公开(公告)号：US20130202524A1

公开(公告)日：2013-08-08

申请号：US13760466

申请日：2013-02-06

Applicant: BASF SE

Inventor： Stefan Maurer ,  Michael Wycisk ,  Julia Petry ,  Stephan Deuerlein ,  Weiping Zhang ,  Chuan Shi ,  Hihara Takashi

IPC: B01J29/72 ,  C01B39/46 ,  C01B39/06

CPC classification number: B01J29/7215 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/502 ,  B01D2257/404 ,  B01J29/7615 ,  B01J35/002 ,  B01J2229/186 ,  B01J2229/42 ,  C01B39/065 ,  C01B39/46

Abstract: Provided is a process for the production of a zeolitic material having a BEA-type framework structure comprising YO2 and X2O3. The process comprises the steps of (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and seed crystals comprising one or more zeolitic materials having a BEA-type framework structure; (2) crystallizing the mixture; and (3) subjecting the zeolitic material having a BEA-type framework structure to an ion-exchange procedure with Cu and/or Fe. Y is a tetravalent element, and X is a trivalent element. The mixture does not contain an organotemplate as structure-directing agent, and the total amount of Cu and/or Fe in the ion-exchanged material ranges from 0.1 to 25 wt.-% calculated as Fe2O3 and CuO. Also provided is a zeolitic material having a BEA-type framework structure, and a method for the treatment of NOx by selective catalytic reduction (SCR).

Abstract translation: 提供了一种生产具有包含YO 2和X 2 O 3的BEA型骨架结构的沸石材料的方法。 该方法包括以下步骤：（1）制备包含一种或多种YO源，X2O3的一种或多种来源的混合物，以及包含一种或多种具有BEA型骨架结构的沸石材料的晶种; （2）使混合物结晶; 和（3）使具有BEA型骨架结构的沸石材料与Cu和/或Fe进行离子交换程序。 Y是四价元素，X是三价元素。 该混合物不含作为结构导向剂的有机模板，并且离子交换材料中的Cu和/或Fe的总量为0.1至25重量％，以Fe 2 O 3和CuO计算。 还提供了具有BEA型骨架结构的沸石材料和通过选择性催化还原（SCR）处理NOx的方法。

公开(公告)号：US11072535B2

公开(公告)日：2021-07-27

申请号：US16631911

申请日：2018-08-03

Applicant: BASF SE

Inventor： Mathias Feyen ,  Ulrich Mueller ,  Xinhe Bao ,  Weiping Zhang ,  Dirk De Vos ,  Hermann Gies ,  Feng-Shou Xiao ,  Toshiyuki Yokoi ,  Ute Kolb ,  Bernd Marler ,  Yong Wang ,  Trees De Baerdemaeker ,  Chuan Shi ,  Xiulian Pan ,  Xiangju Meng

IPC: C01B39/46 ,  B01J29/76 ,  C01B39/02

Abstract: A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition I metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In. A process for preparing such a zeolitic material. Use of such a zeolitic material.

公开(公告)号：US20240109058A1

公开(公告)日：2024-04-04

申请号：US17766578

申请日：2020-11-24

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu, III ,  Robert McGuire ,  Ulrich Mueller ,  Weiping Zhang ,  Chuan Shi

IPC: B01J29/76 ,  B01D53/56 ,  B01D53/94 ,  B01J35/00 ,  B01J37/08 ,  B01J37/30 ,  C01B39/02

CPC classification number: B01J29/76 ,  B01D53/56 ,  B01D53/9418 ,  B01J35/19 ,  B01J37/08 ,  B01J37/30 ,  C01B39/02 ,  B01D2255/2061 ,  B01D2255/20761 ,  B01D2255/50

Abstract: A rare earth element containing zeolitic material having an AEI-type framework structure, the framework structure of the zeolitic material comprising SiO2 and X2O3, X being a trivalent element, wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure, and wherein the zeolitic material is obtainable and/or obtained according to a process involving the hydrothermal treatment of the rare earth element containing zeolitic material at a temperature in the range of from 400 to 1,000° C. A coated monolith substrate comprising a rare earth element containing zeolitic material having an AEI-type framework structure, wherein the zeolitic material is supported on the monolith substrate. A process for the production of a coated monolith substrate comprising a rare earth element containing zeolitic material having an AEI-type framework structure.