摘要:
A powdered graphite and a nonaqueous electrolyte secondary battery are provided. A nonaqueous electrolyte secondary battery is provided which has a highly efficient charge and discharge performance and superior cycle properties. Spheroidizing treatment is appropriately performed for natural graphite having a high capacity by grinding and/or applying impact to form a negative electrode active material, and a negative electrode active layer formed therefrom is provided on a metal electrode foil. Subsequently, the metal electrode foil is applied with a magnetic field so that the spheroidized natural graphite is oriented, followed by drying and compression molding, thereby forming a negative electrode. By the use of this negative electrode, a nonaqueous electrolyte secondary battery can be formed having superior battery properties such as the cycle properties and peeling strength.
摘要:
A nonaqueous electrolyte secondary battery includes a positive electrode having a positive electrode active material, a negative electrode containing a negative electrode active material capable of being doped/undoped with lithium, and a nonaqueous electrolyte. The nonaqueous electrolyte contains at least one of thiols, thiophenes, thioanisoles, thiazoles, thioacetates, aromatic sulfones, and the derivatives thereof. The capacity of the battery is not significantly degraded after cycling and its cycle life is significantly long.
摘要:
A novel carbonate compound represented by the general formula �I!: R.sup.1 CH.sub.2 O--CO--OCH.sub.2 R.sup.2 �I! wherein R.sup.1 represents a hydrogen atom, an alkyl group or an alkyl group substituted with one or more halogen atoms, and R.sup.2 represent an alkyl group having no hydrogen atom at the .alpha.-position thereof or an alkyl group substituted with one or more halogen atoms having no hydrogen atom at the .alpha.-position thereof, with the proviso that R.sup.1 is not identical to R.sup.2, which has excellent properties as solvent, is disclosed. A non-aqueous electrolytic solution and a battery utilizing the novel carbonate compound are also disclosed.
摘要:
A non-aqueous liquid electrolyte secondary cell including a cathode formed of metal lithium, a lithium alloy or a material capable of doping/undoping lithium, an anode and a non-aqueous liquid electrolyte formed by an electrolyte dissolved in a non-aqueous solvent. The non-aqueous solvent contains vinylene carbonate. The non-aqueous liquid electrolyte secondary cell may be advantageously employed as a power supply source for a small-sized lightweight portable electronic equipment.
摘要:
A secondary battery having a non-aqueous electrolyte according to the present invention includes a negative electrode using a carbonaceous material capable of doping and undoping lithium ions as the anode material, a positive electrode using a composite oxide of lithium and-a transition metal as the cathode material, and a non-aqueous electrolyte formed by dissolving an electrolyte into a non-aqueous solvent, the non-aqueous solvent containing methylethyl carbonate and dimethyl carbonate. According to the present invention, a secondary battery having a non-aqueous electrolyte in which normal charge/discharge reactions can be maintained even in battery overcharge and after high-temperature storage of the charged battery, and which exhibits high energy density, long cycle life, high safety performance and excellent environment-resistance, can be produced.
摘要:
A secondary battery which employs a non-aqueous solvent for the electrolyte and which includes a positive electrode formed of a compound oxide of lithium and a negative electrode of a carbonaceous material is disclosed. The non-aqueous electrolyte, comprised of an electrolyte dissolved in the non-aqueous solvent, is employed in such secondary battery. According to the present invention, a mixed solvent composed of propylene carbonate and methyl ethyl carbonate is employed. The volume ratio of propylene carbonate to methyl ethyl carbonate is 6:4 to 3:7 and preferably 4.5:5.5 to 3:7. As the electrolyte, LiPF.sub.6 is dissolved at a concentration of 0.6 to 1.8 mol/lit. The battery is not increased in its internal pressure even when employed under a high temperature environment, while its electrolyte is not solidified when the battery is employed under a low temperature environment, such that a high energy density, a long service life and high operating reliability may be achieved over a broad range of the working temperature.
摘要:
Disclosed are a solvent for cell electrolyte comprising a carbamate represented by the following formula [1]; ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent a linear or branched alkyl group, cell electrolyte and non-aqueous electrolyte battery comprising the solvent. The solvent can provide batteries showing high withstand voltage and excellent charge/discharge efficiency.
摘要:
The present invention relates to a nonaqueous electrolyte secondary battery comprising an anode (3), a cathode (2) and a nonaqueous electrolyte. The anode forming this battery includes composite particles having a carbon material included in a metallic material. As the metallic material, metal capable of electrochemically reacting with lithium in a nonaqueous electrolyte is included.
摘要:
A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.
摘要:
A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.