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    Process for dyeing keratin fibres with a monohydroxyindole associated with an iodide and hydrogen peroxide
    41.
    发明授权
    Process for dyeing keratin fibres with a monohydroxyindole associated with an iodide and hydrogen peroxide 失效
    用与碘化物和过氧化氢相关的单羟基吲哚染色角蛋白纤维的方法

    公开(公告)号：US5034015A

    公开(公告)日：1991-07-23

    申请号：US404512

    申请日：1989-09-08

    Applicant: Alex Junino ,  Gerard Lang ,  Jean J. Vandenbossche

    Inventor： Alex Junino ,  Gerard Lang ,  Jean J. Vandenbossche

    IPC: C07D209/10 ,  A61K8/00 ,  A61K8/20 ,  A61K8/22 ,  A61K8/34 ,  A61K8/35 ,  A61K8/37 ,  A61K8/39 ,  A61K8/40 ,  A61K8/42 ,  A61K8/49 ,  A61Q5/10 ,  C07D209/42

    CPC classification number: A61Q5/10 ,  A61K8/492

    Abstract: Process for dyeing keratin fibres consisting in applying on these fibres a composition (A) containing at least one indole colorant of formula: ##STR1## where R.sub.1 =H or C.sub.1 -C.sub.4 alkyl;R.sub.2 and R.sub.3, which may be identical or different, denote H, C.sub.1 -C.sub.4 alkyl, carboxyl or alkoxycarbonyl; or a salt or a precursor of a compound (I), associated, either with iodide ions, or with H.sub.2 O.sub.2 ; application of composition (A) being preceded or followed by the application of a compound (B) which contains, either H.sub.2 O.sub.2 at a pH of 2 to 12 when (A) contains iodide ions, or iodide ions at a pH of 2 to 11 when (A) contains H.sub.2 O.sub.2.This process allows particularly powerful and resistant dyes to be made.

    Abstract translation: 染色包含在这些纤维上施加的组合物（A）的角蛋白纤维的方法包含至少一种下式的吲哚着色剂：其中R 1 = H或C 1 -C 4烷基; R2和R3可以相同或不同，表示H，C1-C4烷基，羧基或烷氧基羰基; 或与碘离子或与H 2 O 2缔合的化合物（I）的盐或前体; 当（A）含有碘离子时，在pH为2〜12的H 2 O 2或pH为2〜11的碘离子的情况下，应用组合物（A）的施用或化合物（B） （A）含有H 2 O 2。 该方法可以制造出特别强大和有效的染料。

    Compositions for coloring the skin based on indole derivatives
    42.
    发明授权
    Compositions for coloring the skin based on indole derivatives 失效
    基于吲哚衍生物着色皮肤的组合物

    公开(公告)号：US4956174A

    公开(公告)日：1990-09-11

    申请号：US21931

    申请日：1987-03-05

    Applicant: Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    Inventor： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC: A61K8/00 ,  A61K8/34 ,  A61K8/46 ,  A61K8/49 ,  A61K8/58 ,  A61K8/86 ,  A61K8/92 ,  A61Q1/02 ,  A61Q19/04

    CPC classification number: A61Q19/04 ,  A61K8/492

    Abstract: Cosmetic composition designed to impart to the skin a coloring which is substantially similar to the pigmentation resulting from natural tanning, characterized in that it contains, in a cosmetically acceptable medium suitable for topical application, at least one compound of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom, a lower alkyl group or a residue --SiR.sub.9 R.sub.10 R.sub.11, R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ; R.sub.4 and R.sub.5 which may be identical or different, denote a hydrogen atom, a linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group R.sub.6 OSO.sub.2 --, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or an aralkyl group, or alternatively R.sub.4 and R.sub.5, with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group when at least one of the groups, R.sub.1, R.sub.2 or R.sub.3 is other than hydrogen or alternatively a thiocarbonyl group, a residue >P(O)OR.sub.6, a group >CR.sub.7 R.sub.8 or a methylene group, R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, R.sub.8 denoting a lower alkoxy group or a mono- or dialkylamino group and R.sub.9, R.sub.10 or R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 being other than hydrogen; and the corresponding salts with alkali metals, alkaline earth metals, ammonium or amines.

