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公开(公告)号：US20240349591A1
公开(公告)日：2024-10-17
申请号：US18666935
申请日：2024-05-17
发明人： Wei-Chun SHIH , Alexey Borisovich DYATKIN , Harvey WENDT , Walter YEAGER , Marcus COLE , Tyler FLEETHAM , Pierre-Luc T. BOUDREAULT , Zhiqiang JI
CPC分类号： H10K85/342 , C07F15/0033 , C09K11/06 , H10K85/40 , C09K2211/1048 , C09K2211/185 , H10K50/12
摘要： A compound having a formula of Ir(LA)n(LB)m(LC)o, wherein first ligand LA comprises a structure of Formula I,
LB comprises a structure of Formula IIA,
or Formula IIB,
and LC is a bidentate ligand. In these structures, n is 1 or 2, m is 1 or 2, o is 0 or 1, and m+n+o=3; each of moiety A, moiety D, and moiety F is a monocyclic ring or polycyclic fused ring system; moiety B is a polycyclic fused ring system; each of Z1 to Z6 and X1 to X7 is C or N; Y1 is O, S, Se, Te, P, Si, and Ge; and each RA, RB, RC, RD, RE, and RF is hydrogen or a General Substituent. Formulations, OLEDs, and consumer products containing the compound are also provided.-
公开(公告)号：US20240298534A1
公开(公告)日：2024-09-05
申请号：US18618426
申请日：2024-03-27
发明人： Lichang ZENG , Suman LAYEK , Pennington T. BOUDREAULT , Zeinab ELSHENAWY , Gregg KOTTAS , Alexey Borisovich DYATKIN , Scott JOSEPH , Vadim ADAMOVICH , Chuanjun XIA , Ting-Chih WANG , Walter YEAGER
IPC分类号： H10K85/60 , C07D251/24 , C07D405/10 , C07D409/04 , C07D409/10 , C07D421/10 , C09K11/02 , C09K11/06 , H10K50/11 , H10K50/16 , H10K85/30 , H10K101/10
CPC分类号： H10K85/654 , C07D251/24 , C07D405/10 , C07D409/04 , C07D409/10 , C07D421/10 , C09K11/025 , C09K11/06 , H10K85/342 , H10K85/626 , H10K85/6574 , H10K85/6576 , C09K2211/1007 , C09K2211/1059 , C09K2211/1092 , C09K2211/1096 , C09K2211/185 , H10K50/11 , H10K50/16 , H10K2101/10
摘要： A composition of materials including a first compound having a structure according to Formula I
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公开(公告)号：US20240107874A1
公开(公告)日：2024-03-28
申请号：US18497730
申请日：2023-10-30
发明人： Eric A. MARGULIES , Zhiqiang JI , Jui-Yi TSAI , Chun LIN , Alexey Borisovich DYATKIN , Mingjuan SU , Bin MA , Michael S. WEAVER , Julia J. BROWN , Lichang ZENG , Walter YEAGER , Alan DEANGELIS , Chuanjun XIA
CPC分类号： H10K85/342 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1022 , C09K2211/1029 , C09K2211/1033 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H10K50/11
摘要： A compound is disclosed that has a metal coordination complex structure having at least two ligands coordinated to the metal; wherein the compound has a first substituent R1 at one of the ligands' periphery; wherein a first distance is defined as the distance between the metal and one of the atoms in R1 where that atom is the farthest away from the metal among the atoms in R1; wherein the first distance is also longer than any other atom-to-metal distance between the metal and any other atoms in the compound; and wherein when a sphere having a radius r is defined whose center is at the metal and the radius r is the smallest radius that will allow the sphere to enclose all atoms in the compound that are not part of R1, the first distance is longer than the radius r by at least 2.9 Å.
