摘要:
A seawater electrolysis apparatus for generating hydrogen peroxide from seawater by electrolysis to thereby treat the seawater. The seawater electrolysis apparatus comprises an electrolytic cell, a gas diffusion electrode partitioning the electrolytic cell into a gas chamber and an electrolysis chamber, an insoluble metal electrode disposed in the electrolysis chamber as an anode, an inlet and an outlet for passing seawater through the electrolysis chamber, an inlet for supplying an oxygen-containing gas to the gas chamber, and means for passing and diffusing at least part of the gas supplied to the gas chamber passing through the gas diffusion electrode and into the seawater, respectively.
摘要:
The present invention relates to an electrolytic electrode comprising a core material made of a valve metal, a dense electrically conductive tin oxide layer formed on the core material, an .alpha.-lead dioxide layer formed on the tin oxide layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to a method for preparing the electrolytic electrode.
摘要:
A process for producing an electrically conductive mixed oxide comprises sintering a power mixture comprising from 30 to 98% by weight of titanium oxide, in terms of the amount of titanium based on the total amount of all the metallic elements, from 1 to 10% by weight of at least one of titanium metal and titanium hydride, in terms of the amount of titanium based on the total amount of all the metallic elements, and from 1 to 60% by weight of at least one of tantalum oxide and niobium oxide, in terms of the amount of tantalum, niobium, or tantalum and niobium based on the total amount of all of the metallic elements. The process provides a sintered solid comprising titanium, at least one of tantalum and niobium, and a stoichiometrically deficient amount of oxygen. The content of titanium in the sintered solid is from 40 to 99% by weight and the content of tantalum, niobium, or tantalum and niobium in the sintered solid is from 1 to 60% by weight, respectively, based on the total amount of all of the metallic elements in the mixed oxide.
摘要:
The underwater propulsion apparatus, which is mounted on a ship, has the anode and cathode electrodes including an anode compartment and cathode compartment whose electrode materials are separated from seawater in a central duct by the ion exchange membranes so that they are protected from poisoning by seawater. In the method utilizing the apparatus, the anode compartment and cathode compartment are supplied with moist hydrogen and moist oxygen, respectively, so as to substantially suppress the evolution of gas in the duct, which lowers the thrusting force.
摘要:
A process of producing a metallic foil by electrolysis by depositing the metallic foil on a cathode by electrolysis from a sulfuric acid acidic solution is disclosed, which comprises using an electrode having a coating of an electrode active material containing a platinum group metal oxide as an anode and carrying out the electrolysis in an electrolyte containing from 1 to 20 ppm of a lead component when a fluorine component does not exist in the electrolyte or an electrolyte containing from 0.2 to 1 ppm of a fluorine component and from 0.1 to 20 ppm of a lead component when a fluorine component exists in the electrolyte. The life of the electrode can be prolonged and a metallic foil can be stably produced by electrolysis for a long period of time by preventing the lead component(s) derived from the raw material from mixing into the metallic foil.
摘要:
The present invention relates to an electrolytic electrode comprising a core material made of a valve metal, a plasma flame-coated layer containing the oxides of titanium and tantalum formed on the surface of the core material, an interlayer containing platinum and the oxides of titanium and tantalum formed on the surface of the plasma flame-coated layer, an .alpha.-lead dioxide layer formed on the interlayer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to a process for the manufacture thereof.
摘要:
An electrolytic electrode substrate comprises an electrically conductive substrate and, formed on the surface of the electrically conductive substrate, an oxide layer having a thickness of from 10 to 200 .mu.m, wherein the oxide in the oxide layer comprises a non-stoichiometric composition containing oxygen and at least one metal selected from the group consisting of titanium, tantalum, and niobium. An advantage of the electrode substrate is that it is stable when used in electrolytic processes involving a reversal of current flow. Further, the electrode substrate is stable in the presence of corrosive substances such as a fluorine.
摘要:
An electrode structure containing an insoluble metal electrode which is used as an electrode for the electrolysis of an acidic aqueous solution under a high current density is disclosed. An elastic electroconductive material, containing an expanded metal, having formed thereon a corrosion-resistant electroconductive coating, is disposed between an electroconductive electrode substrate and an electrode having on the surface thereof a coating of an electrode material. They are fixed by a detachable fixing device from the surface of the electrode. The electrode can be exchanged when fixing the electrode structure to the electrolytic cell.
摘要:
The present invention relates to a method of producing an electrolytic electrode containing the following steps: forming a lead plating layer on the surface of a metallic core material by using a lead electrolytic plating bath, where the metallic core material is the cathode; forming an .alpha.-lead dioxide layer on the lead plating layer by electrolysis using an alkaline bath containing a lead ion and using the core material as the anode; and forming a .beta.-lead dioxide layer on the .alpha.-lead dioxide layer by electrolysis using an aqueous lead nitrate solution and using the core material as the anode. The electrolytic electrode produced by the foregoing method is capable of electrolysis in an aqueous solution, in particular, in an aqueous corrosive solution containing fluorine ions.
摘要:
The present invention relates to an electrolytic electrode comprising a metallic core material, a lead plating layer formed on the surface of the metallic core material, an .alpha.-lead dioxide layer formed on the surface of the lead plating layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to methods for the preparation thereof.