    Abstract translation: 化妆品组合物被设计成赋予皮肤一种基本上类似于由天然鞣制引起的色素沉着的着色，其特征在于其在适合局部应用的化妆品可接受的介质中包含至少一种下式的化合物： I），其中R 1表示氢原子，低级烷基或残基-SiR 9 R 10 R 11，R 2和R 3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或 一组-COOSiR9R10R11; 可以相同或不同的R 4和R 5表示氢原子，直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， 基团R6OSO2-，基团-SiR9R10R11，基团-P（O）（OR6）2或芳烷基，或者R4和R5与它们所连接的氧原子形成任选含有羰基的环， R 1，R 2或R 3中的至少一个不是氢或硫代羰基，残基> P（O）OR 6，基团> CR 7 R 8或亚甲基，R 6表示氢原子或低级烷基 ，R7表示氢原子或低级烷基，R8表示低级烷氧基或单或二烷基氨基，R9，R10或R11可以相同或不同，表示直链或支链的低级烷基，至少一个 的取代基R 1，R 2，R 3，R 4和R 5不是氢; 和与碱金属，碱土金属，铵或胺的相应的盐。

    Dyeing compositions for keratinous fibres, especially for human hair, containing oxidation dye precursors and heterocyclic couplers
    45.
    发明授权
    Dyeing compositions for keratinous fibres, especially for human hair, containing oxidation dye precursors and heterocyclic couplers 失效
    含有氧化染料前体和杂环成色剂的角质纤维特别是人毛的染色组合物

    公开(公告)号：US4865617A

    公开(公告)日：1989-09-12

    申请号：US92720

    申请日：1987-09-03

    Applicant: Alex Junino ,  Alain Genet ,  Gerard Lang

    Inventor： Alex Junino ,  Alain Genet ,  Gerard Lang

    IPC: C09B67/44 ,  A61K8/00 ,  A61K8/33 ,  A61K8/34 ,  A61K8/35 ,  A61K8/40 ,  A61K8/41 ,  A61K8/42 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C07D317/46 ,  C07D317/66 ,  C09B53/02 ,  C09B57/00 ,  D06P1/32 ,  D06P3/08

    CPC classification number: C07D317/66 ,  A61K8/4973 ,  A61Q5/10 ,  C07D317/46

    Abstract: The invention relates to a dyeing composition for keratinous fibres containing, in a cosmetically acceptable solvent medium, at least one para-type oxidation dye precursor in combination with at least one heterocyclic coupler of formula: ##STR1## in which R denotes a hydrogen atom, a C.sub.1 -C.sub.4 radical, a C.sub.2 -C.sub.4 hydroxyalkyl radical, a C.sub.3 to C.sub.6 polyhydroxyalkyl radical, or a C.sub.2 -C.sub.6 alkoxyalkyl radical, Z, independently of R, denotes a C.sub.1 to C.sub.4 alkyl radical, a C.sub.2 to C.sub.4 hydroxyalkyl radical, a C.sub.3 to C.sub.6 polyhydroxyalkyl radical, a C.sub.2 -C.sub.6 alkoxyalkyl radical or a trifluoroethyl radical, R.sub.1 and R.sub.2 independently of each other denote a hydrogen atom or a C.sub.1 to C.sub.4 alkyl radical, or one of the addition salts of the compound of formula (I) with an inorganic acid, a process for the oxidation dyeing of hair using this composition as well as the new couplers of formula (I) where Z is other than methyl when R.sub.1, R.sub.2 and R=H, the process for their preparation, the new intermediate compounds of formula: ##STR2## and the process for their preparation.

    Abstract translation: 本发明涉及一种用于角蛋白纤维的染色组合物，其在化妆品可接受的溶剂介质中含有至少一种对位型氧化染料前体与至少一种下式的杂环偶联剂：其中R表示 氢原子，C 1 -C 4基团，C 2 -C 4羟基烷基，C 3至C 6多羟基烷基或C 2 -C 6烷氧基烷基，Z独立地表示C 1至C 4烷基，C 2至C 4羟基烷基 自由基，C3至C6多羟基烷基，C2-C6烷氧基烷基或三氟乙基，R1和R2彼此独立地表示氢原子或C1至C4烷基，或式（I）化合物的加成盐之一 （I）的无机酸，使用该组合物进行毛发氧化染色的方法以及式（I）的新型成色剂，其中当R1，R2和R = H时Z不同于甲基，其制备方法 ，新的中间体化合物：

    3-amino-4-nitrophenols, the process for preparation thereof and their use in dyeing keratinous fibres, and new intermediate 4,5-dinitrophenols
    46.
    发明授权
    3-amino-4-nitrophenols, the process for preparation thereof and their use in dyeing keratinous fibres, and new intermediate 4,5-dinitrophenols 失效
    3-氨基-4-硝基苯酚，其制备方法及其在染色角质纤维中的用途，以及新的中间体4,5-二硝基酚

    公开(公告)号：US4740622A

    公开(公告)日：1988-04-26

    申请号：US850695

    申请日：1986-04-11

    Applicant: Alex Junino ,  Gerard Lang ,  Alain Genet

    Inventor： Alex Junino ,  Gerard Lang ,  Alain Genet

    IPC: A61K8/00 ,  A61K8/34 ,  A61K8/35 ,  A61K8/40 ,  A61K8/41 ,  A61Q5/06 ,  A61Q5/10 ,  C07C67/00 ,  C07C205/37 ,  C07C213/00 ,  C07C217/84 ,  C07D317/62 ,  C09B51/00 ,  D06P3/04 ,  C07C87/60 ,  A61K7/13

