公开(公告)号：US5115040A

公开(公告)日：1992-05-19

申请号：US718193

申请日：1991-06-20

申请人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

发明人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

IPC分类号： A61K8/72 ,  A61K8/00 ,  A61Q5/00 ,  A61Q5/02 ,  B01F17/18 ,  C08F8/02 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08F20/34 ,  C08F220/34 ,  C08G81/02 ,  C09K3/16 ,  D06M15/267

CPC分类号： A61Q5/02 ,  A61K8/8152 ,  A61Q5/12 ,  C08F8/44

摘要： Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with dialkylaminoalkanols, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.

公开(公告)号：US5076844A

公开(公告)日：1991-12-31

申请号：US580863

申请日：1990-09-11

申请人： Jurgen Fock ,  Gunther Hahn ,  Gunter Wagerknecht

发明人： Jurgen Fock ,  Gunther Hahn ,  Gunter Wagerknecht

IPC分类号： A61K6/083 ,  C07C271/16 ,  C08F20/36 ,  C08G18/28 ,  C08G18/81

CPC分类号： A61K6/083 ,  C07C271/16 ,  C08F20/36 ,  C08G18/2885 ,  C08G18/8116

摘要： Macromonomeric (meth-)acrylate esters, having fluoroalkyl groups are disclosed. The esters have the general formula ##STR1## wherein R.sup.1 is the same or different and represents a hydrogen or fluorine groupR.sup.2 is the same or different and represents a hydrogen or methyl group,a has a value of 0, 1, 2, 3 or 4,c has a value of 2, 3 or 4,b has an average value of 2 to 30n has an average value of 4 to 12 andm has an average value of 3 to 14.The products can be used in dentistry, preferably as relining material for dental prostheses. The esters have a lower solubility and a higher mechanical strength when cured and adhere to already cured poly(methyl methacrylate).

摘要翻译： 公开了具有氟代烷基的大分子单体（甲基）丙烯酸酯。 酯具有通式为：其中R1相同或不同，表示氢或氟基团R2相同或不同，表示氢或甲基，a的值为0,1 2,3或4中，c的值为2,3或4，b的平均值为2〜30n，平均值为4〜12，m的平均值为3〜14。 用于牙科，优选用作牙科假体的修复材料。 当固化并粘附到已经固化的聚（甲基丙烯酸甲酯）时，酯具有较低的溶解度和较高的机械强度。

公开(公告)号：US5001189A

公开(公告)日：1991-03-19

申请号：US467792

申请日：1990-01-19

申请人： Jurgen Fock ,  Dietmar Schedlitzki

发明人： Jurgen Fock ,  Dietmar Schedlitzki

IPC分类号： C08G18/08 ,  C08G18/50 ,  C08G18/67 ,  C08G65/26 ,  C08G65/32 ,  C08G65/326

CPC分类号： C08G65/2609 ,  C08G18/0828 ,  C08G18/5072 ,  C08G65/326

摘要： Polyoxylalkylene ether with an average molecular weight of 400 to 10,000 with at least one terminal hydroxyl group and at least one lateral --SO.sub.3 X group (X=hydrogen, alkali metal or ammonium ion) is disclosed. The polyoxyalkylene ether is obtainable by the statistical or blockwise addition reaction of (a) .alpha.-alkylene oxides with 2 to 14 carbon atoms or mixtures thereof and (b) allyl and/or methallyl glycidyl ethers to monohydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule, reacting the polymer by a known reaction with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO.sub.3 Y (Y=alkali or ammonium ion) and if necessary, exchanging the cation Y against a hydrogen ion also by a known procedure.The compounds are suitable as polyol components for the preparation of stable, ionic, aqueous polyurethane dispersions with a high solids content.

