Powdered graphite and nonaqueous electrolyte secondary battery
    41.
    发明申请
    Powdered graphite and nonaqueous electrolyte secondary battery 有权
    粉状石墨和非水电解质二次电池

    公开(公告)号:US20060062717A1

    公开(公告)日:2006-03-23

    申请号:US11222616

    申请日:2005-09-09

    IPC分类号: H01M4/58

    摘要: A powdered graphite and a nonaqueous electrolyte secondary battery are provided. A nonaqueous electrolyte secondary battery is provided which has a highly efficient charge and discharge performance and superior cycle properties. Spheroidizing treatment is appropriately performed for natural graphite having a high capacity by grinding and/or applying impact to form a negative electrode active material, and a negative electrode active layer formed therefrom is provided on a metal electrode foil. Subsequently, the metal electrode foil is applied with a magnetic field so that the spheroidized natural graphite is oriented, followed by drying and compression molding, thereby forming a negative electrode. By the use of this negative electrode, a nonaqueous electrolyte secondary battery can be formed having superior battery properties such as the cycle properties and peeling strength.

    摘要翻译: 提供粉状石墨和非水电解质二次电池。 提供了具有高效充放电性能和优异循环性能的非水电解质二次电池。 通过研磨和/或施加冲击形成负极活性物质,适当地对具有高容量的天然石墨进行球化处理,并且在金属电极箔上设置由其形成的负极活性层。 随后,向金属电极箔施加磁场,使球状天然石墨取向,然后进行干燥和压缩成型,从而形成负极。 通过使用该负极,可以形成具有优异的电池特性如循环特性和剥离强度的非水电解质二次电池。

    Nonaqueous electrolyte secondary battery
    42.
    发明授权
    Nonaqueous electrolyte secondary battery 失效
    非水电解质二次电池

    公开(公告)号:US06913856B2

    公开(公告)日:2005-07-05

    申请号:US09837847

    申请日:2001-04-18

    摘要: A nonaqueous electrolyte secondary battery includes a positive electrode having a positive electrode active material, a negative electrode containing a negative electrode active material capable of being doped/undoped with lithium, and a nonaqueous electrolyte. The nonaqueous electrolyte contains at least one of thiols, thiophenes, thioanisoles, thiazoles, thioacetates, aromatic sulfones, and the derivatives thereof. The capacity of the battery is not significantly degraded after cycling and its cycle life is significantly long.

    摘要翻译: 非水电解质二次电池包括具有正极活性物质的正极,含有能够掺杂/未掺杂锂的负极活性物质的负极和非水电解质。 非水电解质含有硫醇,噻吩,硫代苯并咪唑,噻唑,硫代乙酸酯,芳香砜及其衍生物中的至少一种。 循环后电池容量不会明显降低,循环寿命长。

    Carbonate compounds, non-aqueous electrolytic solutions and batteries
comprising non-aqueous electrolytic solutions
    43.
    发明授权
    Carbonate compounds, non-aqueous electrolytic solutions and batteries comprising non-aqueous electrolytic solutions 失效
    碳酸盐化合物,非水电解液和包含非水电解液的电池

    公开(公告)号:US5847188A

    公开(公告)日:1998-12-08

    申请号:US837349

    申请日:1997-04-17

    摘要: A novel carbonate compound represented by the general formula �I!: R.sup.1 CH.sub.2 O--CO--OCH.sub.2 R.sup.2 �I! wherein R.sup.1 represents a hydrogen atom, an alkyl group or an alkyl group substituted with one or more halogen atoms, and R.sup.2 represent an alkyl group having no hydrogen atom at the .alpha.-position thereof or an alkyl group substituted with one or more halogen atoms having no hydrogen atom at the .alpha.-position thereof, with the proviso that R.sup.1 is not identical to R.sup.2, which has excellent properties as solvent, is disclosed. A non-aqueous electrolytic solution and a battery utilizing the novel carbonate compound are also disclosed.

    摘要翻译: 由通式[I]表示的新型碳酸酯化合物:R1CH2O-CO-OCH2R2 [I]其中R1表示氢原子,烷基或被一个或多个卤素原子取代的烷基,R2表示具有 在α位没有氢原子或被一个或多个在其位置没有氢原子的卤素原子取代的烷基,条件是R 1与作为溶剂具有优异性能的R 2不同,是 披露 还公开了一种非水电解液和利用该新型碳酸酯化合物的电池。

    Non-aqueous liquid electrolyte secondary cell
    44.
    发明授权
    Non-aqueous liquid electrolyte secondary cell 失效
    非水电解液二次电池

    公开(公告)号:US5714281A

    公开(公告)日:1998-02-03

    申请号:US851481

    申请日:1997-05-05

    摘要: A non-aqueous liquid electrolyte secondary cell including a cathode formed of metal lithium, a lithium alloy or a material capable of doping/undoping lithium, an anode and a non-aqueous liquid electrolyte formed by an electrolyte dissolved in a non-aqueous solvent. The non-aqueous solvent contains vinylene carbonate. The non-aqueous liquid electrolyte secondary cell may be advantageously employed as a power supply source for a small-sized lightweight portable electronic equipment.