    CPC classification number: A61K8/418 ,  A61Q5/065 ,  C07C205/37 ,  C07D317/62 ,  C09B51/00

    Abstract: New 3-amino-4-nitrophenols, the process for preparation thereof and their use in dyeing keratinous fibres, and new intermediate 4,5-dinitrophenols.The present invention relates to a 3-amino-4-nitrophenol of formula: ##STR1## where Z denotes --CH.sub.2 --W, W denoting hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl, (C.sub.1 -C.sub.3)alkoxy(C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.3)hydroxyalkoxy(C.sub.1 -C.sub.6)alkyl and R denotes hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl or (C.sub.1 -C.sub.3)alkoxy(C.sub.1 -C.sub.6)alkyl, the process for preparation thereof and the intermediate compound of formula: ##STR2## in which Z' denotes CH.sub.2 --W, W denoting C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl, (C.sub.1 -C.sub.3)alkoxy-(C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.3)hydroxyalcoxy(C.sub.1 -C.sub.6)alkyl.The dyes (I) are useful in direct dyeing of keratinous fibres, in particular human hair.

    Abstract translation: 新的3-氨基-4-硝基苯酚，其制备方法及其在染色角质纤维中的用途，以及新的中间体4,5-二硝基酚。 本发明涉及下式的3-氨基-4-硝基苯酚：其中Z表示-CH 2 -W，W表示氢，C 1 -C 6烷基，C 1 -C 6羟烷基，C 2 -C 6多羟基烷基（（ C1-C3）烷氧基（C1-C6）烷基或（C1-C3）羟基烷氧基（C1-C6）烷基，R表示氢，C1-C6烷基，C1-C6羟基烷基，C2-C6多羟基烷基或（C1-C3） （C 1 -C 6）烷基，其制备方法和下式的中间体化合物：其中Z'表示CH2-W，W表示C1-C6羟基烷基，C2-C6多羟基烷基，（C1- C3）烷氧基 - （C1-C6）烷基或（C1-C3）羟基烷氧基（C1-C6）烷基。 染料（I）可用于直角染色角质纤维，特别是人类头发。

    2,4-dinitro- or 2-amino-4-nitro- or 2-nitro-4-amino-6-hydroxyalkylanilines, the process for preparation thereof and their use in dyeing keratinous fibers, and especially human hair
    47.
    发明授权
    2,4-dinitro- or 2-amino-4-nitro- or 2-nitro-4-amino-6-hydroxyalkylanilines, the process for preparation thereof and their use in dyeing keratinous fibers, and especially human hair 失效
    2,4-二硝基或2-氨基-4-硝基 - 或2-硝基-4-氨基-6-羟基烷基苯胺，其制备方法及其在染色角质纤维，特别是人类头发中的用途

    公开(公告)号：US4727192A

    公开(公告)日：1988-02-23

    申请号：US808814

    申请日：1985-12-13

    Applicant: Alex Junino ,  Gerard Lang ,  Nicole Jehanno

    Inventor： Alex Junino ,  Gerard Lang ,  Nicole Jehanno

    IPC: A61K8/41 ,  A61Q5/06 ,  A61Q5/10 ,  C07C215/68 ,  C09B51/00 ,  C07C87/60 ,  A61K7/13 ,  C07C87/28

    CPC classification number: A61K8/418 ,  A61Q5/065 ,  A61Q5/10

    Abstract: The invention relates to a compound of formula ##STR1## in which: X denotes a branched or unbranched alkylene radical containing 2 to 6 carbon atoms, optionally being able to be substituted with one or more hydroxyl radicals;R denotes a hydrogen atom, an alkyl or a mono- or polyhydroxyalkyl radical or an aminoalkyl radical in which the amine group can be mono- or disubstituted with an alkyl radical or with a mono- or polyhydroxyalkyl radical, the nitrogen atom also being able to form part of a heterocyclic system and the alkyl radicals containing 1 to 4 carbon atoms;R' denotes a hydrogen atom or a C.sub.1 to C.sub.4 alkyl radical;Y and Z denote a nitro and/or --NHR.sub.1 radical, R.sub.1 and R, which may be identical or different, having the meanings given above for R, with the proviso that when Y and Z are identical, they necessarily denote nitro radicals,and the cosmetically acceptable salts of the compounds containing a salifiable amine group, and also the process for preparing it and its use in dyeing keratinous fibres, and especially human hair.

