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    Compositions for coloring the skin based on indole derivatives
    1.
    发明授权
    Compositions for coloring the skin based on indole derivatives 失效
    基于吲哚衍生物着色皮肤的组合物

    公开(公告)号：US4956174A

    公开(公告)日：1990-09-11

    申请号：US21931

    申请日：1987-03-05

    申请人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    发明人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/46 ,  A61K8/49 ,  A61K8/58 ,  A61K8/86 ,  A61K8/92 ,  A61Q1/02 ,  A61Q19/04

    CPC分类号： A61Q19/04 ,  A61K8/492

    摘要： Cosmetic composition designed to impart to the skin a coloring which is substantially similar to the pigmentation resulting from natural tanning, characterized in that it contains, in a cosmetically acceptable medium suitable for topical application, at least one compound of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom, a lower alkyl group or a residue --SiR.sub.9 R.sub.10 R.sub.11, R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ; R.sub.4 and R.sub.5 which may be identical or different, denote a hydrogen atom, a linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group R.sub.6 OSO.sub.2 --, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or an aralkyl group, or alternatively R.sub.4 and R.sub.5, with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group when at least one of the groups, R.sub.1, R.sub.2 or R.sub.3 is other than hydrogen or alternatively a thiocarbonyl group, a residue >P(O)OR.sub.6, a group >CR.sub.7 R.sub.8 or a methylene group, R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, R.sub.8 denoting a lower alkoxy group or a mono- or dialkylamino group and R.sub.9, R.sub.10 or R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 being other than hydrogen; and the corresponding salts with alkali metals, alkaline earth metals, ammonium or amines.

    摘要翻译： 化妆品组合物被设计成赋予皮肤一种基本上类似于由天然鞣制引起的色素沉着的着色，其特征在于其在适合局部应用的化妆品可接受的介质中包含至少一种下式的化合物： I），其中R 1表示氢原子，低级烷基或残基-SiR 9 R 10 R 11，R 2和R 3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或 一组-COOSiR9R10R11; 可以相同或不同的R 4和R 5表示氢原子，直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， 基团R6OSO2-，基团-SiR9R10R11，基团-P（O）（OR6）2或芳烷基，或者R4和R5与它们所连接的氧原子形成任选含有羰基的环， R 1，R 2或R 3中的至少一个不是氢或硫代羰基，残基> P（O）OR 6，基团> CR 7 R 8或亚甲基，R 6表示氢原子或低级烷基 ，R7表示氢原子或低级烷基，R8表示低级烷氧基或单或二烷基氨基，R9，R10或R11可以相同或不同，表示直链或支链的低级烷基，至少一个 的取代基R 1，R 2，R 3，R 4和R 5不是氢; 和与碱金属，碱土金属，铵或胺的相应的盐。

    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds
    2.
    发明授权
    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds 失效
    基于吲哚衍生物的角质纤维染色组合物和新化合物

    公开(公告)号：US4822375A

    公开(公告)日：1989-04-18

    申请号：US21932

    申请日：1987-03-05

    申请人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    发明人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/41 ,  A61K8/49 ,  A61K8/92 ,  A61Q5/10 ,  C07D209/08 ,  C07D209/12 ,  C07D209/42 ,  C07D491/04 ,  C07D491/056 ,  C07F7/18 ,  C07F9/572 ,  C09B53/00 ,  C09B53/02 ,  C09B57/00 ,  C09B69/00 ,  D06P3/08 ,  A61K7/13 ,  C07D209/30 ,  C07F9/12

    CPC分类号： C07D491/04 ,  A61K8/492 ,  A61Q5/10 ,  C07D209/08 ,  C07F7/1856 ,  C07F9/5728 ,  C09B69/007 ,  C09B69/008

    摘要： Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds.Dyeing composition for keratinous fibres, and especially human hair, characterized in that it contains, in a cosmetically acceptable medium suitable for dyeing these fibres, at least one dye corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a lower alkyl group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group -COOSiR.sub.9 - R.sub.10 R.sub.11 ; and R.sub.5, which may be identical or different, denote at least one linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, the other group R.sub.4 or R.sub.5 being able to be a hydrogen atom, R.sub.4 and R.sub.5 are not simultaneously acetyl, or alternatively R.sub.4 and R.sub.5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a thiocarbonyl group, a group>P(O)OR.sub.6 or>CR.sub.7 R.sub.8 ;R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, and R.sub.8 denotes a lower alkoxy group or a mono- or dialkylamino group, R.sub.9, R.sub.10 and R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, and the cosmetically acceptable salts of alkali metals, alkaline earth metal metals, ammonia or amines.

