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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    45.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化组分

    公开(公告)号：US20120316300A1

    公开(公告)日：2012-12-13

    申请号：US13579029

    申请日：2011-02-22

    申请人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T.M. Pater ,  Giampiero Morini

    发明人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T.M. Pater ,  Giampiero Morini

    IPC分类号： C08F4/649 ,  C08F210/06

    CPC分类号： C08F110/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F4/6465 ,  C08F2500/15

    摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) wherein: R2, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements or alkoxy groups of formula —OR1, two or more of the R2 groups can be connected together to form a cycle; R1, equal to or different from each other, are C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements, with the proviso that at least one of R2 is —OR1 and the other being selected from succinates of formula (II): wherein the radicals RI and RII, equal to or different from each other, are a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; the radicals RIII to RVI equal to or different from each other, are hydrogen or a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms, and the radicals RIII to RVI which are joined to the same carbon atom of the succinate chain can be linked together to form a cycle.

    摘要翻译： 用于烯烃CH 2 = CHR的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一个选自式（I）的那些，其中：R2 彼此相同或不同的是氢原子或任选含有属于式-OR1的元素或烷氧基的周期表第13-17族的杂原子的C1-C20烃基，R2基中的两个或更多个可以 连接在一起形成一个循环; R1彼此相同或不同的是C1-C20烃基，其任选地含有属于元素周期表第13-17族的杂原子，条件是R 2中的至少一个为-OR 1且另一个选自 来自式（II）的琥珀酸盐：其中基团R 1和R II彼此相同或不同，是任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基; RIII至RVI彼此相同或不同的基团是氢或任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳烷基或烷基芳基，以及RIII至RVI基团连接至 琥珀酸酯链的相同碳原子可以连接在一起形成循环。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    46.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化组分

    公开(公告)号：US20120302709A1

    公开(公告)日：2012-11-29

    申请号：US13579027

    申请日：2011-02-22

    申请人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T.M. Pater ,  Giampiero Morini

    发明人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T.M. Pater ,  Giampiero Morini

    IPC分类号： C08F4/649

    CPC分类号： C08F110/06 ,  C08F4/6545 ,  C08F4/6465 ,  C08F4/651 ,  C08F2500/15

    摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where RI and RII are the same or different and are hydrogen or linear or branched C1-C18 hydrocarbon groups which can also form one or more cyclic structures; RIII groups, equal or different from each other, are hydrogen or C1-C18 hydrocarbon groups; RIV groups equal or different from each other, have the same meaning of RIII except that they cannot be hydrogen; each of RI to RIV groups can contain heteroatoms selected from halogens, N, O, S and Si.

    摘要翻译： 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两种电子给体化合物，其中一种选自烷氧基苯，另一种选自那些 其中R 1和R II相同或不同，为氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。

    Synthesis of Cyclopentadienedithiophene Derivatives
    49.
    发明申请
    Synthesis of Cyclopentadienedithiophene Derivatives 审中-公开
    环戊二烯二噻吩衍生物的合成

    公开(公告)号：US20090118522A1

    公开(公告)日：2009-05-07

    申请号：US11992033

    申请日：2006-09-15

    申请人： Simona Guidotti

    发明人： Simona Guidotti

    IPC分类号： C07D495/04

    CPC分类号： C07D495/04

    摘要： A process for preparing cyclopentadiene derivatives having formula (I) wherein T1 is selected from the group consisting of oxygen (O), or sulphur (S); R1, R2, R3 and R4, are hydrogen atoms, or hydrocarbon radicals; comprising the following steps: a) reacting a compound of formula (II) with a compound of formula (III) in the presence of a palladium or nickel based catalyst and a base; b) contacting the obtained compound with a carbonylating system; and c) treating the product obtained in step b) with a reducing agent.

    摘要翻译： 一种制备式（I）的环戊二烯衍生物的方法，其中T1选自氧（O）或硫（S）; R1，R2，R3和R4是氢原子或烃基; 包括以下步骤：a）在钯或镍基催化剂和碱的存在下使式（II）化合物与式（III）化合物反应; b）使所得化合物与羰基化体系接触; 和c）用还原剂处理步骤b）中获得的产物。