公开(公告)号：US20070100061A1

公开(公告)日：2007-05-03

申请号：US11585197

申请日：2006-10-24

申请人： Takayuki Hattori ,  Katsumi Terakawa ,  Naoya Ichikawa ,  Toshiaki Sakaki ,  Gan Neon ,  Lee Yin

发明人： Takayuki Hattori ,  Katsumi Terakawa ,  Naoya Ichikawa ,  Toshiaki Sakaki ,  Gan Neon ,  Lee Yin

IPC分类号： C08K5/00

CPC分类号： B60C1/0016 ,  B60C1/0025 ,  C08K5/103 ,  C08K5/11 ,  C08L21/00 ,  C08L67/02 ,  C08L67/08 ,  C08L2205/03 ,  C08L7/00 ,  C08L2666/14

摘要： A rubber composition for a tire, in which a specific tackifier is compounded, and tackiness and various physical properties are improved, compared with compounding a petroleum resin or a terpene resin, is provided. The rubber composition for a tire comprising an alkyd resin and a pneumatic tire using the same. It is preferable that a material derived from a resource other than petroleum, particularly, a material derived from animal and/or vegetable, and more particularly, a material derived from an animal oil and/or a vegetable oil is contained in the alkyd resin, and it is preferable that unsaturated polybasic acid is contained in the alkyd resin.

摘要翻译： 与混合石油树脂或萜烯树脂相比，提供了一种轮胎的橡胶组合物，其中特定的增粘剂配混，粘合性和各种物理性能得到改善。 包含醇酸树脂的轮胎用橡胶组合物和使用其的充气轮胎。 优选在醇酸树脂中含有源自石油以外的资源的材料，特别是源自动物和/或植物的材料，更具体地，衍生自动物油和/或植物油的材料， 优选在醇酸树脂中含有不饱和多元酸。

公开(公告)号：US07015264B2

公开(公告)日：2006-03-21

申请号：US10615839

申请日：2003-07-10

申请人： Naoya Ichikawa ,  Yoshiaki Miyamoto ,  Akihiko Hamada

发明人： Naoya Ichikawa ,  Yoshiaki Miyamoto ,  Akihiko Hamada

IPC分类号： C08C1/04 ,  C12N9/96

CPC分类号： C08J5/02 ,  C08C1/04 ,  C08J2307/00 ,  C12N9/54 ,  C12N9/96

摘要： The present invention relates to (1) a deproteinizing agent for natural rubber latex, comprising a protease and one or more water-soluble polymers as an active component; (2) a deproteinized natural rubber latex, which is prepared by subjecting to a deprotenization treatment using the deproteinizing agent, and a method of producing the same; (3) a method of producing a rubber product, which comprises incorporating at least a vulcanizing agent into the latex (2), dipping a mold in the resulting compound latex, and vulcanizing and drying a rubber film formed on the mold; and (4) a method of producing a rubber product, which comprises incorporating at least a heat sensitizer and a vulcanizing agent into the latex (2), dipping a mold in the resulting heat-sensitive coagulable compound latex, and vulcanizing and drying a rubber film formed on the mold.

摘要翻译： 本发明涉及（1）天然橡胶胶乳的脱蛋白剂，其包含蛋白酶和一种或多种水溶性聚合物作为活性成分; （2）通过使用脱蛋白剂进行脱皂化处理而制备的脱蛋白天然橡胶胶乳及其制造方法; （3）一种橡胶制品的制造方法，其特征在于，在所述胶乳（2）中至少含有硫化剂，将模具浸渍在所得的复合胶乳中，硫化，干燥形成在所述模具上的橡胶膜; （4）一种橡胶制品的制造方法，其特征在于，在胶乳（2）中至少含有热敏剂和硫化剂，将模具浸渍在所得的热敏性凝固性化合物胶乳中，硫化，干燥橡胶 胶片在模具上形成。

公开(公告)号：US06943212B2

公开(公告)日：2005-09-13

申请号：US10082243

申请日：2002-02-26

申请人： Naoya Ichikawa ,  Yoshiaki Miyamoto

发明人： Naoya Ichikawa ,  Yoshiaki Miyamoto

IPC分类号： C08C1/04 ,  C08K3/04

CPC分类号： C08C1/04

摘要： The present invention provides a deproteinized natural rubber latex wherein coagulation of a rubber component does not occur when the concentration of calcium ions (Ca2+) is 0.01 mol/L or less and coagulation of the rubber component occurs when the concentration of Ca2+ is 0.1 mol/L or more; a method of preparing the deproteinized natural rubber latex, which comprises adding a protease and two or more surfactants having different coagulation properties to calcium ions (Ca2+) to a natural rubber latex and maturing the natural rubber latex; a rubber product using the deproteinized natural rubber latex; and a proteolytic agent comprising a protease and two or more surfactants. The deproteinized natural rubber latex is a latex wherein rubber molecules are dispersed and stabilized by a surfactant, and also have good film forming properties by means of the anode coagulation method and is less likely to cause uneven thickness of the film and liquid dripping even when a mold is dipped repeatedly in a latex on formation of a rubber film.

