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    Polyelectrolyte complexes
    41.
    发明授权
    Polyelectrolyte complexes 有权

    公开(公告)号：US09796872B2

    公开(公告)日：2017-10-24

    申请号：US15005366

    申请日：2016-01-25

    Applicant: THE CLOROX COMPANY

    Inventor： David R. Scheuing ,  David J. Lestage ,  Carl W. Bennett ,  Mona M. Knock ,  Charles W. Scales ,  William L. Smith ,  Rui Zhang

    IPC: C11D1/62 ,  C09D133/02 ,  C09D5/14 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  A01N59/16 ,  C11D3/37 ,  C11D3/395

    CPC classification number: C09D133/02 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  A01N59/16 ,  C09D5/14 ,  C11D1/62 ,  C11D3/3769 ,  C11D3/3953

    Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.

    Treatment compositions containing water-soluble polyelectrolyte complex which are self-limiting
    43.
    发明授权
    Treatment compositions containing water-soluble polyelectrolyte complex which are self-limiting 有权
    含有自限性水溶性聚电解质络合物的处理组合物

    公开(公告)号：US09593299B2

    公开(公告)日：2017-03-14

    申请号：US15269085

    申请日：2016-09-19

    Applicant: THE CLOROX COMPANY

    Inventor： David R. Scheuing ,  William L. Smith ,  Michael Kinsinger ,  Jared Heymann

    IPC: C07B57/00 ,  A01N33/12 ,  C11D17/04 ,  A01N59/00 ,  A01N59/16 ,  B08B1/00 ,  C11D3/37 ,  C11D3/48 ,  A61L15/10 ,  A61L15/46

    CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

    Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

    Abstract translation: 本发明涉及可选地含有表面活性剂，杀生物剂和/或氧化剂的缔合聚电解质复合物（PEC）的含水组合物，其可以为处理物品提供清洁效果和表面保护，包括减少污染趋势，降低清洁力和改善防污性 ，以及为处理的表面提供抑菌性能，从而获得对水的耐受性，环境暴露和微生物挑战。 提供了处理装置和组合物，其使用通过在适合的混合条件下将水溶性阳离子第一聚电解质与带有相反电荷的水溶性第二聚电解质带入基团的第一聚电解质组合形成的缔合聚电解质复合物和至少一种选自以下的氧化剂：碱 次氯酸，次氯酸，溶解氯，任何游离氯源，酸性亚氯酸钠，活性氯产生化合物的金属盐和/或碱土金属盐及其任何组合或混合物。 还提供了在水溶液中形成具有约0.10至20的R值的至少一种氧化剂的稳定的缔合聚电解质络合物的方法。

    Hypohalite compositions comprising a diallyl dimethyl ammonium chloride polymer
    45.
    发明授权
    Hypohalite compositions comprising a diallyl dimethyl ammonium chloride polymer 有权
    包含二烯丙基二甲基氯化铵聚合物的次卤酸盐组合物

    公开(公告)号：US09045719B1

    公开(公告)日：2015-06-02

    申请号：US14571122

    申请日：2014-12-15

    Applicant: The Clorox Company

    Inventor： Sukhvinder Kaur ,  Terutaka T. Kitagawa ,  David R. Scheuing

    IPC: C11D3/24 ,  C11D3/395 ,  C11D3/48 ,  C11D7/28 ,  C11D9/28 ,  C11D1/62

    CPC classification number: C11D3/3953 ,  C11D1/62 ,  C11D3/3773 ,  C11D3/3956

    Abstract: The invention relates to compositions and methods of treatment employing compositions including a cationic polyelectrolyte, without any anionic polyelectrolytes, so that no polyelectrolyte complex (PEC) is formed. In addition to not forming PECs, and being free of anionic water-soluble polymers (i.e., an anionic polyelectrolyte polymer that could form a PEC with the cationic polyelectrolyte), the composition is also free of random copolymers, block copolymers, coacervates, precipitates, and silicone copolymers. The composition may be a concentrate, to be diluted prior to use to treat a surface.

    Abstract translation: 本发明涉及使用不含任何阴离子聚电解质的包含阳离子聚电解质的组合物的组合物和方法，使得不形成聚电解质络合物（PEC）。 除了不形成PEC，并且不含阴离子水溶性聚合物（即，可以与阳离子聚电解质形成PEC的阴离子聚电解质聚合物）之外，组合物也不含无规共聚物，嵌段共聚物，凝聚层，沉淀物， 和硅氧烷共聚物。 组合物可以是在使用前稀释以处理表面的浓缩物。

    ANIONIC MICELLES WITH CATIONIC POLYMERIC COUNTERIONS SYSTEMS THEREOF
    48.
    发明申请
    ANIONIC MICELLES WITH CATIONIC POLYMERIC COUNTERIONS SYSTEMS THEREOF 审中-公开
    具有阳离子聚合物反应体系的阴离子胶

    公开(公告)号：US20150038392A1

    公开(公告)日：2015-02-05

    申请号：US14517484

    申请日：2014-10-17

    Applicant: The Clorox Company

    Inventor： David R. Scheuing ,  Travers Anderson ,  William L. Smith ,  Erika Szekeres ,  Rui Zhang

    IPC: C11D1/00 ,  C11D3/395

    CPC classification number: C11D1/008 ,  B65D81/32 ,  C11D1/02 ,  C11D3/3765 ,  C11D3/3953 ,  C11D3/3956 ,  C11D17/041

    Abstract: The invention relates to a polymer-micelle complex. The polymer-micelle complexes include a negatively charged micelle that is electrostatically bound to a water-soluble polymer bearing a positive charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.

    Abstract translation: 本发明涉及聚合物 - 胶束复合物。 聚合物 - 胶束复合物包括与带有正电荷的水溶性聚合物静电结合的带负电荷的胶束。 聚合物不包含嵌段共聚物，胶乳颗粒，聚合物纳米颗粒，交联聚合物，硅氧烷共聚物，含氟表面活性剂或两性共聚物。 组合物不形成凝聚层，并且当施加到表面时不形成膜。

    CATIONIC MICELLES WITH ANIONIC POLYMERIC COUNTERIONS METHODS THEREOF
    50.
    发明申请
    CATIONIC MICELLES WITH ANIONIC POLYMERIC COUNTERIONS METHODS THEREOF 审中-公开
    具有阴离子聚合反应的阳离子聚合物的方法

    公开(公告)号：US20140121281A1

    公开(公告)日：2014-05-01

    申请号：US13663830

    申请日：2012-10-30

    Applicant: THE CLOROX COMPANY

    Inventor： David R. Scheuing ,  Travers Anderson ,  Thomas F. Fahlen ,  William L. Smith ,  Erika Szekeres ,  Rui Zhang

    IPC: A01N25/30

    CPC classification number: A01N25/30 ,  A01N33/12 ,  A01N47/44 ,  A01N25/00 ,  A01N25/04 ,  A01N25/10

    Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.

    Abstract translation: 本发明涉及聚合物 - 胶束复合物。 聚合物 - 胶束复合物包括选自单体季铵化合物，单体双胍化合物及其混合物的带正电荷的胶束。 带正电的胶束静电结合到带有负电荷的水溶性聚合物上。 聚合物不包含嵌段共聚物，胶乳颗粒，聚合物纳米颗粒，交联聚合物，硅氧烷共聚物，含氟表面活性剂或两性共聚物。 组合物不形成凝聚层，并且当施加到表面时不形成膜。

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