摘要:
Processes for the enzyme-catalyzed synthesis of triglycerides containing polyunsaturated fatty acids in which the synthesis is preceded by a pre-hydrolysis in which (a) C1-4 alkyl esters of polyunsaturated fatty acids are completely or partly hydrolyzed in vacuo with continuous addition of water or are partly hydrolyzed in several stages without vacuum, (b) after the hydrolysis, the water is removed by separation or distillation and (c) the synthesis of the polyunsaturated fatty acids with glycerol in vacuo in the presence of an enzyme to form their triglycerides is carried out under low-water conditions, (d) the enzymes are removed from the triglyceride by separation or filtration and (e) the remaining fatty acids and/or possible residues of C1-4 alkyl esters are removed from the triglyceride by distillation or refining; the pre-hydrolysis and the subsequent synthesis preferably being carried out as a one-pot process in the same reactor and in the presence of the same enzyme.
摘要:
Processes for preparing conjugated fatty acid glycerides comprising: (a) isomerizing a fatty acid lower alkyl ester corresponding to the general formula (I) in the presence of a basic catalyst at a temperature of from 100 to 160° C., to form a conjugated fatty acid lower alkyl ester: R1CO—OR2 (I) wherein R1CO represents an acyl radical having from 16 to 22 carbon atoms and at least two carbon-carbon unsaturations and R2 represents an alkyl radical having from 1 to 4 carbon atoms; and (b) transesterifying the conjugated fatty acid lower alkyl ester with glycerol to form a conjugated fatty acid glyceride, wherein a lower alkanol corresponding to the general formula R2OH is formed, wherein R2 is as defined above, and the lower alkanol is continuously removed from the transesterification reaction; are described.
摘要:
The present invention relates to a process for the preparation of polydiorganosiloxane block copolycarbonates having special bridging members between the siloxane blocks and the carbonate blocks, and the polydiorganosiloxane block copolycarbonates which are obtainable by the process according to the invention and with which optionally further customary additives can be mixed.
摘要:
A powder containing particles, which particles include gum arabic and at least one polyunsaturated fatty acid (PUFA) ester, where the ratio by weight of the quantity of gum arabic present in the particles to the quantity of the polyunsaturated fatty acid ester present in the particles is from about 1:1.4 to about 1:0.25, is provided. A process for the production of the particles is also provided.
摘要:
Compositions in powder form of sterols or stanol esters, and milk powder and/or proteins are disclosed. A process of making the compositions is also disclosed. The suitability of incorporation of the compositions in powder form in food products, for example beverages and milk products, is also disclosed.
摘要:
The invention relates to a process for the enzymatic synthesis of esters of polyunsaturated, short-chain or sensitive fatty acids with a high triglyceride content, which is made up of an enzymatic synthesis of the mixture of triglycerides and partial glycerides starting from free fatty acid, methyl or ethyl esters and glycerol, a subsequent selective enzymatic back-hydrolysis of the partial glycerides to fatty acid and glycerol and distillation-based separation of the triglycerides, and to the triglyceride-rich ester mixtures obtainable by this process. The process is preferably carried out as a one-pot process in the same reactor and in the presence of the same enzyme.
摘要:
Processes for preparing conjugated fatty acid glycerides comprising: (a) isomerizing a fatty acid lower alkyl ester corresponding to the general formula (I) in the presence of a basic catalyst at a temperature of from 100 to 160° C., to form a conjugated fatty acid lower alkyl ester: R1CO—OR2 (I) wherein R1CO represents an acyl radical having from 16 to 22 carbon atoms and at least two carbon-carbon unsaturations and R2 represents an alkyl radical having from 1 to 4 carbon atoms; and (b) transesterifying the conjugated fatty acid lower alkyl ester with glycerol to form a conjugated fatty acid glyceride, wherein a lower alkanol corresponding to the general formula R2OH is formed, wherein R2 is as defined above, and the lower alkanol is continuously removed from the transesterification reaction; are described.
摘要:
Processes for producing conjugated linoleic acid are described which comprise: (a) isomerizing a linoleic acid lower alkyl ester in the presence of an alkali metal alcoholate to form a conjugated linoleic acid lower alkyl ester; (b) saponifying the conjugated linoleic acid lower alkyl ester in the presence of an aqueous lye to form a saponification product; and (c) neutralizing the saponification product with phosphoric acid.
摘要:
The disclosed invention relates to emulsions containing, based on the total weight of the emulsion, a) 0.1 to 50% by weight of a conjugated linoleic acid or derivative thereof, b) 0.1 to 30% by weight of a vegetable lecithin mixture, c) 0 to 20% by weight of a co-emulsifier, d) 0 to 70% by weight of a polyol, e) 0 to 70% by weight of a carbohydrate, f) 0 to 1% by weight of an antioxidant, and g) 20 to 99% by weight of an aqueous phase, with the proviso that the emulsion contains no other oils and fats except for the triglycerides of components a), b) and/or c) optionally present. The emulsions may be directly processed in foods, more particularly beverages, and show high stability in storage.
摘要:
A process for producing a graft copolymer is disclosed. The graft copolymer, based on a rubber which contains phenolic OH groups and grafted with polycarbonate chains is produced under the conditions of the two-phase interfacial polycondensation. Also disclosed are gasoline resistant thermoplastic polycarbonate compositions containing the graft.