公开(公告)号：US09605100B2

公开(公告)日：2017-03-28

申请号：US15193195

申请日：2016-06-27

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish M. Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08F4/659 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US09334350B2

公开(公告)日：2016-05-10

申请号：US14639582

申请日：2015-03-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/02 ,  C08F210/16 ,  C08F210/14 ,  C08J5/18 ,  C08L23/08

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

公开(公告)号：US20150376312A1

公开(公告)日：2015-12-31

申请号：US14842888

申请日：2015-09-02

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F210/16 ,  C08J5/00

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US09062134B2

公开(公告)日：2015-06-23

申请号：US14277140

申请日：2014-05-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Joel L. Martin ,  Albert P. Masino ,  Qing Yang ,  Youlu Yu

IPC: C08F4/6592 ,  C08F4/642 ,  C08F10/00 ,  C08F210/16 ,  C08F4/76 ,  C07F17/00 ,  C08F4/659

CPC classification number: C08F4/76 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/12

Abstract: The present invention provides polymerization catalyst compositions employing half-metallocene compounds with a heteroatom-containing ligand bound to the transition metal. Methods for making these hybrid metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.

Abstract translation: 本发明提供了采用具有与过渡金属结合的含杂原子的配体的半茂金属化合物的聚合催化剂组合物。 还提供了制备这些杂化茂金属化合物和在用于烯烃聚合的催化剂组合物中使用这些化合物的方法。

公开(公告)号：US20150011381A1

公开(公告)日：2015-01-08

申请号：US14493384

申请日：2014-09-23

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F4/76 ,  C08F4/52

CPC classification number: C08F4/76 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08F110/02 ,  C08F2500/04 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。

公开(公告)号：US20140235804A1

公开(公告)日：2014-08-21

申请号：US14264284

申请日：2014-04-29

Applicant: Chevron Phillips Chemical Company LP

Inventor： Albert P. Masino ,  Rex E. Murray ,  Qing Yang ,  Steve J. Secora ,  Kumudini C. Jayaratne ,  William B. Beaulieu ,  Errun Ding ,  Gary L. Glass ,  Alan L. Solenberger ,  Ted H. Cymbaluk

IPC: C08F4/642

CPC classification number: C08F4/642 ,  C08F4/12 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

Abstract: The present invention provides dual catalyst systems and polymerization processes employing these dual catalyst systems. The disclosed polymerization processes can produce olefin polymers at higher production rates, and these olefin polymers may have a higher molecular weight and/or a lower melt index.

Abstract translation: 本发明提供了使用这些双重催化剂体系的双重催化剂体系和聚合方法。 公开的聚合方法可以以更高的生产速率生产烯烃聚合物，并且这些烯烃聚合物可以具有较高的分子量和/或较低的熔体指数。

公开(公告)号：US11186707B2

公开(公告)日：2021-11-30

申请号：US16710839

申请日：2019-12-11

Applicant: Chevron Phillips Chemical Company LP

Inventor： William B. Beaulieu ,  Errun Ding

IPC: C08L23/08

Abstract: A method comprising introducing a polymerization feed comprising an α-olefin, a diluent, and a diene to a polymerization system, under polymerization conditions, whereby a polymer product is produced, wherein the diene is present at a level in the range of from about 1 ppm to about 1000 ppm based on the diluent.

公开(公告)号：US20210054178A1

公开(公告)日：2021-02-25

申请号：US16543686

申请日：2019-08-19

Applicant: Chevron Phillips Chemical Company LP

Inventor： Chung Ching Tso ,  Errun Ding ,  Randall S. Muninger ,  John T. Blagg ,  Yongwoo Inn ,  Max P. McDaniel ,  Ashish M. Sukhadia ,  Sarah Eppinger

IPC: C08L23/06 ,  C08F210/16 ,  C08F4/6592

Abstract: Ethylene polymers having a density from 0.908 to 0.925 g/cm3, a melt index from 0.5 to 3 g/10 min, a ratio of Mw/Mn from 2 to 4, a ratio of Mz/Mw from 1.6 to 2.3, a CY-a parameter from 0.45 to 0.6, and an ATREF profile characterized by a single peak at a peak ATREF temperature from 76 to 88° C., and by less than 4.5 wt. % of the polymer eluting above a temperature of 91° C. These ethylene polymers can be used to produce various articles of manufacture, such as blown and cast films with a beneficial combination of high tear resistance and low haze.

公开(公告)号：US10899855B2

公开(公告)日：2021-01-26

申请号：US16166224

申请日：2018-10-22

Applicant: Chevron Phillips Chemical Company LP

Inventor： Ashish M. Sukhadia ,  Max P. McDaniel ,  Errun Ding ,  Guylaine St. Jean ,  Qing Yang ,  Daniel G. Hert ,  Chung Ching Tso

IPC: C08L23/08 ,  C08F210/16 ,  C08F4/6592 ,  C08F10/02 ,  C08J5/18 ,  C08F210/02 ,  C08F4/659 ,  C08F210/08 ,  C08F210/14

Abstract: Disclosed herein are ethylene-based polymers produced using dual metallocene catalyst systems. These polymers have low densities, high molecular weights, and broad molecular weight distributions, as well as having the majority of the long chain branches in the lower molecular weight component of the polymer, and the majority of the short chain branches in the higher molecular weight component of the polymer. Films produced from these polymers have improved impact and puncture resistance.

公开(公告)号：US10435492B2

公开(公告)日：2019-10-08

申请号：US15890524

申请日：2018-02-07

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Youlu Yu ,  Qing Yang ,  Richard M. Buck

IPC: C08F210/02 ,  C08F210/16 ,  C08F4/659

Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.