公开(公告)号：US11529618B2

公开(公告)日：2022-12-20

申请号：US16462408

申请日：2017-11-28

Applicant: BASF SE

Inventor： Robert McGuire ,  Christiane Janke ,  Ulrich Mueller ,  Ekkehard Schwab

IPC: B01J29/70 ,  C07C1/20 ,  C10G3/00 ,  C10G11/18 ,  B01J29/04 ,  B01J29/87 ,  B01J29/89 ,  B01J29/78 ,  B01J29/86 ,  C07C11/04 ,  C07C11/08 ,  B01J37/02 ,  B01J35/00 ,  B01J37/00

Abstract: The present invention relates to catalyst comprising one or more metal oxides and/or metalloid oxides and a zeolitic material having the CHA framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material comprises one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof, and wherein the framework of the zeolitic material comprised in the catalyst contains substantially no phosphorous, as well as to a process for the preparation of a catalyst comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof and to a catalyst obtainable therefrom. Furthermore, the present invention relates to a method for the conversion of oxygenates to olefins employing the inventive catalyst, as well as to the use of the inventive catalyst in specific applications.

公开(公告)号：US11291980B2

公开(公告)日：2022-04-05

申请号：US16461134

申请日：2017-12-20

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC: B01J29/89 ,  B01J35/10 ,  B01J37/00 ,  C01B37/00

Abstract: A process for preparing an extrudable composition comprising a titanium-containing zeolitic material having framework type MWW, the process comprising providing a titanium-containing zeolitic material having framework type MWW, having a water absorption capacity of at least 11 weight-%, subjecting the titanium-containing zeolitic material having framework type MWW an acid treatment, optionally incorporating zinc in the acid-treated titanium-containing zeolitic material having framework type MWW; preparing a composition comprising the titanium-containing zeolitic material having framework type MWW obtained from (ii) or (iii), a precursor of a silica binder, water, and a kneading agent, wherein the composition does not comprise a polyethylene oxide.

公开(公告)号：US11072535B2

公开(公告)日：2021-07-27

申请号：US16631911

申请日：2018-08-03

Applicant: BASF SE

Inventor： Mathias Feyen ,  Ulrich Mueller ,  Xinhe Bao ,  Weiping Zhang ,  Dirk De Vos ,  Hermann Gies ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Ute Kolb ,  Bernd Marler ,  Yong Wang ,  Trees De Baerdemaeker ,  Chuan Shi ,  Xiulian Pan ,  Xiangju Meng

IPC: C01B39/46 ,  B01J29/76 ,  C01B39/02

Abstract: A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition I metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In. A process for preparing such a zeolitic material. Use of such a zeolitic material.

公开(公告)号：US10995008B2

公开(公告)日：2021-05-04

申请号：US16086251

申请日：2017-03-22

Applicant: BASF SE

Inventor： Benedikt Kalo ,  Thomas Geiger ,  Rene Koenig ,  Ulrich Mueller ,  Stefan Maurer

IPC: C01B39/00 ,  C01B39/02 ,  B01J29/70 ,  B01J37/00 ,  B01J37/06 ,  C01B39/48 ,  C01B39/04 ,  B01D15/36 ,  B01D71/02 ,  B01J6/00 ,  B01J20/18 ,  B01J29/00

Abstract: A process for the calcination of a zeolitic material, wherein the process contains the steps of (i) providing a zeolitic material containing YO2 and optionally further containing X2O3 in its framework structure in the form of a powder and/or of a suspension of the zeolitic material in a liquid, wherein Y stands for a tetravalent element and X stands for a trivalent element; (ii) atomization of the powder and/or of the suspension of the zeolitic material provided in (i) in a gas stream for obtaining an aerosol; and (iii) calcination of the aerosol obtained in (ii) for obtaining a calcined powder, a zeolitic material obtained by the above process, and its use as a molecular sieve, as an adsorbent, for ion-exchange, as a catalyst, and/or as a catalyst support.

公开(公告)号：US10981796B2

公开(公告)日：2021-04-20

申请号：US16349364

申请日：2017-12-12

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Regina Vogelsang ,  Nicole Sabine Bruns ,  Jan-Oliver Weidert

IPC: C01B37/00 ,  C01B39/00 ,  B01J29/70 ,  B01J29/89 ,  B01D3/06 ,  B01J29/86 ,  B01J35/10 ,  C01B39/02 ,  C01B39/06

Abstract: A process comprising hydrothermally synthesizing a titanium-containing zeolitic material having framework type MWW in the presence of an MWW template compound, obtaining a mother liquor comprising water, a first portion of the MWW template compound and a titanium-containing zeolitic material having framework type MWW comprising a second portion of the MWW template compound, separating the first portion of the MWW template compound from the mother liquor and recycling the first portion of the MWW template compound into a hydrothermal synthesis of a titanium-containing zeolitic material having framework type MWW.

