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公开(公告)号:US20230292589A1
公开(公告)日:2023-09-14
申请号:US18319759
申请日:2023-05-18
发明人: Jui-Yi TSAI , Eric A. Margulies , Zhiqiang Ji , Alexey Borisovich Dyatkin , Walter Yeager , Mingjuan Su
CPC分类号: H10K85/342 , C07F15/0033 , C09K11/06 , H10K85/40 , H10K85/615 , H10K85/622 , H10K85/626 , H10K85/654 , H10K85/657 , H10K85/6572 , H10K85/6576 , C09K2211/1037 , C09K2211/185 , C09K2211/1033 , H10K50/11
摘要: A compound having a metal coordination complex structure, where the compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature is disclosed. The compound has a first ligand coordinated to a metal. The free-state of the first ligand has a first triplet energy T1 of EL at 77K, while the compound has a first triplet energy T1 of E at 77K, and the difference in energy (ΔE) between E and EL is ≤250 meV. The compound has a triplet emission spectrum with a FWHM value of no more than 45 nm. Organic light emitting devices, consumer products, and formulations containing the compounds are also disclosed.
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公开(公告)号:US11746122B2
公开(公告)日:2023-09-05
申请号:US17573237
申请日:2022-01-11
发明人: Jui-Yi Tsai , Alexey Borisovich Dyatkin , Zhiqiang Ji , Walter Yeager , Pierre-Luc T. Boudreault
CPC分类号: C07F15/0033 , H10K85/342
摘要: A compound including a first ligand LX of Formula II
is disclosed, where F is a 5-membered or 6-membered carbocyclic or heterocyclic ring; each RF and RG independently represents mono to the maximum possible number of substitutions, or no substitution; Z3 and Z4 are each independently C or N and coordinated to a metal M to form a 5-membered chelate ring; G is a fused ring structure comprising five or more fused heterocyclic or carbocyclic rings, of which one or two rings are of Formula III
the fused heterocyclic or carbocyclic rings in the fused ring structure G are 5-membered or 6-membered; of which if two or more 5-membered rings are present, at least two of the 5-membered rings are fused to one another; Y can be one of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO2, CR′R″, SiR′R″, and GeR′R″; the metal M can be coordinated to other ligands; and the ligand LX can be linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand.-
公开(公告)号:US11739081B2
公开(公告)日:2023-08-29
申请号:US16800520
申请日:2020-02-25
IPC分类号: H10K85/40 , C07D409/14 , C07D405/14 , C07D403/04 , C07D333/76 , C07F7/08 , C07D251/24 , C07C15/38 , C07C15/30 , C07D403/14 , H10K85/60
CPC分类号: C07D409/14 , C07C15/30 , C07C15/38 , C07D251/24 , C07D333/76 , C07D403/04 , C07D403/14 , C07D405/14 , C07F7/0812 , H10K85/40 , H10K85/622 , H10K85/654 , H10K85/6572 , H10K85/6574 , H10K85/6576
摘要: Transition metal compounds having naphthalene imide moiety having enhanced electron withdrawing property and more metal-ligand charge transfer (MLCT) based excited state are disclosed. The disclosed compounds will improve the photoluminescent quantum yield (PLQY) and produce phosphorescent emission in red to near IR region which has many desired applications.
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公开(公告)号:US11718634B2
公开(公告)日:2023-08-08
申请号:US16550376
申请日:2019-08-26
IPC分类号: C07F15/00 , H10K85/30 , H10K50/11 , H10K50/12 , H10K101/10 , H10K85/40 , H10K85/60 , H10K50/81 , H10K50/82
CPC分类号: C07F15/0033 , H10K50/11 , H10K85/342 , H10K85/40 , H10K85/622 , H10K85/654 , H10K85/655 , H10K85/6572 , H10K85/6576 , H10K50/12 , H10K50/81 , H10K50/82 , H10K2101/10
摘要: Cyclometallated iridium complexes having triphenylene or aza triphenylene and bulky alkyl substitution that can be used as emitters in OLEDs to improve the external quantum efficiency (EQE) and lifetime of OLEDs are disclosed.
