公开(公告)号：US20060128890A1

公开(公告)日：2006-06-15

申请号：US11297470

申请日：2005-12-09

申请人： Konrad Knoll ,  Daniel Wagner ,  Jurgen Koch ,  Peter Merkel

发明人： Konrad Knoll ,  Daniel Wagner ,  Jurgen Koch ,  Peter Merkel

IPC分类号： C08L53/00

CPC分类号： C08L53/025 ,  C08F297/04 ,  C08L51/003 ,  C08L53/02 ,  C08L2666/24 ,  C08L2666/02 ,  C08L53/00

摘要： Mixtures comprising linear block copolymers composed of vinylaromatic monomers and dienes of the structure (I) S1-B1-S2 and (II) B2-S3, where S1 is a block composed of vinylaromatic monomers whose number-average molar mass Mn is in the range from 40 000 to 1 00 000 g/lmol, each Of S2 and S3 is a block composed of vinylaromatic monomers whose number-average molar mass Mn is in the range from 5000 to 20 000 g/mol, each of B1 and B2 is one or more blocks composed of dienes or is copolymer blocks composed of dienes and vinylaromatic monomers whose number-average molar mass Mn is in the range from 15 000 to 100 000 g/mol, and the ratio of block copolymers (I)/(II) is in the range from 0.5 to 10, and their use for impact-modification of blends using polystyrene.

摘要翻译： 包含由乙烯基芳族单体和结构（I）S 1 -S 1 -S 2 -S 2的二烯构成的线性嵌段共聚物的混合物和（II） B 2 -S 3，其中S 1是由数均摩尔质量M N n的乙烯基芳族单体组成的嵌段， SUB>在40000至10000g / lmol的范围内，每个S 2和S 3是由乙烯基芳族单体组成的嵌段，其数均摩尔数 质量M N n在5000至20000g / mol的范围内，B 1和B 2 2中的每一个是一个或多个组成的嵌段 的二烯或由二烯和乙烯基芳族单体组成的共聚物嵌段，其数均摩尔质量M n N在15 000至100 000g / mol的范围内，嵌段共聚物（I）的比例 /（II）在0.5至10的范围内，并且它们用于使用聚苯乙烯的共混物的冲击改性。

公开(公告)号：US06673857B1

公开(公告)日：2004-01-06

申请号：US09959395

申请日：2001-10-24

申请人： Konrad Knoll ,  Richard Rebizak ,  Rainer Anderlik ,  Sabine Philipp ,  Josef Wünsch

发明人： Konrad Knoll ,  Richard Rebizak ,  Rainer Anderlik ,  Sabine Philipp ,  Josef Wünsch

IPC分类号： C08L510

CPC分类号： C08L53/02 ,  C08L23/04 ,  C08L23/10 ,  C08L23/22 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14

摘要： A thermoplastic elastomer composition comprises a) from 5 to 99% by weight of a block copolymer which is composed of hard blocks S made from vinyl aromatic monomers and of one or more random soft blocks B/S made from dienes and from vinyl aromatic monomers, b) from 1 to 95% by weight of a plasticizer with a higher polarity than white oil and with a lower polarity than diisooctyl phthalate, c) from 0 to 50% by weight of a polyolefin, and d) from 0 to 60% by weight of additives, where the total of a) to d) is 100% by weight. The use of the molding compositions to produce flexible or elastic moldings is described, as are the resultant moldings.

摘要翻译： 一种热塑性弹性体组合物包含：（a）5至99重量％的由乙烯基芳族单体制成的硬质块S和由二烯和乙烯基芳族单体制成的一种或多种无规软嵌段B / S组成的嵌段共聚物，b ）1至95重量％的具有比白油高的极性并且具有比二异辛基邻苯二甲酸酯低的极性的增塑剂，c）0至50重量％的聚烯烃，和d）0至60重量％的 添加剂，其中a）至d）的总量为100重量％。 描述了模制组合物用于生产柔性或弹性模制品的用途，以及所得模制品。

公开(公告)号：US06521712B1

公开(公告)日：2003-02-18

申请号：US09471288

申请日：1999-12-23

申请人： Konrad Knoll ,  Herrmann Gausepohl ,  Wolfgang Fischer ,  Josef Wünsch ,  Paul Naegele ,  Jürgen Koch

发明人： Konrad Knoll ,  Herrmann Gausepohl ,  Wolfgang Fischer ,  Josef Wünsch ,  Paul Naegele ,  Jürgen Koch

IPC分类号： C08F29300

CPC分类号： C08F293/00 ,  C08F293/005 ,  C08F297/04 ,  C08L25/06 ,  C08L51/003 ,  C08L53/02 ,  C08L2666/24 ,  C08L2666/02

摘要： Block copolymers comprise at least two hard blocks S1 and S2 made from vinyl aromatic monomers and, between these, at least ore random soft block B/S made from vinyl aromatic monomers and from dienes, where the proportion of the hard blocks is above 40% by weight, based on the total block copolymer, wherein the 1,2-vinyl content in the soft block B/S is less than 20%.