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公开(公告)号：US20230354690A1
公开(公告)日：2023-11-02
申请号：US18153542
申请日：2023-01-12
发明人： Chuanjun XIA , Chun LIN , Pierre-Luc T. BOUDREAULT , Jui-Yi TSAI , Mingjuan SU , Lichang ZENG , Zhiqiang JI , Edward BARRON , Walter YEAGER , Alexey Borisovich DYATKIN
CPC分类号： H10K85/342 , C07F15/0033 , C09K11/025 , C09K11/06 , H10K85/654 , H10K85/6576 , C09K2211/1029 , C09K2211/185 , H10K50/11
摘要： A composition including a first compound capable of functioning as a phosphorescent emitter in an OLED is provided. The first compound has at least one aromatic ring and at least one substituent R directly bonded to one of the at least one aromatic rings. Each substituent R has the formula of
where (a) G1 is selected from NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group; (b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group; or (c) G1 is selected from direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group; and R is directly bonded to a phenyl, pyridine, or triazine. R1, R2, and R3 are are a variety of substituents. Formulations and devices, such as an OLEDs, that include the first compound are also described.-
公开(公告)号：US20230331757A1
公开(公告)日：2023-10-19
申请号：US18297759
申请日：2023-04-10
发明人： Wei-Chun SHIH , Alexey Borisovich DYATKIN , Jui-Yi TSAI , Pierre-Luc T. BOUDREAULT , Walter YEAGER , Suman LAYEK , Jerald FELDMAN
CPC分类号： C07F15/0033 , H10K85/342 , H10K50/82 , H10K50/81
摘要： A compound comprising a first ligand LA of Formula I,
is provided. In Formula I, each of X1 to X12 is C or N; Y is a linking group; each RA, RB and RC can be hydrogen or a substituent; at least one RA, RB or RC comprises an electron-withdrawing group; and LA forms a 5-membered chelate ring with an Ir atom via the dashed lines. In addition a number of conditions must be met based on whether or not any pair of RA is joined to form a ring. Formulations, OLEDs, and consumer products containing the compound are also provided.-
公开(公告)号：US20230147066A1
公开(公告)日：2023-05-11
申请号：US17959321
申请日：2022-10-04
发明人： Alexey Borisovich DYATKIN , Jui-Yi TSAI , Pierre-Luc T. BOUDREAULT , Walter YEAGER , Hsiao-Fan CHEN
CPC分类号： C07F15/0033 , H01L51/0085 , C07B2200/05
摘要： A compound having a formula of M(LA)p(LB)q(LC)r, where LA has a structure of Formula I,
LB is a bidentate ligand; and LC has a structure of Formula II,
is provided. In Formula I and Formula II, the compound can be homoleptic or heteroleptic and can include up to three different ligands; K3 and K4 are each independently a direct bond, O, or S; each of moiety A and moiety B represents a monocyclic ring or a polycyclic, fused-ring structure; each of Z1 and Z2 is C or N; and at least one of RA, RB, RC1, RC2, or RC3 comprises a structure of Formula III,
In Formula III, L is bivalent organic linker, and Z is Si or Ge. Each RA, RB, RC1, RC2, and RC3 is independently hydrogen or a General Substituent, and each of R1, R2, and R3 is a General Substituent. Formulations, OLEDs, and consumer products including such compounds are also provided.-
公开(公告)号：US20230130017A1
公开(公告)日：2023-04-27
申请号：US17959323
申请日：2022-10-04
发明人： Alexey Borisovich DYATKIN , Zhiqiang JI , Jui-Yi TSAI , Elena SHEINA , Wei-Chun SHIH , Pierre-Luc T. BOUDREAULT , Jerald FELDMAN , Walter YEAGER
摘要： A compound comprising a first ligand LA of Formula I, is provided. In Formula I, moiety A is a heterocyclic fused ring system comprising a 5-membered ring fused to a 6-membered ring; moiety B is an aromatic ring or fused ring system; each RA and RB is independently a hydrogen or a General Substituent; K is a direct bond, O, or S; at least one of RA and RB comprises a substituent R comprising a silyl group or a germyl group; ligand LA is coordinated to a metal M, which has an atomic mass of at least 40; and metal M may be coordinated to other ligands Formulations, OLEDs, and consumer products containing the same are also provided.
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公开(公告)号：US20230124626A1
公开(公告)日：2023-04-20
申请号：US17698816
申请日：2022-03-18
发明人： Derek Ian WOZNIAK , Zhiqiang JI , Wei-Chun SHIH , James FIORDELISO , Walter YEAGER , Pierre-Luc T. BOUDREAULT
摘要： A compound including a first ligand LA of Formula I, is provided. In Formula I, each of moiety A and moiety B independently represents monocyclic or polycyclic rings; one of Z1 and Z2 is C and the other is N; K is a direct bond, O, or S; at least one RA or RB has a structure of Formula II, where at least two of X1 to X4 are C; L is a direct bond or an organic linker; each R, R′, R″, RA, RB, and RC is a hydrogen or a General Substituent; and LA is coordinated to a metal M. Formulations, OLEDs, and consumer products containing the compound are also provided.
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公开(公告)号：US20220399510A1
公开(公告)日：2022-12-15
申请号：US17718690
申请日：2022-04-12
摘要： A compound including a first ligand LA of Formula I, is described. In Formula I, each of X1 to X9 is independently C or N; one of Z1 and Z2 is C and the other is N; each of K1 and K2 is independently a direct bond, O, or S; at least one of K1 and K2 is a direct bond; at least one RB is not hydrogen; R3 is selected from alkyl, heteroalkyl, cycloalkyl, and heterocycloalkyl; LA is coordinated to a metal M; at least one of the following is true: (i) at least one RB comprises a 5- or 6-membered, (ii) two adjacent RB are joined to form a fused 5- or 6-membered ring, or (iii) RB comprises a carbocyclic or heterocyclic ring substituted with at least one electron withdrawing group. Devices, consumer products, and formulations including the compound are also described.
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公开(公告)号：US20220302395A1
公开(公告)日：2022-09-22
申请号：US17674001
申请日：2022-02-17
发明人： Alexey Borisovich DYATKIN , Jui-Yi TSAI , Walter YEAGER , Zhiqiang JI , Alan DEANGELIS , Pierre-Luc T. BOUDREAULT
摘要： Disclosed is a compound including a ligand LA of Formula I where each of moiety A and moiety B is independently a monocyclic or polycyclic ring structure including 5-membered and/or 6-membered carbocyclic or heterocyclic rings; where moiety B includes a structure of Formula II These compounds are useful as a component in the emissive layer of OLEDs.
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