公开(公告)号：US10793443B2

公开(公告)日：2020-10-06

申请号：US16202918

申请日：2018-11-28

Applicant: BASF SE

Inventor： Stefan Maurer ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Xiangju Meng ,  Feng-Shou Xiao ,  Yeqing Wang

IPC: C01B39/12 ,  C01B39/48 ,  B01J29/86 ,  B01J20/18 ,  B01D15/36 ,  B01D53/86

Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises(a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals,(b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material,(c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure,wherein the one or more organotemplates have the formula (I) R1R2R3N  (I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

公开(公告)号：US10780432B2

公开(公告)日：2020-09-22

申请号：US16470834

申请日：2018-01-18

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Markus Weber ,  Nicolai Tonio Woerz ,  Christian Mueller

IPC: B01J29/89 ,  B01J29/70 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  C01B39/02 ,  C01B39/06 ,  C01B39/12 ,  C07D301/12 ,  B01J37/08

Abstract: A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

公开(公告)号：US10544116B2

公开(公告)日：2020-01-28

申请号：US16315680

申请日：2017-07-19

Applicant: BASF SE

Inventor： Joaquim Henrique Teles ,  Marvin Kramp ,  Christian Mueller ,  Nicolai Tonio Woerz ,  Bernd Metzen ,  Tobias Keller ,  Dominic Riedel ,  Markus Weber ,  Daniel Urbanczyk ,  Andrei-Nicolae Parvulescu ,  Ulrike Wegerle ,  Ulrich Mueller

IPC: C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: Disclosed herein is a process for purifying propylene oxide, including the steps of: (i) providing a stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing a carbonyl group —C(═O)—; and (ii) separating propylene oxide from the stream S0 by subjecting the stream S0 to distillation conditions in a distillation column to obtain a gaseous top stream S1c which is enriched in propylene oxide compared to the stream S0, a liquid bottoms stream S1a which is enriched in acetonitrile and water compared to the stream S0, and a side stream S1b containing propylene oxide which is enriched in the carbonyl compound compared to the stream S0.

公开(公告)号：US10544115B2

公开(公告)日：2020-01-28

申请号：US16076600

申请日：2017-02-16

Applicant: BASF SE

Inventor： Dominic Riedel ,  Joaquim Henrique Teles ,  Heiner Schelling ,  Ulrike Wegerle ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Jochen Mannweiler ,  Timo Henn ,  Thomas Luederitz ,  Nicolai Tonio Woerz ,  Christian Mueller ,  Markus Weber ,  Daniel Urbanczyk

IPC: C07D301/12 ,  C07D301/36 ,  B01J19/00 ,  B01J29/70 ,  C07D303/04

Abstract: A continuous process for the preparation of propylene oxide, comprising a start-up stage and normal run stage, wherein the normal run stage comprises (i) continuously providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, a formate salt, water and optionally propane, wherein in the liquid feed stream, the molar amount of the formate salt relative to the molar amount of hydrogen peroxide at a given point of time during the normal run stage is aN(Fo/H2O2); (ii) continuously passing the liquid feed stream provided in (i) into an epoxidation zone comprising a catalyst comprising a titanium zeolite having framework type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the formate salt, optionally propene, and optionally propane; (iii) continuously removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the formate salt, optionally propene, and optionally propane; wherein the normal run stage is characterized in an average rate of change of aN(Fo/H2O2) of less than 0 h−1.

公开(公告)号：US10435381B2

公开(公告)日：2019-10-08

申请号：US16318221

申请日：2017-07-19

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： Joaquim Henrique Teles ,  Marvin Kramp ,  Christian Mueller ,  Nicolai Tonio Woerz ,  Bernd Metzen ,  Tobias Keller ,  Dominic Riedel ,  Heiner Schelling ,  Markus Weber ,  Daniel Urbanczyk ,  Andrei-Nicolae Parvulescu ,  Ulrike Wegerle ,  Ulrich Mueller ,  Meinolf Weidenbach ,  Werner J. Witzl ,  Karsten Luecke

IPC: C07D301/32 ,  C07D301/12 ,  C07D303/04 ,  B01D3/00 ,  B01D3/14 ,  B01D5/00 ,  B01D3/40 ,  B01J29/08

Abstract: The present invention is related to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, water, organic solvent, and propene; (iv) separating propene from the effluent stream by distillation, comprising (iv.1) subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous top stream S0 enriched in propene compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream S01 enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (iv.2) returning a condensed portion of the stream S0 to an upper part of the distillation unit.