Fluoroalkyl surfactants
    41.
    发明授权
    Fluoroalkyl surfactants 失效
    氟烷基表面活性剂

    公开(公告)号:US07638650B2

    公开(公告)日:2009-12-29

    申请号:US11890376

    申请日:2007-08-06

    申请人: Weiming Qiu

    发明人: Weiming Qiu

    摘要: A compound of formula (I): wherein k is 1 or 2; Y is —CH2CH(CF3)2 or —(CH2)nCF; X is hydrogen, —(CH2)nRf, or —C(O)[CF(A)]p-B—Rf, wherein B is a covalent bond, —O— or —(CH2)m—; A is —F or —CF3; and each Rf is independently C1 to C6 perfluorinated alkyl, optionally interrupted by one or more oxygens; Ro is Ro1 or is an alkyl having from about 10 to about 100 carbon atoms, interrupted or substituted by one or more hydrophilic groups; R is hydrogen or a C1 to C4 alkyl; and Ro1 is an aliphatic group of from about 10 to about 100 carbon atoms, interrupted by about from about 5 to about 50 ether oxygens; provided that 1) when Y is —(CH2)nRf, Ro is Ro1; 2) when X is hydrogen, Y is —CH2CH(CF3)2; and 3) when X is —(CH2)nRf and Y is —(CH2)nRf, Ro is Ro1.

    摘要翻译: 式(I)的化合物:其中k为1或2; Y是-CH 2 CH(CF 3)2或 - (CH 2)n CF; X是氢, - (CH 2)n R f或-C(O)[CF(A)] p-B-Rf,其中B是共价键,-O-或 - (CH 2)m - A是-F或-CF 3; 并且每个Rf独立地为C1至C6全氟化烷基,任选地被一个或多个氧中断; Ro是Ro1或是具有约10至约100个碳原子的烷基,被一个或多个亲水基团中断或取代; R是氢或C1至C4烷基; 且Ro1为约10至约100个碳原子的脂族基团,间隔约5至约50个醚氧; 条件是1)当Y为 - (CH2)nRf时,Ro为Ro1; 2)当X是氢时,Y是-CH 2 CH(CF 3)2; 和3)当X是 - (CH2)nRf且Y是 - (CH2)nRf时,Ro是Ro1。

    Fluoropolymer compositions and treated substrates
    42.
    发明申请
    Fluoropolymer compositions and treated substrates 失效
    含氟聚合物组合物和经处理的基材

    公开(公告)号:US20090286949A1

    公开(公告)日:2009-11-19

    申请号:US12152736

    申请日:2008-05-16

    IPC分类号: C08G18/74

    摘要: A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r—XH   (I) whereinRf is a perfluoroalkyl group having 1 to about 6 carbon atoms;subscript x is 1 to about 6;subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof;subscript r is 0 or 1;the total number of carbons in said formula (I) excluding (R1)r—XH ranges from about 8 to about 22;X is —O—, —NR—, —S—, —S(CH2)tO—, or —S(CH2)tNR—;subscript t is from 1 to about 10;R is H or C1-4 alkyl;R1 is certain divalent radicals;n is 2 to 4;s is 1 to about 50;R2, R3, and R4 are each independently hydrogen or a C1-C6 alkyl group; and(ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.

    摘要翻译: 具有至少一个氨基甲酸酯键的聚合物:(i)使(a)至少一种二异氰酸酯,多异氰酸酯或其混合物反应,和(b)至少一种选自式(I)的氟化化合物:Rf(CH 2) x [(CF 2 CF 2)y(CH 2 CH 2)z] m(R 1)r -XH(I)其中Rf是具有1至约6个碳原子的全氟烷基; 下标x为1〜6; 下标y,z和m各自独立地为1,2或3,或其混合物; 下标r为0或1; 除(R1)r-XH以外的所述式(I)中的碳数总计为约8至约22; X是-O-,-NR - , - S - , - S(CH 2)t O-或-S(CH 2)t NR-; 下标t为1〜10; R是H或C 1-4烷基; R1是一定的二价基团; n为2〜4; s为1至约50; R2,R3和R4各自独立地为氢或C1-C6烷基; 和(ii)任选地与(c)水,连接剂或其混合物反应。

    Poly(meth)acrylamides and poly(meth)acrylates containing fluorinated amide
    44.
    发明申请
    Poly(meth)acrylamides and poly(meth)acrylates containing fluorinated amide 失效
    聚(甲基)丙烯酰胺和含氟化酰胺的聚(甲基)丙烯酸酯