公开(公告)号：US4927961A

公开(公告)日：1990-05-22

申请号：US414659

申请日：1989-09-29

申请人： Jurgen Fock ,  Dietmar Schedlitzki

发明人： Jurgen Fock ,  Dietmar Schedlitzki

IPC分类号： C08G18/08 ,  C08G18/50 ,  C08G18/67 ,  C08G65/26 ,  C08G65/32 ,  C08G65/326

CPC分类号： C08G65/2609 ,  C08G18/0828 ,  C08G18/5072 ,  C08G65/326

摘要： Polyoxylalkylene ether with an average molecular weight of 400 to 10,000 with at least one terminal hydroxyl group and at least one lateral --SO.sub.3 X group (X=hydrogen, alkali metal or ammonium ion) is disclosed. The polyoxyalkylene ether is obtainable byThe statistical or blockwise addition reaction of (a) .alpha.-alkylene oxides with 2 to 14 carbon atoms or mixtures hereof and (b) allyl and/or methallyl glycidyl ethers to monohydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule,reacting the polymer by a known reaction with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO.sub.3 Y (Y=alkali or ammonium ion) andif necessary, exchanging the cation Y against a hydrogen ion also by a known procedure.The compounds are suitable as polyol components for the preparation of stable, ionic, aqueous polyurethane dispersions with a high solids content.

摘要翻译： 公开了具有至少一个末端羟基和至少一个侧面-SO 3 X基团（X =氢，碱金属或铵离子）的平均分子量为400至10,000的聚氧化亚烷基醚。 聚氧化烯醚可以通过（a）具有2至14个碳原子的α-亚烷基氧化物或其混合物的统计学或阻滞加成反应获得，和（b）烯丙基和/或甲代烯丙基缩水甘油醚与一元至四元脂肪醇与多达8个 选择组分（a）与组分（b）的比例，使得至少一个烯丙基醚基团与平均分子连接，使已知反应的聚合物与基于烯丙基醚基团的反应至少 等摩尔量的式HSO 3 Y的化合物（Y =碱或铵离子），如果需要，也可以通过已知的方法将阳离子Y与氢离子交换。 该化合物适用作多元醇组分，用于制备具有高固体含量的稳定的离子型水性聚氨酯分散体。

公开(公告)号：US4207379A

公开(公告)日：1980-06-10

申请号：US929408

申请日：1978-07-31

申请人： Jurgen Fock ,  Eckehard Schamberg ,  Werner Schafer

发明人： Jurgen Fock ,  Eckehard Schamberg ,  Werner Schafer

IPC分类号： B32B21/08 ,  B05D7/04 ,  B05D7/06 ,  B32B27/04 ,  B32B27/08 ,  B32B27/10 ,  B32B27/36 ,  C08F283/00 ,  C08J5/24 ,  C08L67/06 ,  D06N7/00 ,  D06N7/02 ,  D06N7/04 ,  D06N7/06 ,  D21H17/51 ,  D21H19/28 ,  D21H27/28 ,  B32B27/06 ,  B32B23/08

CPC分类号： D21H19/28 ,  D21H27/28 ,  D21H17/51 ,  Y10T428/31786 ,  Y10T428/31906 ,  Y10T428/31957 ,  Y10T428/3196 ,  Y10T428/31964 ,  Y10T428/31967

摘要： This invention relates to an improvement in a substrate web coated with a thermosetting coating resin and optionally impregnated with an aminoplast resin, in particular a web of paper, for the surface finishing of woodwork panels or laminates, the improvement that the coating resin is a modified polyester resin, composed of (a) 60 to 95% by weight of a hardenable polyester resin, (b) 1 to 15% by weight of a cross-linking agent for the polyester resin, (c) 5 to 40% by weight of a thermoplastic containing predominantly linear, high-molecular weight, reactive groups, (d) 1 to 15% by weight of a monomer with at least one polymerizable double bond and at least one group which reacts with the reactive group of the thermoplastic, and (e) a hardening catalyst, and optionally dyes, pigments and/or fillers. The invention also relates to a process for preparing a synthetic resin coated substrate web.

摘要翻译： 本发明涉及一种涂覆有热固性涂层树脂并任选地浸渍有氨基塑料树脂，特别是纸幅的基材网的改进，用于木工板或层压板的表面处理，涂层树脂是改性的 由（a）60〜95重量％的可硬化聚酯树脂构成的聚酯树脂，（b）1〜15重量％的聚酯树脂用交联剂，（c）5〜40重量％ 含有主要线性，高分子量反应性基团的热塑性塑料，（d）1至15重量％的具有至少一个可聚合双键的单体和至少一个与热塑性弹性体反应基团反应的基团，和（ e）硬化催化剂，以及任选的染料，颜料和/或填料。 本发明还涉及一种制备合成树脂涂覆的基材网的方法。