摘要翻译： 本发明提供一种脱蛋白天然橡胶胶乳，其中当钙离子浓度（Ca 2+）为0.01mol / L以下时，橡胶成分的凝固不发生，并且发生橡胶组分的凝结 当Ca 2+浓度为0.1mol / L以上时， 一种制备脱蛋白天然橡胶胶乳的方法，其包括将蛋白酶和两种或更多种具有不同凝固性质的表面活性剂与钙离子（Ca 2+ 2 +）加入到天然橡胶胶乳中并熟化天然橡胶胶乳 ; 使用脱蛋白天然橡胶胶乳的橡胶制品; 和包含蛋白酶和两种或更多种表面活性剂的蛋白水解剂。 脱蛋白天然橡胶胶乳是其中橡胶分子通过表面活性剂分散和稳定的胶乳，并且还通过阳极凝固方法具有良好的成膜性能，并且即使当 在形成橡胶膜时，将模具重复地浸渍在胶乳中。

公开(公告)号：US06239253B1

公开(公告)日：2001-05-29

申请号：US09356523

申请日：1999-07-19

申请人： Yasuyuki Tanaka ,  Yuichi Hioki ,  Naoya Ichikawa

发明人： Yasuyuki Tanaka ,  Yuichi Hioki ,  Naoya Ichikawa

IPC分类号： C08C104

CPC分类号： C08C1/04 ,  Y10S528/932

摘要： A deproteinized natural rubber substantially free from any protein and a process for producing the same which comprises treating a latex with a protease and a specific surfactant or a combination of specific surfactants and separating rubber particles are disclosed. A method for elevating the green strength of a natural rubber and a method for lowering the green strength of a natural rubber are also disclosed. Furthermore, a means for preventing allergy induced by natural rubber is also disclosed.

摘要翻译： 公开了一种基本上不含任何蛋白质的脱蛋白天然橡胶及其制备方法，其包括用蛋白酶和特定表面活性剂或特定表面活性剂和分离橡胶颗粒的组合处理胶乳。 还公开了提高天然橡胶的生坯强度的方法和降低天然橡胶的生坯强度的方法。 此外，还公开了一种防止由天然橡胶引起的变态反应的方法。

公开(公告)号：US5610212A

公开(公告)日：1997-03-11

申请号：US241989

申请日：1994-05-13

申请人： Yasuyuki Tanaka ,  Yuichi Hioki ,  Masaharu Hayashi ,  Naoya Ichikawa ,  Toshiaki Sakaki

发明人： Yasuyuki Tanaka ,  Yuichi Hioki ,  Masaharu Hayashi ,  Naoya Ichikawa ,  Toshiaki Sakaki

IPC分类号： C08C1/00 ,  C08C1/04 ,  C08C1/06 ,  C08K5/41

CPC分类号： C08C1/04 ,  C08C1/06

摘要： A means for stabilizing a deproteinized natural rubber latex is disclosed, comprising adding a stabilizer selected from the group consisting of (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer. By adding the stabilizer, the mechanical stability of a deproteinized natural rubber latex can be markedly improved.

摘要翻译： 公开了一种用于稳定脱蛋白天然橡胶胶乳的方法，包括加入选自（a）阴离子表面活性剂，（b）两性表面活性剂，（c）非离子表面活性剂，（d）非离子或两性 低聚物或聚合物，和（e）阴离子低聚物或聚合物。 通过添加稳定剂，可以显着提高脱蛋白天然橡胶胶乳的机械稳定性。

公开(公告)号：US5585459A

公开(公告)日：1996-12-17

申请号：US241714

申请日：1994-05-12

申请人： Yasuyuki Tanaka ,  Yuichi Hioki ,  Masaharu Hayashi ,  Naoya Ichikawa ,  Toshiaki Sakaki

发明人： Yasuyuki Tanaka ,  Yuichi Hioki ,  Masaharu Hayashi ,  Naoya Ichikawa ,  Toshiaki Sakaki

IPC分类号： C08C1/04 ,  C08C1/14 ,  C08C1/15

CPC分类号： C08C1/15 ,  C08C1/04 ,  C08C1/14

摘要： A process for producing raw rubber from a deproteinized natural rubber is disclosed, which comprises coagulating rubber particles in the deproteinized natural rubber latex by: (1) adding a nonionic surfactant having a cloud point of from 20.degree. to 100.degree. C. and a molecular weight of 300 or more to the deproteinized natural rubber latex and heating the latex to a temperature not lower than the cloud point of the nonionic surfactant; or (2) adding a coagulation assistant selected from the group consisting of: (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer, to the deproteinized natural rubber latex; and then recovering the coagulated rubber particles. According to the process of the present invention, raw rubber containing substantially no metal ion can be produced with a high efficiency.

摘要翻译： 公开了一种从脱蛋白天然橡胶生产生橡胶的方法，其包括：通过以下步骤将脱蛋白天然橡胶胶乳中的橡胶颗粒凝结：（1）加入浊点为20至100℃的非离子表面活性剂和分子 重量为300以上的脱蛋白天然橡胶胶乳，并将胶乳加热至不低于非离子表面活性剂的浊点的温度; 或（2）加入选自以下的凝血助剂：（a）阴离子表面活性剂，（b）两性表面活性剂，（c）非离子表面活性剂，（d）非离子或两性低聚物或聚合物，和 ）阴离子低聚物或聚合物; 然后回收凝固的橡胶颗粒。 根据本发明的方法，可以高效率地生产基本上不含金属离子的生橡胶。