Ammonium nitriles and the use thereof as hydrophobic bleaching activators
    41.
    发明授权
    Ammonium nitriles and the use thereof as hydrophobic bleaching activators 失效
    腈类腈及其作为疏水性漂白活化剂的用途

    公开(公告)号:US07015185B2

    公开(公告)日:2006-03-21

    申请号:US10486939

    申请日:2003-03-12

    CPC classification number: C11D3/3925 C07C255/25

    Abstract: The invention relates to ammonium nitriles of general formula (I), wherein the radicals R3, R4, R5 and X− have the meaning as cited in the description and R1 and R2 respectively represent individually a straight or branched chained C5–C24-alkyl, alkenyl or alkylether group. The inventive compounds are used as bleaching activators in washing, cleaning, and disinfective agents and in textile and paper bleaching.

    Abstract translation: 本发明涉及通式(I)的铵腈,其中R 3,R 4,R 5和X 5, - 具有在说明书中引用的含义,R 1和R 2分别独立地表示直链或支链的C 5 - -C 24 - 烷基,烯基或烷基醚基。 本发明化合物用作洗涤,清洁和消毒剂以及织物和纸张漂白中的漂白活化剂。

    Use of transition metal complexes as bleach catalysts in laundry detergents and cleaning compositions
    42.
    发明申请
    Use of transition metal complexes as bleach catalysts in laundry detergents and cleaning compositions 失效
    过渡金属配合物作为漂白催化剂在衣物洗涤剂和清洁组合物中的应用

    公开(公告)号:US20050209120A1

    公开(公告)日:2005-09-22

    申请号:US11041468

    申请日:2005-01-24

    CPC classification number: C11D3/168 C11D3/3932

    Abstract: The use is claimed of transition metal complexes of the formula (I) [M(L)Yn]Xm   (I) where M is a metal atom from the group of Mn and Fe, L is a ligand of the general formula (II) or (III) where R1, R2, R3 and R4 are the same or different and are each H, C1-C8-alkyl or C6-C12-alkaryl; X and Y are each an uncharged or anionic ligand from the group of CH3CN, chloride, bromide, nitrate, perchlorate, sulfate, citrate, hexafluorophosphate, trifluoromethanesulfonate, tetrafluoroborate, tetraphenylborate or an anion of organic acids having C1-C22 carbon atoms, n and m are each a number from 0 to 4 as bleach catalysts in laundry detergents and cleaning compositions.

    Abstract translation: 要求使用式(I)的过渡金属络合物<?in-line-formula description =“In-line Formulas”end =“lead”?> [M(L)Y (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中M是来自Mn和Fe,L的金属原子 是通式(II)或(III)的配体,其中R 1,R 2,R 3和R 4相同或不同,并且各自为H,C 1 -C 8 > - 烷基或C 6 -C 12 - 烷芳基; X和Y各自是来自CH 3 N,CN,氯化物,溴化物,硝酸盐,高氯酸盐,硫酸盐,柠檬酸盐,六氟磷酸盐,三氟甲磺酸盐,四氟硼酸盐,四苯基硼酸盐或有机酸阴离子的不带电荷或阴离子配体 具有C 1 -C 22碳原子,n和m各自为0至4的数,作为洗衣洗涤剂和清洁组合物中的漂白催化剂。

    Alkenylaminomethylenephosphonic acids and copolymers thereof with
unsaturated carboxylic acids
    48.
    发明授权
    Alkenylaminomethylenephosphonic acids and copolymers thereof with unsaturated carboxylic acids 失效
    具有不饱和羧酸的亚甲基氨基磺酰脲类和共聚物

    公开(公告)号:US5126418A

    公开(公告)日:1992-06-30

    申请号:US642519

    申请日:1991-01-17

    CPC classification number: C08F30/02 C07F9/3808

    Abstract: Alkenylaminomethylenephosphonic acids of the formula ##STR1## in which R.sub.1 is hydrogen, C.sub.4 -C.sub.10 -alkyl, phenyl, naphthyl, methylphenyl, hydroxyphenyl, methoxyphenyl, methylnaphthyl, hydroxynaphthyl or methoxynaphthyl,R.sub.2 is hydrogen,R.sub.3, R.sub.4, R.sub.5 are hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl, andM is hydrogen or a cation,and copolymers comprising 0.1-99.9% by weight, preferably 1-50% by weight, of one or more monomers of the formula I, in which R.sub.2 is hydrogen or a group of the formula--CH.sub.2 PO.sub.3 M.sub.2, and 99.9-0.1% by weight, preferably 99-50% by weight, of one or more monomers of the formula IIR.sub.1 'R.sub.2 'C.dbd.CR.sub.3 'X (II)in whichR.sub.1 ' is hydrogen or a group of the formula --COOM,R.sub.2 ' is hydrogen, phenyl or a group of the formula --COOM,R.sub.3 ' is hydrogen, methyl or a group of the formula --COOM or --CH.sub.2 COOM,X is a group of the formula --COOM orR.sub.2 ' and R.sub.3 ' together are a C.sub.4 -alkylene orR.sub.1 ' X together are a group of the formula ##STR2## or R.sub.3 ' and X together are a group of the formula ##STR3## These copolymers are suitable as complexing agents, in particular detergents as builder and co-builder, peroxide stabilizers and as granulating aids for bleaching activators and in crude oil recovery as scale inhibitors having anti-corrosive action.