    公开(公告)号:US20080039605A1

    公开(公告)日:2008-02-14

    申请号:US11500532

    申请日:2006-08-08

    申请人: Weiming Qiu

    发明人: Weiming Qiu

    IPC分类号: C08F120/00

    摘要: A composition comprising a copolymer having repeating units in any sequence of Formula I wherein Rf is a straight or branched perfluoroalkyl group having from about 1 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, X3 is oxygen or X1, each X1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing an oxygen, nitrogen, or sulfur, or a combination thereof, G is F or CF3, A is an amide, j is zero or positive integer, X2 is an organic linking group, Y is O, N or S, h is zero when Y is N, and h is one when Y is O or S, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, B is H or wherein Rf, X1, X3, G, A, and j are as defined above, provided that when B is H, j is a positive integer, m is a positive integer, q is zero or a positive integer when Y is O, and q is a positive integer when Y is N or S, p is zero or a positive integer when Y is O, and p is a positive integer when Y is N or S, each W is independently various copolymer units.

    摘要翻译: 一种组合物,其包含具有式I的任何顺序的重复单元的共聚物,其中R 1是具有约1至约20个碳原子的直链或支链全氟烷基或其混合物,其任选地中断 通过至少一个氧原子,X 3是氧或X 1,每个X 1独立地是具有约1个的有机二价连接基团 至约20个碳原子,任选地含有氧,氮或硫或其组合,G是F或CF 3,A是酰胺,j是零或正整数,X 2是有机连接基团,Y是O,N或S,当Y是N时,h是0,当Y是O或S时,h是1,Z是H,直链或支链烷基具有 约1至约4个碳原子或卤化物,B为H或其中R 1,X 1,X 3,G,A 和j如上所定义,条件是当B为H时,j为正整数,m为正整数,q为零或po 当Y为O时为静态整数,当Y为N时,q为正整数,p为0,Y为O时为正整数,Y为N或S时,p为正整数,W各自独立地为 共聚单元。

    Polycyclic fluoroalkanes
    46.
    发明授权
    Polycyclic fluoroalkanes 失效
    多环氟烷烃

    公开(公告)号:US07084314B1

    公开(公告)日:2006-08-01

    申请号:US11149635

    申请日:2005-06-09

    IPC分类号: C07C19/08

    摘要: Polycyclic fluoroalkanes that are highly transparent to UV wavelengths ranging from about 190 nm to 260 nm are provided. The polycyclic fluoroallkanes are suitable for use in a variety of applications, particularly in the vacuum UV and deep UV region of the electromagnetic spectrum. For example, the polycyclic fluoroalkanes are useful in optical couplants, optical cements, optical elements, optical inspection media for semiconductor wafers and devices, and immersion photolithography, particularly at 193 and 248 nm exposure wavelength.

    摘要翻译: 提供了对从约190nm到260nm范围内的UV波长高度透明的多环氟烷烃。 多环氟烷烃适用于各种应用,特别是在电磁光谱的真空UV和深UV区域。 例如,多环氟烷烃可用于光学偶联剂,光学粘合剂,光学元件,用于半导体晶片和器件的光学检查介质以及浸渍光刻,特别是在193和248nm曝光波长下。

    Processes for preparing high purity polycyclic fluoroalkanes
    47.
    发明授权
    Processes for preparing high purity polycyclic fluoroalkanes 失效
    制备高纯度多环氟代烷烃的方法

    公开(公告)号:US07078575B1

    公开(公告)日:2006-07-18

    申请号:US11149614

    申请日:2005-06-09

    IPC分类号: C07C19/08

    摘要: Processes for preparing high purity polycyclic fluoroalkanes are provided. The polycyclic fluoroalkanes are useful as solvents, cleaning agents, heat transfer fluids, refrigerants, lubricants, and, in a preferred embodiment, by virtue of high refractive index and high transparency to UV wavelengths, optical applications in the vacuum ultraviolet (VUV).

    摘要翻译: 提供制备高纯度多环氟代烷烃的方法。 多环氟烷烃可用作溶剂,清洁剂,传热流体,制冷剂,润滑剂,并且在优选的实施方案中,由于高折射率和对UV波长的高透明度,真空紫外线(VUV)中的光学应用。