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公开(公告)号：US08697279B2
公开(公告)日：2014-04-15
申请号：US13007123
申请日：2011-01-14
申请人： Sergei Kniajanski , Andrey Ivanovich Meshkov , Grigorii Lev Soloveichik , Michael Alan Vallance
发明人： Sergei Kniajanski , Andrey Ivanovich Meshkov , Grigorii Lev Soloveichik , Michael Alan Vallance
IPC分类号： H01M10/0563 , H01M10/30 , H01M10/39 , H01M4/38
CPC分类号： H01M4/364 , H01M2/1646 , H01M2/18 , H01M4/136 , H01M4/5815 , H01M4/582 , H01M10/052
摘要： In one embodiment, a cathode composition comprises a transition metal and/or a transition metal salt, wherein the transition metal is selected from the group consisting of nickel, iron, cobalt, chromium, manganese, molybdenum, zinc, and antimony, and a combination comprising at least one of the foregoing; an alkali metal halide; an electrolyte salt comprising an alkali metal halide and a metal halide; and a sulfide compound selected from the group consisting of gallium sulfide, antimony sulfide, and a combination comprising at least one of the foregoing. An energy storage device comprising the electrode composition is also provided.
摘要翻译： 在一个实施方案中，阴极组合物包含过渡金属和/或过渡金属盐，其中过渡金属选自镍，铁，钴，铬，锰，钼，锌和锑，以及组合 包括前述的至少一个; 碱金属卤化物; 包含碱金属卤化物和金属卤化物的电解质盐; 和选自由硫化镓，硫化锑组成的组的硫化物，以及包含上述的至少一种的组合。 还提供了包括电极组合物的能量存储装置。
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公开(公告)号：US08329336B2
公开(公告)日：2012-12-11
申请号：US12893661
申请日：2010-09-29
CPC分类号： H01M10/26 , H01M2300/0054 , H01M2300/0057 , Y10T29/49108 , Y10T29/49115
摘要： A cathode composition is provided. The cathode composition includes at least one electroactive metal, wherein the electroactive metal is at least one selected from the group consisting of titanium, vanadium, niobium, molybdenum, nickel, iron, cobalt, chromium, manganese, silver, antimony, cadmium, tin, lead and zinc; a first alkali metal halide; an electrolyte salt comprising a reaction product of a second alkali metal halide and a metal halide, wherein the electrolyte salt has a melting point of less than about 300 degrees Centigrade; and a metal chlorosulfide compound having a formula (I) M1M2p+1SnCl4+3p−2n wherein “M1” is a metal selected from group IA of the periodic table, “M2” is a metal selected from group IIIA of the periodic table, “p” is 0 or 1, and “n” is equal to or greater than 0.5. An article and an energy storage device comprising the cathode composition is provided. A method of forming the energy storage device is provided.
摘要翻译： 提供阴极组合物。 阴极组合物包括至少一种电活性金属，其中电活性金属是选自钛，钒，铌，钼，镍，铁，钴，铬，锰，银，锑，镉，锡， 铅锌 第一碱金属卤化物; 电解质盐，其包含第二碱金属卤化物和金属卤化物的反应产物，其中所述电解质盐的熔点小于约300摄氏度; 和具有式（I）的金属氯化硫化物M1M2p + 1SnCl4 + 3p-2n其中M1是选自元素周期表的IA族的金属，M2是选自元素周期表IIIA族的金属，p是0或1 ，n等于或大于0.5。 提供了一种包含阴极组合物的制品和储能装置。 提供一种形成能量存储装置的方法。
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公开(公告)号：US08030509B2
公开(公告)日：2011-10-04
申请号：US12512105
申请日：2009-07-30
申请人： Robert James Perry , Larry Neil Lewis , Michael Joseph O'Brien , Grigorii Lev Soloveichik , Sergei Kniajanski , Tunchiao Hubert Lam , Julia Lam Lee , Malgorzata Iwona Rubinsztajn
发明人： Robert James Perry , Larry Neil Lewis , Michael Joseph O'Brien , Grigorii Lev Soloveichik , Sergei Kniajanski , Tunchiao Hubert Lam , Julia Lam Lee , Malgorzata Iwona Rubinsztajn
IPC分类号： C07F7/10 , C07D303/02 , B01D53/14 , B01D53/34 , B01D53/62
CPC分类号： B01D53/1475 , B01D53/1493 , F23J2215/50 , Y02C10/04 , Y02C10/06 , Y02C10/08
摘要： In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.
