摘要:
A biofuel cell has a structure in which a cathode and an anode are opposed to each other with a electrolyte layer provided therebetween, at least one of the cathode and the anode including an electrode on which at least one enzyme and at least one electron mediator are immobilized. The concentration of the electron mediator immobilized on the electrode is at least 10 times a Michaelis constant Km of the electron mediator for the enzyme, which is determined by measurement in a solution.
摘要:
To provide a fuel cell and a method of using the same, which enable such a reaction environment as to exhibit excellent properties as electrode sufficiently, and to provide a cathode for the fuel cell, a device using an electrode reaction, and an electrode for the device using an electrode reaction. A fuel cell 10 includes an electrolyte solution 7 arranged between a cathode 1 and an anode 5. The cathode 1 includes a porous material made typically of carbon and an immobilized thereon. The fuel cell is so configured as to bring at least part of the cathode 1 into contact with a reactant in a gaseous phase. The cathode 1 preferably further includes an immobilized electron-transfer mediator in addition to the enzyme. The reactant in a gaseous phase can be, for example, air or oxygen.
摘要:
A fuel cell and an electronic device equipped therewith are disclosed. The fuel cell is of the type having a cathode and an anode facing each other with a proton conductor interposed therebetween, with at least either of the cathode or anode having an enzyme as a catalyst immobilized thereon, wherein at least a first cathode, a first proton conductor, an anode, a second proton conductor, and a second cathode are sequentially placed thereon, and in fuel is held in contact with at least part of the anode.
摘要:
A porous electroconductive material is provided. The electroconductive material enables efficient enzymatic metabolic reactions on electrodes and yields electrodes having immobilized enzymes thereon which remain stable in any working environment. The porous electroconductive material, which has a three-dimensional network structure, is formed from a skeleton of porous material and a carbonaceous material covering the surface of the skeleton. The porous material constituting the skeleton is foamed metal or alloy. This porous electroconductive material is made into an electrode, and enzymes are immobilized on this electrode. The resulting electrode with immobilized enzymes thereon is used as the anode of a bio-fuel cell.
摘要:
Provided is a fuel cell having a structure in which a cathode and an anode face each other with a proton conductor therebetween. In this fuel cell, an oxygen reductase or the like is immobilized on at least the cathode, and the cathode is composed of a material having pores therein such as porous carbon. In this fuel cell, the volume of water contained in the cathode is controlled to be 70% or less of the volume of the pores of the cathode, whereby a high current value can be stably obtained through optimization of the amount of moisture contained in the cathode when an enzyme is immobilized on at least the cathode. Also provided is a method for operating the fuel cell.
摘要:
Provided are an enzyme immobilizing method, a fuel cell and an electrode for the fuel cell which employ the enzyme immobilizing method, and a method for manufacturing the fuel cell and the electrode. The enzyme immobilizing method prevents reduction in enzyme activity when the enzyme is immobilized on the electrode, so as to make it possible to obtain a high catalyst current value. In the method for immobilizing an enzyme on the electrode used in the fuel cell, an enzyme variant with at least one amino acid residue being deleted, substituted, added, or inserted in a wild-type amino acid sequences is used as the enzyme, and the enzyme variant increases in activity through heat treatment. The immobilization is performed within a temperature range which makes it possible to increase the activity of the enzyme variant.
摘要:
A fuel cell and an electronic device equipped therewith are disclosed. The fuel cell is of the type having a cathode and an anode facing each other with a proton conductor interposed therebetween, with at least either of the cathode or anode having an enzyme as a catalyst immobilized thereon, wherein at least a first cathode, a first proton conductor, an anode, a second proton conductor, and a second cathode are sequentially placed thereon, and in fuel is held in contact with at least part of the anode.
摘要:
A zoom lens includes a first lens unit having a negative refractive power, a second lens unit having a positive refractive power, and a third lens unit having a positive refractive power. The first lens unit, the second lens unit, and the third lens unit are arranged in order from an object side to an image side. Distances between the lens units change during zooming. The first lens unit consists of two lenses. Radii of curvature of a lens surface closest to the object side and a lens surface closest to the image side in the first lens unit, a focal length of the first lens unit, and a focal length of the entire zoom lens at a telephoto end are set appropriately.
摘要:
A screw fastening device having a compact clutch that is directly connected to an output side of a DC motor. The output of the DC motor can be suppressed so that the DC motor and the clutch can be made compact. Accordingly, the device main body is more compact and lighter.
摘要:
A zoom lens includes a first lens unit having a positive refractive power, a second lens unit having a negative refractive power, a third lens unit having a positive refractive power, and a rear group including at least one lens unit. The first lens unit, the second lens unit, the third lens unit, and the rear group are arranged in order from an object side to an image side. The second and third lens units move for zooming. Imaging magnifications of the second lens unit at a wide angle end and a telephoto end, imaging magnifications of the third lens unit at the wide angle end and the telephoto end, a moving amount of the third lens unit along an optical axis during zooming from the wide angle end to the telephoto end, and a total lens length at the telephoto end are set based on predetermined conditions.