    摘要翻译: 包括由金属锂形成的阴极,锂合金或能够掺杂/不掺杂锂的材料的非水电解液二次电池,由溶解在非水溶剂中的电解质形成的阳极和非水电解液。 非水溶剂含有碳酸亚乙烯酯。 非水电解液二次电池可以有利地用作小尺寸轻型便携式电子设备的电源。

    Secondary battery having non-aqueous electrolyte
    45.
    发明授权
    Secondary battery having non-aqueous electrolyte 失效
    二次电池具有非水电解质

    公开(公告)号:US5561005A

    公开(公告)日:1996-10-01

    申请号:US233992

    申请日:1994-04-28

    IPC分类号: H01M4/58 H01M10/40

    CPC分类号: H01M10/0569 H01M4/583

    摘要: A secondary battery having a non-aqueous electrolyte according to the present invention includes a negative electrode using a carbonaceous material capable of doping and undoping lithium ions as the anode material, a positive electrode using a composite oxide of lithium and-a transition metal as the cathode material, and a non-aqueous electrolyte formed by dissolving an electrolyte into a non-aqueous solvent, the non-aqueous solvent containing methylethyl carbonate and dimethyl carbonate. According to the present invention, a secondary battery having a non-aqueous electrolyte in which normal charge/discharge reactions can be maintained even in battery overcharge and after high-temperature storage of the charged battery, and which exhibits high energy density, long cycle life, high safety performance and excellent environment-resistance, can be produced.

    摘要翻译: 根据本发明的具有非水电解质的二次电池包括使用能够掺杂和去掺杂锂离子作为负极材料的碳质材料的负极,使用锂和过渡金属的复合氧化物的正极作为 阴极材料和通过将电解质溶解在非水溶剂中形成的非水电解质,所述非水溶剂含有碳酸甲乙酯和碳酸二甲酯。 根据本发明,具有非水电解质的二次电池,即使在电池过充电中也能够维持正常的充放电反应,并且在充电电池的高温保存之后,具有高能量密度,长循环寿命 可以生产出高安全性能和优异的耐环境性能。

    Secondary battery having non-aqueous electrolyte
    46.
    发明授权
    Secondary battery having non-aqueous electrolyte 失效
    二次电池具有非水电解质

    公开(公告)号:US5437945A

    公开(公告)日:1995-08-01

    申请号:US131957

    申请日:1993-10-08

    IPC分类号: H01M4/58 H01M6/16 H01M10/40

    摘要: A secondary battery which employs a non-aqueous solvent for the electrolyte and which includes a positive electrode formed of a compound oxide of lithium and a negative electrode of a carbonaceous material is disclosed. The non-aqueous electrolyte, comprised of an electrolyte dissolved in the non-aqueous solvent, is employed in such secondary battery. According to the present invention, a mixed solvent composed of propylene carbonate and methyl ethyl carbonate is employed. The volume ratio of propylene carbonate to methyl ethyl carbonate is 6:4 to 3:7 and preferably 4.5:5.5 to 3:7. As the electrolyte, LiPF.sub.6 is dissolved at a concentration of 0.6 to 1.8 mol/lit. The battery is not increased in its internal pressure even when employed under a high temperature environment, while its electrolyte is not solidified when the battery is employed under a low temperature environment, such that a high energy density, a long service life and high operating reliability may be achieved over a broad range of the working temperature.

    摘要翻译: 公开了一种二次电池,其使用非水溶剂作为电解质,并且包括由锂的复合氧化物形成的正极和碳质材料的负极的二次电池。 在这种二次电池中使用包含溶解在非水溶剂中的电解质的非水电解质。 根据本发明,使用由碳酸丙烯酯和碳酸甲乙酯组成的混合溶剂。 碳酸丙烯酯与碳酸甲乙酯的体积比为6:4〜3:7,优选为4.5:5.5〜3:7。 作为电解液,以0.6〜1.8mol / L的浓度溶解LiPF 6。 即使在高温环境下使用时,电池的内部压力也不会增加,而当电池在低温环境下使用时,其电解质不固化,使得能量密度高,使用寿命长,运行可靠性高 可以在宽的工作温度范围内实现。