摘要:
A novel carbonate compound represented by the general formula [I]:R.sup.3 CH.sub.2 O-CO-OCH.sub.2 R.sup.4 [I]wherein R.sup.3 represents an alkyl group or an alkyl group substituted with one or more halogen atoms, and R.sup.4 represent an alkyl group having no hydrogen atom at the .beta.-position thereof or an alkyl group substituted with one or more halogen atoms having no hydrogen atom at the .beta.-position thereof, with the proviso that R.sup.3 is not identical to R.sup.4, which has excellent properties as solvent, is disclosed. A non-aqueous electrolytic solution and a battery utilizing the novel carbonate compound are also disclosed.
摘要:
A novel carbonate compound represented by the general formula �I!: R.sup.1 CH.sub.2 O--CO--OCH.sub.2 R.sup.2 �I! wherein R.sup.1 represents a hydrogen atom, an alkyl group or an alkyl group substituted with one or more halogen atoms, and R.sup.2 represent an alkyl group having no hydrogen atom at the .alpha.-position thereof or an alkyl group substituted with one or more halogen atoms having no hydrogen atom at the .alpha.-position thereof, with the proviso that R.sup.1 is not identical to R.sup.2, which has excellent properties as solvent, is disclosed. A non-aqueous electrolytic solution and a battery utilizing the novel carbonate compound are also disclosed.
摘要:
A non-aqueous liquid electrolyte secondary cell including a cathode formed of metal lithium, a lithium alloy or a material capable of doping/undoping lithium, an anode and a non-aqueous liquid electrolyte formed by an electrolyte dissolved in a non-aqueous solvent. The non-aqueous solvent contains vinylene carbonate. The non-aqueous liquid electrolyte secondary cell may be advantageously employed as a power supply source for a small-sized lightweight portable electronic equipment.
摘要:
A secondary battery having a non-aqueous electrolyte according to the present invention includes a negative electrode using a carbonaceous material capable of doping and undoping lithium ions as the anode material, a positive electrode using a composite oxide of lithium and-a transition metal as the cathode material, and a non-aqueous electrolyte formed by dissolving an electrolyte into a non-aqueous solvent, the non-aqueous solvent containing methylethyl carbonate and dimethyl carbonate. According to the present invention, a secondary battery having a non-aqueous electrolyte in which normal charge/discharge reactions can be maintained even in battery overcharge and after high-temperature storage of the charged battery, and which exhibits high energy density, long cycle life, high safety performance and excellent environment-resistance, can be produced.
摘要:
A secondary battery which employs a non-aqueous solvent for the electrolyte and which includes a positive electrode formed of a compound oxide of lithium and a negative electrode of a carbonaceous material is disclosed. The non-aqueous electrolyte, comprised of an electrolyte dissolved in the non-aqueous solvent, is employed in such secondary battery. According to the present invention, a mixed solvent composed of propylene carbonate and methyl ethyl carbonate is employed. The volume ratio of propylene carbonate to methyl ethyl carbonate is 6:4 to 3:7 and preferably 4.5:5.5 to 3:7. As the electrolyte, LiPF.sub.6 is dissolved at a concentration of 0.6 to 1.8 mol/lit. The battery is not increased in its internal pressure even when employed under a high temperature environment, while its electrolyte is not solidified when the battery is employed under a low temperature environment, such that a high energy density, a long service life and high operating reliability may be achieved over a broad range of the working temperature.
摘要:
Disclosed are a solvent for cell electrolyte comprising a carbamate represented by the following formula [1]; ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent a linear or branched alkyl group, cell electrolyte and non-aqueous electrolyte battery comprising the solvent. The solvent can provide batteries showing high withstand voltage and excellent charge/discharge efficiency.
摘要:
A non-aqueous electrolytic solutions which has self-distinguishing property, low reactivity to metal lithium and high withstand voltage is provided. The non-aqueous electrolytic solutions of the first invention comprise, as electrolyte, lithium salt preferably LiPF.sub.6 and, as solvent, phosphoric acid esters of the following general formula [1]; ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, represent an alkyl group or an alkyl group substituted by one or more halogen atoms and at least one of R.sup.1, R.sup.2, and R.sup.3 represents an alkyl group substituted by one or more halogen atoms. The non-aqueous electrolytic solutions of the second invention comprise, as solvents for electrolyte, trimethyl phosphate, one or more linear carbonates represented by the following general formula [3]; ##STR2## (wherein R.sup.6 represents methyl or ethyl group and R.sup.7 represents a linear or branched alkyl group having 1 to 3 carbon atoms) and one or more cyclic carbonates and, as electrolyte, LiPF.sub.6 ; wherein content of the trymetyl phosphate is 1 to 10% by volume of the solvents for electrolyte. The non-aqueous electrolytic solution is suitable for a cell using carbon material capable of being doped and dedoped with lithium ions as a negative electrode active material and complexed oxide of lithium and a transition metal as a positive electrode active material.
摘要:
The purpose of the present invention is to provide: an adhesive composition for optical applications, which is capable of suppressing luminance unevenness without deteriorating the contrast characteristics in optical applications, and which can be used for optical members and prevents the optical members from separation in a reliability test; an adhesive layer; an optical member; an image display device and the like. An adhesive composition for optical applications, which contains a modified (meth)acrylic graft polymer and an isocyanate crosslinking agent, is prepared. The modified (meth)acrylic graft polymer is obtained by graft polymerizing chains, each of which contains a cyclic ether group-containing monomer, to the trunk polymer, and contains, as constituent components, an alkyl(meth)acrylate, a cyclic ether group-containing monomer, and an acyclic ether group-containing monomer. An adhesive layer for optical applications, which is formed from the composition, an optical member, an image display device and the like are also produced.
摘要:
Disclosed is an optical sheet with an adhesive layer, which has excellent adhesion, excellent aggregability and excellent long-term durability, and wherein an adhesive layer part does not fill recesses and projections over time, said recesses and projections having been formed by processing. Specifically, an optical sheet with an adhesive layer is produced by arranging an adhesive layer on a recessed and projected surface of an optical film which has been subjected to processing for forming recesses and projections. In addition, the optical sheet with an adhesive layer is bonded to various light sources or image display elements, thereby obtaining light sources or image display devices that have improved light extraction efficiency without changing the designs of the light sources or image display elements, while securing uniform light emission and improving viewing angles especially in devices that comprises the image display elements.
摘要:
A reactive polymer-supporting porous film is provided as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film. The partially crosslinked reactive polymer is obtained by the reaction of a crosslinkable polymer having at least one group selected from the 3-oxetanyl group and epoxy group reactive with a polycarboxylic acid. The reactive polymer-supporting porous film has a separator and electrodes sufficiently bonded to each other and with low inner resistance suitably used for production of battery excellent in high rate performance. Further, provided is a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and electrodes together.