公开(公告)号：US4177221A

公开(公告)日：1979-12-04

申请号：US847753

申请日：1977-11-02

申请人： Eckehard Schamberg ,  Jurgen Fock ,  Otto Klocker ,  Eberhard Esselborn

发明人： Eckehard Schamberg ,  Jurgen Fock ,  Otto Klocker ,  Eberhard Esselborn

IPC分类号： C08F299/00 ,  B32B21/08 ,  B32B27/36 ,  C08F283/01 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  C08L67/06 ,  C08L29/14

CPC分类号： C08L67/06

摘要： This invention relates to a thermosetting, substrate-free, storage-resistant synthetic resin foil which is hard, scratch- and abrasion-proof in the hardened state, comprising: (a) about 60 to 95% by weight of a hardenable polyester resin, (b) about 1 to 15% by weight of a cross-linking agent for the polyester resin, (c) about 5 to 40% by weight of a thermoplastic containing predominantly linear, high-molecular weight reactive groups, (d) about 1 to 15% by weight of a monomer with at least one polymerizable double bond and at least one group reactable with the reactive group of the thermoplastic under the conditions of reaction, (e) and at least one hardening catalyst, and optionally dyestuffs, pigments and/or fillers. The invention also relates to a process for preparing the novel foil of the invention.

摘要翻译： 本发明涉及一种在硬化状态下硬，耐划伤和耐磨损的热固性，无基材的耐储存合成树脂箔，包括：（a）约60至95重量％的可硬化聚酯树脂， （b）约1至15重量％的用于聚酯树脂的交联剂，（c）约5至40重量％的主要具有线性，高分子量反应性基团的热塑性塑料，（d）约1至约1重量％ 至少15重量％的具有至少一个可聚合双键的单体和至少一个可在反应条件下与热塑性弹性体反应的基团，（e）和至少一种硬化催化剂，以及任选的染料，颜料和 /或填料。 本发明还涉及制备本发明的新型箔的方法。

公开(公告)号：US4138450A

公开(公告)日：1979-02-06

申请号：US815235

申请日：1977-07-13

申请人： Jurgen Fock ,  Eckehard Schamberg ,  Wolfgang Hoffmann

发明人： Jurgen Fock ,  Eckehard Schamberg ,  Wolfgang Hoffmann

IPC分类号： C08F265/00 ,  C08F265/04 ,  C08L33/20

CPC分类号： C08F265/04 ,  Y10T428/31891

摘要： This invention relates to a copolymerizate foil suitable for surface finishing, and which may be thermosetting, composed of:(A) an elastomeric copolymerizate with a glass transition temperature no higher than +10.degree. C., obtained by copolymerizing(a) 70 to 99% by weight of an acrylic acid alkyl ester with 1 to 8 carbon atoms in the alkyl residue,(b) 1 to 20% by weight of at least one of a hydroxyalkyl ester with 2 to 4 carbon atoms in the alkyl residue, and an acid amide of acrylic or methacrylic acid,(c) 0 to 20% by weight of at least one of acrylonitrile and methacrylonitrile, and optionally(d) 0 to 2% by weight of a cross-linking monomer with at least two reactive, non-conjugated double bonds in the molecule, the reactivity of the double bonds possibly varying,Where the sum of a, b, c, and d amounts to 100% by weight, acting as the grafting base, onto which is grafted(B) a hard-brittle copolymerizate obtained by copolymerizing(a) 10 to 60% by weight of at least one of styrene and one or more methacrylic acid alkyl esters with 1 to 20 carbon atoms in the alkyl residue,(b) 1 to 10% by weight of an acrylic acid alkyl ester with 1 to 8 carbon atoms in the alkyl residue,(c) 0 to 20% by weight of an N-methoxymethyl amide of at least one of acrylic acid and methacrylic acid,(d) 0 to 20% by weight of a hydroxyalkyl ester of acrylic or methacrylic acid with 2 to 4 carbon atoms in the alkyl residue,(e) 0 to 20% by weight of acrylic or methacrylic acid amide, the molar ratio of component c to the sum of d and e being about 1 : 1 and that of d : e ranging from 4 : 1 to 1 : 4, and optionally(f) >20 to 75% by weight of at least one of acrylonitrile and methacrylonitrile,Where the sum of components a through f is 100% by weight and where the ratio by weight of the elastomeric copolymerizate A to the hard-brittle copolymerizate B is 1 : 3 to 1 : 20.

摘要翻译： 本发明涉及适用于表面处理的共聚合箔，其可以是热固性的，由以下组成：