    Abstract translation: 本发明涉及式（I）的化合物，其中：X表示含有2至6个碳原子的支链或非支链亚烷基，任选地可被一个或多个羟基取代; R表示氢原子，烷基或单羟基或多羟基烷基或氨基烷基，其中胺基可以被烷基或与单羟基或多羟基烷基单体或二取代，氮原子也可以 形成杂环体系的一部分和含有1至4个碳原子的烷基; R'表示氢原子或C1〜C4烷基; Y和Z表示硝基和/或-NHR 1基团，R 1和R可以相同或不同，具有上面对R给出的含义，条件是当Y和Z相同时，它们必须表示硝基，并且 含有可成胺基团的化合物的化妆品可接受的盐，以及其制备方法及其在染色角质纤维，特别是人类头发中的用途。

    Dyeing composition containing a laccase and method for dyeing keratinous fibres
    48.
    发明申请
    Dyeing composition containing a laccase and method for dyeing keratinous fibres 审中-公开
    含有漆酶的染色组合物和染色角质纤维的方法

    公开(公告)号：US20060021155A1

    公开(公告)日：2006-02-02

    申请号：US10992474

    申请日：2004-11-19

    Applicant: Gerard Lang ,  Jean Cotteret

    Inventor： Gerard Lang ,  Jean Cotteret

    IPC: A61K8/00

    CPC classification number: A61K8/66 ,  A61Q5/10

    Abstract: The invention concerns a cosmetic composition for oxidation dyeing of keratinous fibres comprising in a support suitable for keratinous fibre dyeing: (a) at least an enzyme such as laccase; (b) at least a particular alkalising agent; (c) at least an oxidation colouring agent, as well as the dyeing methods using said composition.

    Abstract translation: 本发明涉及用于角质纤维的氧化染色的化妆品组合物，其包含在适于角质纤维染色的载体中：（a）至少一种酶，例如漆酶; （b）至少一种特定的碱化剂; （c）至少一种氧化着色剂，以及使用该组合物的染色方法。

    Hair dye compositions and process comprising and utilizing a combination of isatin and aminopyrimidine derivatives
    50.
    发明授权
    Hair dye compositions and process comprising and utilizing a combination of isatin and aminopyrimidine derivatives 失效
    染发剂组合物和方法，其包含并利用靛红和氨基嘧啶衍生物的组合

    公开(公告)号：US5340366A

    公开(公告)日：1994-08-23

    申请号：US136125

    申请日：1993-10-15

    Applicant: Gerard Lang ,  Jean Cotteret

    Inventor： Gerard Lang ,  Jean Cotteret

    IPC: A61K8/00 ,  A61K8/25 ,  A61K8/34 ,  A61K8/37 ,  A61K8/49 ,  A61K8/73 ,  A61K8/97 ,  A61Q5/10 ,  C07D209/38 ,  C07D213/74 ,  C07D239/48 ,  C07D239/52 ,  C09B7/02 ,  C09B67/42 ,  D06P3/08 ,  A61K7/13

    CPC classification number: A61Q5/10 ,  A61K8/492 ,  A61K8/4953

    Abstract: A process for dyeing keratinous fibers involves applying to the fibers, at least one compound of formula ##STR1## wherein R.sub.1 represents hydrogen, alkyl, acetyl, benzoyl, phenyl or carboxylalkyl and R.sub.2 and R.sub.3 represent hydrogen, alkyl, hydroxyl, halogen, nitro, alkyl phenyl, phenyl or alkoxy, and an aminopyrimidine of the formula ##STR2## wherein R.sub.5 represents hydrogen, hydroxyl or ##STR3## represents hydroxyl or ##STR4## R.sub.7 represents H or NH.sub.2, R.sub.8 represents ##STR5## and R.sub.9 and R.sub.10 represent hydrogen, alkyl, (CH.sub.2).sub.p -Z wherein p is 1 to 4 and Z represents OH, halogen, NH.sub.2, NHR' or NHR'R" wherein R' and R" represent alkyl or together form a heterocycle, with the proviso that one of R.sub.5 to R.sub.8 represents NH.sub.2.

    Abstract translation: 用于染色角质纤维的方法包括向纤维施用至少一种式（IMAGE）化合物，其中R 1表示氢，烷基，乙酰基，苯甲酰基，苯基或羧基烷基，R 2和R 3表示氢，烷基，羟基，卤素，硝基， 烷基苯基，苯基或烷氧基，和下式的氨基嘧啶，其中R 5表示氢，羟基或羟基表示羟基，或者R 7表示H或NH 2，R 8表示氢，R 9和R 10表示氢， 烷基，（CH 2）p Z，其中p为1至4，Z表示OH，卤素，NH 2，NHR'或NHR'R“，其中R'和R”表示烷基或一起形成杂环，条件是 R5至R8表示NH2。

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