自组织电池结构公开(公告)号：US07387851B2
公开(公告)日：2008-06-17
申请号：US10354673
申请日：2003-01-30
CPC分类号： H01M10/0565 , H01G11/06 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/0525 , Y02E60/13
摘要： An electrochemical device includes a first electrode in electrical communication with a first current collector, a second electrode in electrical communication with a second current collector and a crosslinked solid polymer in contact with the first and second electrodes. At least one of the first and second electrodes includes a network of electrically connected particles comprising an electroactive material, and the particles of one electrode exert a repelling force on the other electrode when the first and second electrodes are combined with an uncrosslinked precursor to the solid polymer.
摘要翻译： 电化学装置包括与第一集电器电连通的第一电极，与第二集电器电连通的第二电极和与第一和第二电极接触的交联固体聚合物。 第一和第二电极中的至少一个包括包含电活性材料的电连接的颗粒的网络，并且当第一和第二电极与未交联的前体与固体组合时，一个电极的颗粒在另一个电极上施加排斥力 聚合物。
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公开(公告)号：US06482540B1
公开(公告)日：2002-11-19
申请号：US09616700
申请日：2000-07-14
申请人： Antoni S. Gozdz , Tao Zheng
发明人： Antoni S. Gozdz , Tao Zheng
IPC分类号： H01M610
CPC分类号： H01M10/0431 , H01M10/0413
摘要： A multi-fold rechargeable battery cell structure comprising electrode elements and separator elements, wherein relief slots are formed along the fold axes of the outermost electrode elements in order to relieve folding stresses which could result in damage and impairment of the operation of the cell. The slots are formed adjacent to regions of intact electrode material in each outermost electrode element and are arranged such that the slots of one electrode element are aligned with the regions of intact electrode material of the other electrode element. In this manner, electrode element planar integrity is maintained while the effective laminate fold region thickness is reduced.
摘要翻译： 一种包括电极元件和分离器元件的多重可再充电电池单元结构，其中沿着最外电极元件的折叠轴线形成有释放槽，以便减轻可能导致电池操作的损坏和损坏的折叠应力。 在每个最外面的电极元件中，槽与完整电极材料的区域相邻地形成，并且被布置为使得一个电极元件的槽与另一个电极元件的完整电极材料的区域对齐。 以这种方式，保持电极元件的平面完整性，同时降低有效层叠折叠区域厚度。
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公开(公告)号：US5552239A
公开(公告)日：1996-09-03
申请号：US297349
申请日：1994-08-29
CPC分类号： H01M10/05 , H01M6/10 , H01M6/30 , H01M6/40 , Y10T29/49108
摘要： A rechargeable battery comprises a laminate electrolytic cell in which a flexible plasticized polymer hybrid electrolyte/separator layer is interposed between positive and negative electrode layers of lithium-ion intercalating polymeric matrix compositions bearing respective current collector foils. An elongate laminar cell is formed into a unified battery by means of an initial transverse fold disposing one electrode/collector within the structure and with subsequent sequential folds spiralling the cell, without need for interposed insulation, outwardly toward the electrode ends where the collectors accommodate battery terminals. Immersion of the structure in a solvent extracts the polymer plasticizer which is subsequently replaced by contact with lithium salt solution electrolyte to activate the battery.
摘要翻译： 可再充电电池包括层压电解池，其中柔性增塑聚合物混合电解质/隔离层插入在带有各自集电器箔的锂离子嵌入聚合物基质组合物的正电极层和负电极层之间。 细长的层状电池通过在结构内设置一个电极/集电器的初始横向折叠形成为统一的电池，并且随后的顺序折叠使电池螺旋化，而不需要插入的绝缘，朝向收集器容纳电池的电极端部 终端。 将结构浸入溶剂中提取聚合物增塑剂，随后通过与锂盐溶液电解质的接触来替代以增加电池的活性。
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47.发明授权Method of making an electrolyte activatable lithium-ion rechargeable battery cell 失效制造电解质可活化锂离子可再充电电池的方法
公开(公告)号：US5456000A
公开(公告)日：1995-10-10
申请号：US369191
申请日：1995-01-05
IPC分类号： C08J9/26 , C08J9/28 , H01M2/02 , H01M2/16 , H01M4/64 , H01M6/18 , H01M6/30 , H01M6/32 , H01M6/42 , H01M6/46 , H01M10/04 , H01M10/05 , H01M10/052 , H01M10/0565
CPC分类号： H01M10/05 , C08J9/28 , H01M10/0431 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , H01M6/32 , H01M6/46 , C08J2327/16 , H01M2300/0085 , H01M6/30 , H01M6/42 , Y02P70/54 , Y10T29/4911 , Y10T29/49114
摘要： Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated to form a unitary battery cell structure. The structure may be stored indefinitely, since it is essentially devoid of electrolyte solution which typically comprises a moisture-sensitive lithium salt. Prior to the battery's being put into service, at least a portion of the compatible polymeric composition plasticizer is displaced by contact with a lithium salt electrolyte solution or is removed by extraction with a selective solvent and replaced with the electrolyte solution by simple imbibition. The battery thus activated may then be charged and recharged in the usual manner.
摘要翻译： 配制为增塑聚合物基质组合物层的锂离子可再充电电池单元电极和电解质/隔膜元件被层压以形成单体电池单元结构。 结构可以无限期地存储，因为它基本上不含通常包含湿敏锂盐的电解质溶液。 在电池投入使用之前，至少一部分相容的聚合物组合物增塑剂通过与锂盐电解质溶液的接触而移位，或者通过用选择性溶剂萃取除去，并通过简单的吸入代替电解质溶液。 然后由此激活的电池可以以通常的方式进行充电和再充电。
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48.发明授权
公开(公告)号：US5429891A
公开(公告)日：1995-07-04
申请号：US243018
申请日：1994-05-13
IPC分类号： C08J9/28 , H01M2/16 , H01M6/18 , H01M10/052 , H01M10/0565 , H01M6/16 , H01M4/66
CPC分类号： C08J9/28 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , C08J2327/16
摘要： A polymeric film useful as an interelectrode separator or electrolyte member in electrolytic devices, such as rechargeable batteries, comprises a copolymer of vinylidene fluoride and hexafluoropropylene, a medium to high-boiling plasticizer, and a finely divided inorganic filler which has been subjected to actinic radiation or thermal energy to cause crosslinking thereof in the presence of a crosslinking agent selected from the group consisting of an acrylate ester, di- or triallyl ester and a di- or triglycidyl ether.
摘要翻译： 用作电解装置（例如可再充电电池）中的电极间隔离物或电解质构件的聚合物膜包括偏二氟乙烯和六氟丙烯的共聚物，中至高沸点增塑剂和经过光化辐射的细碎无机填料 或热能在交联剂存在下引起交联，所述交联剂选自丙烯酸酯，二或三烯丙酯和二 - 或三缩水甘油醚。
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