摘要翻译： 嵌段共聚物包含由乙烯基芳族单体制成的至少两个硬嵌段S1和S2，并且在这些之间，至少是由乙烯基芳族单体制成的矿石随机软嵌段B / S和二烯，其中硬嵌段的比例高于40％ ，基于总嵌段共聚物，其中软嵌段B / S中的1,2-乙烯基含量小于20％。

公开(公告)号：US06399727B1

公开(公告)日：2002-06-04

申请号：US09913993

申请日：2001-08-21

申请人： Konrad Knoll ,  Hans-Herbert Brintzinger ,  Sjoerd Harder ,  Armin Weeber ,  Florian Feil

发明人： Konrad Knoll ,  Hans-Herbert Brintzinger ,  Sjoerd Harder ,  Armin Weeber ,  Florian Feil

IPC分类号： C08F450

CPC分类号： C08F297/04 ,  C08F12/04 ,  C08F36/04 ,  C08F4/50

摘要： Polymerization initiator comprising an alkaline earth metal compound chosen from the group a) of heteroleptic alkaline earth metal compounds of the formula I L—M—R  (I)  or b) of cationic alkaline earth metal complexes of the formula II [D→M—R]+X−  (II),  where M: is Ca, Sr or Ba, L: is a polymerization-inactive ligand, R: is a polymerization-active ligand, D: is a donor ligand, and X: is a non-coordinating anion, and processes for the preparation of the polymerization initiators and processes for anionic polymerization in the presence of the polymerization initiators.

摘要翻译： 聚合引发剂，其包含碱土金属化合物，其选自式I的异位碱土金属化合物，式I））其中M为Ca，Sr或Ba的阳离子碱土金属配合物，L：是聚合 - 无活性配体，R：是聚合活性配体，D：是供体配体，X是非配位阴离子，在聚合引发剂存在下制备聚合引发剂和阴离子聚合方法。

公开(公告)号：US08575269B2

公开(公告)日：2013-11-05

申请号：US12677960

申请日：2008-09-03

申请人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner

发明人： Konrad Knoll ,  Jürgen Koch ,  Piyada Charoensirisomboon ,  Daniel Wagner

IPC分类号： C08L53/02 ,  B32B3/12 ,  B32B1/08

CPC分类号： C08L25/06 ,  C08K5/0016 ,  C08L25/10 ,  C08L53/02 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/24 ,  C08L2666/02

摘要： A mixture which contains a) a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −70° to 0° C., c) a polystyrene C, and its use for the production of packaging for electronics components.

摘要翻译： 包含a）共聚物或嵌段共聚物A的组合物，其包含一种或多种共聚物嵌段（B / S）A，它们分别由65至95重量％的乙烯基芳族单体和35至5重量％的二烯 并且其玻璃化转变温度TgA在40℃至90℃的范围内，b）嵌段共聚物B，其包含至少一个由乙烯基芳族单体组成的硬质块S，并且包含一个或多个共聚物嵌段（B / S）B，其分别由20至60重量％的乙烯基芳族单体和80至40重量％的二烯组成，并且其玻璃化转变温度TgB在-70℃至0℃的范围内， c）聚苯乙烯C及其用于生产电子元件包装的用途。

公开(公告)号：US20110020575A1

公开(公告)日：2011-01-27

申请号：US12921043

申请日：2009-03-04

申请人： Konrad Knoll ,  Koch Jürgen ,  Piyada Charoensirisomboon

发明人： Konrad Knoll ,  Koch Jürgen ,  Piyada Charoensirisomboon

IPC分类号： B32B1/08 ,  C08L53/00

CPC分类号： C08L25/16 ,  C08F297/02 ,  C08F297/04 ,  C08L25/06 ,  C08L53/00 ,  C08L53/02 ,  C08L2205/02 ,  Y10T428/139 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/06

摘要： Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene. The present invention moreover relates to a process for the preparation of the inventive compositions, to the use of the inventive compositions for the production of moldings, of foils, of fibers, or of foams, to moldings, foils, fibers, or foams comprising the inventive composition, and also to the use of the inventive composition as packaging for electronic components, such as integrated circuits (microchips) (“electronic packing”), for applications in chemical engineering, in household products, in bathroom items, e.g. toothbrush tumblers, cosmetics holders, etc., as housings, as tubes, as profiles, for medical items or medical devices, and in toys.