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公开(公告)号:US11711969B2
公开(公告)日:2023-07-25
申请号:US17343138
申请日:2021-06-09
IPC分类号: H01L51/00 , H10K85/30 , C07F15/00 , C09K11/06 , H10K50/11 , H10K50/15 , H10K50/16 , H10K50/17 , H10K50/18 , H10K101/10 , H10K101/30 , H10K101/40
CPC分类号: H10K85/342 , C07F15/0033 , C09K11/06 , C09K2211/1011 , C09K2211/1037 , C09K2211/185 , H10K50/11 , H10K50/15 , H10K50/16 , H10K50/17 , H10K50/171 , H10K50/18 , H10K2101/10 , H10K2101/30 , H10K2101/40
摘要: A novel compound is disclosed which includes a ligand LA of Formula II,
wherein:
ring B is independently a 5-membered or 6-membered carbocyclic or heterocyclic ring;
X1 to X4 are each independently selected from the group consisting of C, N, and CR;
at least one pair of adjacent X1 to X4 are each C and fused to Formula V
where indicated by “”; X5 to X12 are each independently C or N; the maximum number of N within a ring is two; Z and Y are each independently selected from the group consisting of O, S, Se, NR′, CR′R″, SiR′R″, and GeR′R″; RB and RC each independently represents zero, mono, or up to a maximum allowed substitutions to its associated ring; each of RB, RC, R, R′, and R″ is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; and two substituents can be joined or fused to form a ring; the ligand LA is complexed to a metal M through the two indicated dash lines of each Formula; and the ligand LA can be joined with other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand.-
公开(公告)号:US11672175B2
公开(公告)日:2023-06-06
申请号:US16867696
申请日:2020-05-06
IPC分类号: H01L51/50 , H01L51/00 , C09K11/06 , C09K11/02 , C07D487/04 , C07D405/14
CPC分类号: H01L51/0072 , C07D405/14 , C07D487/04 , C09K11/025 , C09K11/06 , H01L51/0052 , H01L51/0067 , H01L51/0073 , H01L51/0074 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H01L51/5072 , H01L2251/5384
摘要: Indolocarbazole materials with substitution attached at specific positions and methods to synthesize the same are disclosed. The materials are used as hosts for improving performance of organic electroluminescence devices.
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公开(公告)号:US11647667B2
公开(公告)日:2023-05-09
申请号:US16880333
申请日:2020-05-21
发明人: Jui-Yi Tsai , Alexey Borisovich Dyatkin , Zhiqiang Ji , Pierre-Luc T. Boudreault , Peter Wolohan , Sean Michael Ryno , Hsiao-Fan Chen , Tyler Fleetham , Noah Horwitz
CPC分类号: H01L51/0085 , C07F15/0033 , C09K11/06 , C07B2200/05 , C09K2211/1033 , C09K2211/185 , H01L51/5012 , H01L51/5016
摘要: Provided are organometallic compounds. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.
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公开(公告)号:US11639363B2
公开(公告)日:2023-05-02
申请号:US16847922
申请日:2020-04-14
摘要: Provided are compounds having a first ligand LA of Formula I where, R and RA each represents mono to the maximum allowable substitutions, or no substitution; Z1 to Z4 are each independently C or N; at least two adjacent Z1 to Z4 are C and the corresponding R groups attached to them form a structure of Formula II
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公开(公告)号:US20230023959A1
公开(公告)日:2023-01-26
申请号:US17894659
申请日:2022-08-24
发明人: LICHANG ZENG , Chuanjun Xia , Zhiqiang Ji , Chun Lin
摘要: Metal complexes with ligands bearing a five member aromatic moiety fused with dibenzofuran or its analogues useful as electroluminescence materials in OLEDs are disclosed.
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公开(公告)号:US20220402954A1
公开(公告)日:2022-12-22
申请号:US17380518
申请日:2021-07-20
发明人: Wei-Chun SHIH , Zhiqiang Ji , Pierre-Luc T. Boudreault , Walter YEAGER , Bert ALLEYNE , Derek WOZNIAK , James FIORDELISO
摘要: A compound including a first ligand LA of Formula I, is disclosed. In Formula I, ring B is a 5- or 6-membered ring; X1, X2, and X3 are each CRA or N; R is a 5- or 6-membered carbocyclic or heterocyclic ring, which can be further fused or substituted; and (1) when ring B is an unfused 6-membered ring, X1 and X2 are N, and X3 is C; and (2) when ring B is a fused 6-membered ring, ring B has the structure of Formula II, In this structure, the wavy line indicates the point of connection to ring A; Q1 to Q6 are each C or N; and, when proviso (2) applies, (I) at least one of X1, X2, and X3 is N; or (II) R is two or more fused or unfused 5- or 6-membered carbocyclic or heterocyclic rings, or (III) at least ring A or R is substituted with a partially or fully deuterated alkyl or partially or fully deuterated cycloalkyl group.
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