摘要翻译： 根据一个方面，本发明提供了包含结构I，II，III，IV或V中的至少一种的氨基硅氧烷组合物，所述组合物可用于从诸如发电厂烟道气体的气流捕获二氧化碳。 此外，本发明提供了制备氨基硅氧烷组合物的方法。 还提供了减少使用本发明的氨基 - 硅氧烷组合物的工艺流中二氧化碳的量作为与二氧化碳反应以与二氧化碳形成加合物的物质的方法。 本发明提供的氨基硅氧烷组合物与二氧化碳的反应是可逆的，因此该方法提供所述组合物的多周期使用。
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公开(公告)号：US20100055513A1
公开(公告)日：2010-03-04
申请号：US12617986
申请日：2009-11-13
CPC分类号： H01M4/90 , H01M4/8825 , H01M4/9008 , H01M4/92 , H01M4/921 , H01M4/925 , H01M4/926 , H01M8/04186 , H01M8/04201 , H01M8/06 , H01M8/186 , H01M8/22 , H01M16/003 , H01M2008/1095 , Y02E60/528
摘要： An electrochemical energy conversion and storage system comprises an electrochemical energy conversion device, in fluid communication with a source of an organic liquid carrier of hydrogen and an oxidant, for receiving, catalyzing and electrochemically oxidizing at least a portion of the hydrogen to generate electricity, a hydrogen depleted liquid, and water; and a vessel for receiving the hydrogen depleted liquid; wherein the organic liquid carrier of hydrogen comprises at least two secondary hydroxy groups is provided.
摘要翻译： 一种电化学能量转换和储存系统包括与氢和氧化剂的有机液体载体的源流体连通的电化学能量转换装置，用于接收，催化和电化学氧化至少一部分氢以发电; 耗尽氢的液体和水; 和用于接收耗尽氢的液体的容器; 其中提供氢的有机液体载体包含至少两个仲羟基。
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公开(公告)号：US20090242459A1
公开(公告)日：2009-10-01
申请号：US12055889
申请日：2008-03-26
IPC分类号： C10G45/04
CPC分类号： C10G27/12 , C10G21/00 , C10G21/003
摘要： A method for purifying a sulfur-containing fuel oil comprising (a) contacting in a first reaction mixture the sulfur-containing fuel oil with an exogenous binary catalyst, hydrogen peroxide, and a water-soluble acid at a temperature in a range of from about 25° C. to about 150° C. to provide a first oxidized mixture; and (b) separating at least one oxidized sulfur compound from the first oxidized mixture to provide a purified fuel oil. The first reaction mixture may further comprise a phase transfer catalyst. Furthermore, the sulfur-containing fuel oil may be deasphalted prior to contacting with the catalyst, hydrogen peroxide, and the water-soluble acid.
摘要翻译： 一种净化含硫燃料油的方法，包括（a）在第一反应混合物中使含硫燃料油与外源二元催化剂，过氧化氢和水溶性酸在约 25℃至约150℃，以提供第一氧化混合物; 和（b）从第一氧化混合物中分离出至少一种氧化的硫化合物以提供纯化的燃料油。 第一反应混合物可以进一步包含相转移催化剂。 此外，含硫燃料油在与催化剂，过氧化氢和水溶性酸接触之前可以脱沥青。
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公开(公告)号：US07559978B2
公开(公告)日：2009-07-14
申请号：US11229984
申请日：2005-09-19
IPC分类号： B01D19/00
CPC分类号： C25B9/10
摘要： A system for gas-liquid separation in electrolysis processes is provided. The system includes a first compartment having a liquid carrier including a first gas therein and a second compartment having the liquid carrier including a second gas therein. The system also includes a gas-liquid separator fluidically coupled to the first and second compartments for separating the liquid carrier from the first and second gases.
摘要翻译： 提供了一种在电解过程中进行气液分离的系统。 该系统包括具有包括第一气体的液体载体的第一隔室和具有其中包含第二气体的液体载体的第二隔室。 该系统还包括流体耦合到第一和第二隔室的气液分离器，用于将液体载体与第一和第二气体分离。
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公开(公告)号：US20080308465A1
公开(公告)日：2008-12-18
申请号：US11761674
申请日：2007-06-12
摘要： A method for removing metals from fuel containing vanadium or nickel including intimately mixing an adsorbent with the fuel and isolating the treated fuel. The treated fuel has reduced levels of vanadium, nickel and other metals. Systems for fuel treatment are also provided.