    摘要翻译： 基于吲哚衍生物的角质纤维染色组合物和新化合物。 用于角质纤维，特别是人类头发的染色组合物，其特征在于，其在适合于染色这些纤维的化妆品可接受的培养基中含有至少一种对应于下式的染料：其中R 1表示氢原子 或低级烷基或-SiR 9 R 10 R 11基团; R2和R3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或基团-COOSiR9-R10R11; 和R 5可以相同或不同，表示至少一个直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， SiR 9 R 10 R 11，基团-P（O）（OR 6）2或基团R 6 OSO 2 - ，另一基团R 4或R 5可以是氢原子，R 4和R 5不同时为乙酰基，或者R4和R5连同 形成任选地含有羰基，硫代羰基，基团> P（O）OR 6或> CR 7 R 8的环的氧原子。 R6表示氢原子或低级烷基，R7表示氢原子或低级烷基，R8表示低级烷氧基或一或二烷基氨基，R9，R10和R11可相同或不同， 表示直链或支链的低级烷基，以及碱金属，碱土金属金属，氨或胺的美容上可接受的盐。

    Use of indole derivative for dyeing keratin materials, tinctorial compositions, new compounds and dyeing process
    6.
    发明授权
    Use of indole derivative for dyeing keratin materials, tinctorial compositions, new compounds and dyeing process 失效
    用于染色材料，化学成分，新化合物和染色工艺的染料衍生用途

    公开(公告)号：US5131911A

    公开(公告)日：1992-07-21

    申请号：US769811

    申请日：1991-10-02

    申请人： Gerard Lang ,  Serge Forestier ,  Alex Junino ,  Herve Richard ,  Jean Jacques Van den Bossche

    发明人： Gerard Lang ,  Serge Forestier ,  Alex Junino ,  Herve Richard ,  Jean Jacques Van den Bossche

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/39 ,  A61K8/49 ,  A61K8/58 ,  A61Q1/00 ,  A61Q5/10 ,  C07D209/08

    CPC分类号： A61Q5/10 ,  A61K8/492 ,  C07D209/08

    摘要： Process for dyeing keratin fibers by using derivatives of formula: ##STR1## where: R.sub.1 =H, lower alkyl or SiR.sub.11 R.sub.12 R.sub.13 ;R.sub.2 and R.sub.3, which may be identical or different, =H, alkyl, carboxyl, alkoxycarbonyl or --COOSiR.sub.11 R.sub.12 R.sub.13 ;R.sub.4 to R.sub.7, which may be identical or different, =H or an O--Z group, where Z=H, C.sub.1 -C.sub.20 alkyl, aralkyl, formyl, C.sub.2 -C.sub.20 acyl, C.sub.3 -C.sub.20 alkenyl, --SiR.sub.11 R.sub.12 R.sub.13, --P(O)(OR.sub.8).sub.2, R.sub.8 OSO.sub.2 ;or a heterocycle which may contain a P(O)(OR.sub.8) or CR.sub.9 R.sub.10 group;with the reservation that at least two of R.sub.4 to R.sub.7 denotes OZ or form a ring, and that at least one of R.sub.4 or R.sub.7 represents OZ;R.sub.8 and R.sub.9 =H, lower alkyl;R.sub.10 =alkoxy, mono- or dialkylamino;R.sub.11, R.sub.12 and R.sub.13, which may be identical or different, are alkyl groups;or their alkali metal, alkaline-earth metal, ammonium and amine salts.

    摘要翻译： 通过使用下式的衍生物染色角蛋白纤维的方法：其中：R1 = H，低级烷基或SiR11R12R13; R2和R3可以相同或不同，= H，烷基，羧基，烷氧基羰基或-COOSiR11R12R13; 其中Z = H，C 1 -C 20烷基，芳烷基，甲酰基，C 2 -C 20酰基，C 3 -C 20链烯基，-SiR 11 R 12 R 13，-P（O）（OR 8），R 4至R 7可以相同或不同， 2，R8OSO2; 或可含有P（O）（OR 8）或CR 9 R 10基团的杂环; 保留R4至R7中的至少两个表示OZ或形成环，并且R4或R7中的至少一个表示OZ; R8和R9 = H，低级烷基; R10 =烷氧基，单或二烷基氨基; R 11，R 12和R 13可以相同或不同，是烷基; 或它们的碱金属，碱土金属，铵和胺盐。

    2-substituted para-aminophenols and their use for dyeing keratinous fibres
    7.
    发明授权
    2-substituted para-aminophenols and their use for dyeing keratinous fibres 失效
    2-取代对氨基苯酚及其用于染色角质纤维的用途

    公开(公告)号：US5202487A

    公开(公告)日：1993-04-13

    申请号：US933583

    申请日：1992-08-24

    申请人： Alex Junino ,  Gerard Lang ,  Alain Genet

    发明人： Alex Junino ,  Gerard Lang ,  Alain Genet

    IPC分类号： C07C217/76 ,  C07C323/29

    CPC分类号： A61K8/415 ,  A61Q5/10 ,  C07C217/76 ,  C07C323/29

    摘要： 2-Substituted para-aminophenols of general formula: ##STR1## where Y denotes oxygen or sulphur and R denotes a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl or C.sub.1 -C.sub.6 haloalkyl or a C.sub.2 -C.sub.6 polyhydroxyalkyl, provided that when Y=O, R is not methyl or ethyl and when Y=S, R is not ethyl; anddye composition containing one or more compounds of formula (I) where Y denotes an oxygen or sulphur atom and R is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.2 -C.sub.6 polyhydroxyalkyl.

    摘要翻译： 2-取代的具有下式的对氨基苯酚：其中Y表示氧或硫，R表示C 1 -C 6烷基，C 1 -C 6羟基烷基或C 1 -C 6卤代烷基或C 2 -C 6多羟基烷基， Y = O，R不是甲基或乙基，当Y = S时，R不是乙基; 和含有一种或多种式（I）的化合物的染料组合物，其中Y表示氧或硫原子，R是C 1 -C 6烷基，C 1 -C 6羟基烷基，C 1 -C 6卤代烷基或C 2 -C 6多羟基烷基。