摘要翻译： 组合物，其包含至少一种由至少一种烷基化苯乙烯，丙烯腈和（如果合适的话）至少一种另外的单体组成的共聚物A，至少一种嵌段共聚物B，其具有至少一个形成硬相的嵌段， 至少一种乙烯基芳族单体，并且具有至少一个形成软相并由至少一种乙烯基芳族单体和至少一种二烯构成的嵌段和至少一种其它共聚物C，以及如果合适的话，一种聚合物D，其中共聚物C 是由至少一种乙烯基芳族单体组成的第一嵌段，至少由一种二烯构成的第二嵌段和由至少一种甲基丙烯酸甲酯单体组成的第三嵌段或至少包含至少50％ 的甲基丙烯酸甲酯，聚合物D是选自玻璃透明和耐冲击聚苯乙烯的至少一种苯乙烯聚合物。 本发明还涉及制备本发明组合物的方法，本发明组合物用于生产模制品，箔，纤维或泡沫的用途，用于模制品，箔，纤维或泡沫，其包括 本发明的组合物，以及本发明组合物用作电子部件的包装，例如集成电路（微芯片）（“电子包装”），用于化学工程，家用产品，浴室用品中的应用，例如 牙刷滚筒，化妆品保持器等，作为外壳，作为管，用作医疗用品或医疗装置的型材，以及玩具。

公开(公告)号：US20100261824A1

公开(公告)日：2010-10-14

申请号：US12747369

申请日：2008-12-11

申请人： Konrad Knoll ,  Michel Pepers ,  Peter Wolf ,  Piyada Charoensirisomboon

发明人： Konrad Knoll ,  Michel Pepers ,  Peter Wolf ,  Piyada Charoensirisomboon

IPC分类号： C08K5/09

CPC分类号： D06N1/00

摘要： The present invention relates to a thermoplastic molding composition comprising (A) as component A, particles composed of at least one oxidatively crosslinked vegetable oil as core, encapsulated by at least one thermoplastic, (B) as component B, at least one further thermoplastic compatible with the at least one thermoplastic present in the shell of component A, (C) as component C, at least one resin compatible with the at least one thermoplastic present in the shell of component A, (D) as component D, at least one filler, and (E) as component E, if appropriate, further additives, and also to a process for the production of this thermoplastic molding composition.

摘要翻译： 本发明涉及一种热塑性模塑组合物，其包含（A）作为组分A，由至少一种氧化交联的植物油作为芯组成的颗粒，由至少一种热塑性塑料包封，（B）作为组分B，至少一种另外的热塑性相容性 存在于组分A的外壳中的至少一种热塑性材料（C）作为组分C，至少一种与组分A壳体中存在的至少一种热塑性塑料相容的树脂，（D）作为组分D，至少一种 填充剂和（E）作为组分E，如果合适的话，还可使用其它添加剂，以及制备该热塑性模塑组合物的方法。

公开(公告)号：US20100184889A1

公开(公告)日：2010-07-22

申请号：US12668286

申请日：2008-07-08

申请人： Konrad Knoll ,  Maarten Staal ,  Piyada Charoensirisomboon ,  Volker Warzelhan

发明人： Konrad Knoll ,  Maarten Staal ,  Piyada Charoensirisomboon ,  Volker Warzelhan

IPC分类号： C08K3/04 ,  C08K5/3492

CPC分类号： C08L53/025 ,  C08K3/04 ,  C08K3/32 ,  C08K5/34928 ,  C08L53/02 ,  C08L2666/04 ,  C08L2666/02

摘要： The invention relates to a flameproofed resilient block polymer comprising polymerized units of at least one vinylaromatic monomer and at least one diene monomer with at least one flameproofing agent B) which comprises a compound comprising phosphorus, in particular a phosphorus-containing melamine compound, a process for the preparation and the use for the production of moldings.