摘要翻译： 一种从含有钒或镍的燃料中除去金属的方法，包括使吸附剂与燃料紧密地混合并分离处理过的燃料。 经处理的燃料具有降低的钒，镍和其他金属的含量。 还提供燃料处理系统。
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48.发明申请Method of forming a porous nickel coating, and related articles and compositions 审中-公开形成多孔镍涂层的方法以及相关的制品和组合物公开(公告)号：US20070278108A1
公开(公告)日：2007-12-06
申请号：US11444918
申请日：2006-06-01
CPC分类号： C25B11/035 , C25B1/02 , C25F3/14 , H01M4/8885 , H01M4/98 , H01M8/1011 , H01M2008/1095 , Y02E60/523
摘要： A method of forming a porous nickel coating is provided. The method includes the steps of: depositing a coating onto a substrate by melting and atomizing two consumable electrode wires of a selected composition in a wire-arc spray device, so as to form a molten, atomized material, and directing the material to the substrate to form a coating deposit; the selected composition including nickel and a sacrificial metal; and then dissolving at least a portion of the sacrificial metal from the coating deposit by applying a positive potential in an alkaline electrolyte, so as to obtain a porous nickel coating. An electrolytic cell that includes a porous nickel coating is also described.
摘要翻译： 提供一种形成多孔镍涂层的方法。 该方法包括以下步骤：通过在线弧喷涂装置中熔化和雾化所选组成的两条可消耗电极线，将涂层沉积到基底上，以形成熔融的雾化材料，并将材料引导到基底 形成涂层沉积物; 所选择的组合物包括镍和牺牲金属; 然后通过在碱性电解质中施加正电势将来自涂层沉积物的至少一部分牺牲金属溶解，以获得多孔镍涂层。 还描述了包括多孔镍涂层的电解槽。
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公开(公告)号：US06706908B2
公开(公告)日：2004-03-16
申请号：US10135724
申请日：2002-04-30
申请人： Kirill Vladimirovich Shalyaev , Grigorii Lev Soloveichik , Donald Wayne Whisenhunt, Jr. , Bruce Fletcher Johnson
发明人： Kirill Vladimirovich Shalyaev , Grigorii Lev Soloveichik , Donald Wayne Whisenhunt, Jr. , Bruce Fletcher Johnson
IPC分类号： C07C6996
CPC分类号： B01J31/2226 , B01J21/063 , B01J23/44 , B01J23/72 , B01J31/0239 , B01J31/2234 , B01J2231/321 , B01J2531/16 , B01J2531/46 , B01J2531/824
摘要： The present invention provides a method and catalyst composition for carbonylating aromatic hydroxy compounds, comprising the step of contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst composition comprising an effective amount of at least one Group 8, 9, or 10 metal source, an effective amount of a combination of inorganic co-catalysts comprising at least one Group 4 metal source and at least one Group 11 metal source, an effective amount of at least one salt co-catalyst with an anion selected from the group consisting of carboxylate, benzoate, acetate, sulfate, and nitrate, wherein the carbonylation catalyst composition is free of a halide source.
摘要翻译： 本发明提供了用于羰基化芳族羟基化合物的方法和催化剂组合物，其包括在羰基化催化剂组合物存在下使至少一种芳族羟基化合物与氧和一氧化碳接触的步骤，所述羰基化催化剂组合物包含有效量的至少一种第8族， 9或10个金属源，有效量的包含至少一种第4族金属源和至少一种第11族金属源的无机助催化剂的组合，有效量的至少一种选择了阴离子的盐助催化剂 由羧酸盐，苯甲酸盐，乙酸盐，硫酸盐和硝酸盐组成的组，其中羰基化催化剂组合物不含卤化物源。
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公开(公告)号：US06465675B1
公开(公告)日：2002-10-15
申请号：US09677487
申请日：2000-10-02
申请人： Grigorii Lev Soloveichik , Kirill Vladimirovich Shalyaev , Marsha Mottel Grade , Bruce Fletcher Johnson
发明人： Grigorii Lev Soloveichik , Kirill Vladimirovich Shalyaev , Marsha Mottel Grade , Bruce Fletcher Johnson
IPC分类号： C07C6996
CPC分类号： B01J23/8926 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes an effective amount of a Group VIII B metal source; an effective amount of a bromide composition; an effective amount of an activating organic solvent; an effective amount of a combination of inorganic co-catalysts comprising a lead source and a copper source; and an effective amount of a base.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在包含有效量的VIIIB族金属源的羰基化催化剂体系的存在下使至少一种芳族羟基化合物与氧和一氧化碳接触来羰基化芳族羟基化合物的方法; 有效量的溴化物组成; 有效量的活化有机溶剂; 有效量的包含铅源和铜源的无机助催化剂的组合; 和有效量的碱。
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