    Abstract translation: 式(Ⅰ)的烯基氨基亚甲基膦酸,其中R1是氢,C4-C10-烷基,苯基,萘基,甲基苯基,羟基苯基,甲氧基苯基,甲基萘基,羟基萘基或甲氧基萘基,R2是氢,R3,R4,R5是氢 或甲基,R 5是氢,C 1 -C 4 - 烷基或苯基,M是氢或阳离子,和包含0.1-99.9重量%,优选1-50重量%的一种或多种式I单体的共聚物 ,其中R 2是氢或式-CH 2 PO 3 M 2的基团,和99.9-0.1重量%,优选99-50重量%的一种或多种式II的R 1'R 2 C = CR 3'X( II)其中R1'是氢或式-COOM,R2'是氢,苯基或式-COOM的基团,R3'是氢,甲基或式-COOM或-CH2COOM的基团, X是式-COOM或R 2'的基团,R 3'一起是C 4 - 亚烷基或R 1'X一起是下式的基团,或者R 3'和X一起是式 这些共聚物适合作为络合剂,特别是作为助洗剂和助洗剂,过氧化物稳定剂的洗涤剂,以及作为漂白活化剂的造粒助剂和作为具有抗腐蚀作用的防垢剂的原油回收。

    Thrombin inhibitory new dihydroxybenzene ether derivatives
    50.
    发明授权
    Thrombin inhibitory new dihydroxybenzene ether derivatives 失效
    凝血酶抑制新二羟基苯醚衍生物

    公开(公告)号:US4590291A

    公开(公告)日:1986-05-20

    申请号:US385355

    申请日:1982-06-07

    CPC classification number: C07C65/24 C07C59/68 C07C59/90 C07C65/40

    Abstract: An ether derivative of a dihydroxybenzene of the formula ##STR1## in which R.sup.1 is 1 to 3 identical or different substituents selected from hydrogen, halogen, trifluoromethyl, carboxyl, alkyl, alkoxy, alkylmercapto and carbalkoxy, with in each case 1 to 4 carbon atoms in the alkyl and alkoxy groups, andR.sup.2 and R.sup.3 are different and each is an alkyl or alkenyl chain in which 1 or 2 CH.sub.2 chain members are optionally replaced by O, S, CO or a phenylene group, and/or in which the chain is optionally substituted by 1 to 3 identical or different substituents selected from hydroxyl, halogen, trifluoromethyl, phenyl, carboxyl, alkyl, alkoxy, alkylmercapto, carbalkoxy, and acyl, the phenyl radical in turn optionally being substituted by halogen, trifluoromethyl, carboxyl, alkyl, alkoxy, alkylmercapto or carbaloxy, and the abovementioned alkyl, alkoxy and acyl groups in each case containing 1 to 4 carbon atoms, and in which at least one of the radicals R.sup.2 or R.sup.3 is substituted and/or in at least one of the radicals R.sup.2 or R.sup.3 1 or 2 chain members are replaced by 1 or 2 identical or different radicals selected from O, S, CO and phenylene, is effective in combating cardiac infarcations, angina pectoric, thromboembolic illnesses, in venous and arterial regions and arteriosclerosis.

    Abstract translation: 其中R 1是1至3个相同或不同的选自氢,卤素,三氟甲基,羧基,烷基,烷氧基,烷基巯基和烷氧基的取代基的式“IMAGE”的二羟基苯的醚衍生物,在每种情况下为1至4个碳原子 在烷基和烷氧基中,且R 2和R 3不同,并且各自为烷基或烯基链,其中1或2个CH 2链成员任选被O,S,CO或亚苯基取代,和/或其中链 任选地被1至3个相同或不同的选自羟基,卤素,三氟甲基,苯基,羧基,烷基,烷氧基,烷基巯基,烷氧基和酰基的取代基取代,苯基依次任选被卤素,三氟甲基,羧基,烷基 ,烷氧基,烷基巯基或卡巴氧基,以及上述烷基,烷氧基和酰基,每种情况下含有1至4个碳原子,并且其中至少一个基团R 2或R 3被取代和/或至少一个o 基团R 2或R 3 1或2链成员被选自O,S,CO和亚苯基的1或2个相同或不同的基团取代,有效地对抗静脉和动脉区域的心脏梗塞,心绞痛,血栓栓塞性疾病,以及 动脉硬化。

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