摘要翻译： 本发明涉及一种包含至少一种乙烯基芳族单体和至少一种二烯单体与至少一种二烯单体的聚合单元和至少一种防火剂B）的隔爆弹性嵌段聚合物，其包含含磷化合物，特别是含磷三聚氰胺化合物， 用于制备和用于生产模制品。

公开(公告)号：US07064164B2

公开(公告)日：2006-06-20

申请号：US10496080

申请日：2002-11-19

申请人： Konrad Knoll ,  Philippe Desbois ,  Hans-Michael Walter ,  Michael Ishaque ,  Till Gerlach ,  Friederike Osswald

发明人： Konrad Knoll ,  Philippe Desbois ,  Hans-Michael Walter ,  Michael Ishaque ,  Till Gerlach ,  Friederike Osswald

IPC分类号： C08F297/04

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L53/025 ,  C08L2666/24

摘要： The present invention relates to mixtures comprising linear block copolymers made from vinylaromatic monomers and from dienes of the structure (I) S1-B1-S2 and (II) S3-B2-S4, where S1 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 40,000 to 100,000 g/mol, each of S2, S3 and S4 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 5,000 to 20,000 g/mol, each of B1 and B2 is a block made from dienes or a copolymer block made from dienes and from vinylaromatic monomers with numberaverage molar mass Mn in the range from 15,000 to 40,000 g/mol, and the ratio of the block copolymers (I)/(II) is in the range from 0.6 to 2.

摘要翻译： 本发明涉及包含由乙烯基芳族单体和结构式（I）的二烯制备的线性嵌段共聚物的混合物，其中R 1，R 2，R 2， 和（II）S 3 -S 2 -S S 4，其中S 1是一个制成的块 来自具有40,000至100,000g / mol的数均分子量M N n N的乙烯基芳族单体，S 2，S 3， 和S 4是由数均分子量M 2 N 2以上的乙烯基芳族单体制成的嵌段，其数量为5,000〜20,000g / mol，B 1 和B 2是由二烯制成的嵌段或由二烯制成的共聚物嵌段和数均分子量M N n N的乙烯基芳族单体在15,000至 40,000g / mol，嵌段共聚物（I）/（II）的比例在0.6〜2的范围内。

公开(公告)号：US20050215723A1

公开(公告)日：2005-09-29

申请号：US11085473

申请日：2005-03-22

申请人： Konrad Knoll ,  Roland Weidisch

发明人： Konrad Knoll ,  Roland Weidisch

IPC分类号： C08L53/02 ,  C08F293/00

CPC分类号： C08L53/02 ,  C08L2205/02 ,  C08L2666/24

摘要： A blend comprising a) from 5 to 40% by weight of a linear block copolymer of vinylaromatic monomers and dienes of the structure (I) S1—(B/S)1—S2 having a flexible phase fraction (B/S)1 of not more than 55% by weight, based on the block copolymer (I) and b) from 95 to 60% by weight of a linear block copolymer of vinylaromatic monomers and dienes of the structure (II) S3—(B/S)2—S4 having a flexible phase fraction (B/S)2 of at least 65% by weight, based on the block copolymer (II), where S1 is a block of vinylaromatic monomers having a number average molar mass Mn in the range from 40 000 to 100 000 g/mol, S2, S3 and S4 are in each case blocks of vinylaromatic monomers having a number average molar mass Mn in the range from 5000 to 20 000 g/mol, (B/S)1 and (B/S)2 are in each case copolymer blocks of dienes and vinylaromatic monomers having a number average molar mass Mn in the range from 15 000 to 40 000 g/mol.

摘要翻译： 一种共混物，其包含a）5至40重量％的乙烯基芳族单体和结构（I）S 1 - （B / S）1 95至60重量％的乙烯基芳族单体和结构（II）的二烯的线性嵌段共聚物S 3 - （B / S）2 -S < 基于嵌段共聚物（II），具有至少65重量％的柔性相分数（B / S）2 的4 是一种乙烯基芳族单体，其数均摩尔质量M n n在40 000至100 000g / mol的范围内，S 2，S 3， 在每种情况下，数均分子量为5000〜200000g / mol的乙烯基芳族单体的嵌段（B / S）＆lt; 1＆gt;和（B / S）2＆lt; 2＆gt;在各种情况下是二烯和乙烯基的共聚物嵌段 具有15000至40000g / mol的数均摩尔质量M n n N的芳族单体。