Process for producing rechargeable electrochemical device
    42.
    发明授权
    Process for producing rechargeable electrochemical device 失效
    生产可充电电化学装置的方法

    公开(公告)号:US4658498A

    公开(公告)日:1987-04-21

    申请号:US681848

    申请日:1984-12-04

    摘要: An alloy capable of reversibly absorbing and desorbing lithium ions in a non-aqueous electrolyte containing lithium ions on charging and discharging has excellent applicability to anode for rechargeable electrochemical devices. However, such alloy, when absorbed with lithium, loses its flexibility, so that when it is incorporated in a device in a charged state, it is subject to trouble such as cracking and can not display its properties. This invention adopts a method in which anode alloy is combined with lithium by connecting them so as to be electronically conductive to each other and this combination is fitted into the device, and then the electrolyte is supplied into the device to have lithium absorbed in anode alloy in the device. According to this method, cracking of cathode can be prevented.

    摘要翻译: PCT No.PCT / JP84 / 00171 Sec。 371日期1984年12月4日第 102(e)日期1984年12月4日PCT提交1984年4月5日PCT公布。 WO94 / 04001 PCT出版物 日期:1984年10月11日。在充电和放电的含有锂离子的非水电解质中能够可逆吸收和解吸锂离子的合金对于可再充电电化学装置的阳极具有极好的适用性。 然而,当用锂吸收时,这种合金失去其柔性,使得当其以带电状态并入设备时,其遭受诸如破裂的故障,并且不能显示其性能。 本发明采用一种方法,其中将阳极合金与锂组合以使其彼此电子导电,并将该组合装配到装置中,然后将电解质供应到装置中以将锂吸收在阳极合金中 在设备中。 根据该方法,可以防止阴极开裂。

    Secondary battery with nonaqueous electrolyte and method of
manufacturing same
    45.
    发明授权
    Secondary battery with nonaqueous electrolyte and method of manufacturing same 失效
    具有非水电解质的二次电池及其制造方法

    公开(公告)号:US5316875A

    公开(公告)日:1994-05-31

    申请号:US916967

    申请日:1992-07-20

    摘要: There is provided a secondary battery comprising a positive and a negative electrode and a nonaqueous electrolyte. The positive electrode is made by dipping an electrode comprising a positive active material such as LiMn.sub.2 O.sub.4, LiMnO.sub.2, LiCoO.sub.2, LiNiO.sub.2, LiFeO.sub.2 or .gamma.LiV.sub.2 O.sub.5, in a solution containing butyllithium, phenyllithium, or naphthyllithium. The negative electrode of the battery absorbs and desorbs lithium by charging and discharging, and the nonaqueous electrolyte contains a lithium salt. Also provided is a method of manufacturing a secondary battery comprising a nonaqueous electrolyte. The method comprises the steps of preparing an electrode group containing a positive electrode of LiMn.sub.2 O.sub.4, LiMnO.sub.2, LiCoO.sub.2, LiNiO.sub.2, LiFeO.sub.2 or .gamma.-LiV.sub.2 O.sub.5, as the active material, and a negative electrode which absorbs and desorbs lithium by charging and discharging, with a separator therebetween. The group is placed in a battery case, and to the case is added a solution containing butyllithium etc. The solution is removed and an organic electrolyte as a nonaqueous electrolyte is added to the battery case.

    摘要翻译: 提供一种包含正极和负极和非水电解质的二次电池。 正极通过在包含丁基锂,苯基锂或萘基锂的溶液中浸渍包含LiMn 2 O 4,LiMnO 2,LiCoO 2,LiNiO 2,LiFeO 2或γLiV 2 O 5等正极活性物质的电极。 电池的负极通过充放电吸收和解吸锂,非水电解质含有锂盐。 还提供了一种制造包含非水电解质的二次电池的方法。 该方法包括以下步骤:制备含有LiMn 2 O 4,LiMnO 2,LiCoO 2,LiNiO 2,LiFeO 2或γ-LiV 2 O 5的正极作为活性材料的电极组,以及通过充电和放电吸收和解吸锂的负极, 分离器之间。 将该组放置在电池壳体中,并且向壳体中加入含有丁基锂等的溶液。除去溶液,并将电解质的有机电解质添加到电池壳体中。

    Method of manufacturing sealed rechargeable batteries
    46.
    发明授权
    Method of manufacturing sealed rechargeable batteries 失效
    密封充电电池的制造方法

    公开(公告)号:US5131920A

    公开(公告)日:1992-07-21

    申请号:US713286

    申请日:1991-06-11

    IPC分类号: H01M4/38 H01M10/34

    摘要: The invention relates to a new method of manufacturing a sealed rechargeable alkaline battery including metal oxides as positive electrode active materials and a hydrogen absorbing alloy as a negative electrode material. The basic principle of the method is that, instead of the conventional electrochemical formation, the property of a hydrogen absorbing alloy is utilized to cause the negative electrode to absorb hydrogen to thereby achieve precharged portions within the negative electrode having a relatively larger capacity as compared with the positive electrode. Regardless of the kind of positive electrode, the method of the invention insures a broad freedom in the capacity appropriation between the positive and negative electrodes.

    摘要翻译: 本发明涉及一种包括金属氧化物作为正极活性物质和作为负极材料的吸氢合金的密封可充电碱性电池的新方法。 该方法的基本原理是,代替常规的电化学形成,利用吸氢合金的性质使负极吸收氢,从而在具有相对较大容量的负极内实现预充电部分,与 正电极。 无论正极的种类如何,本发明的方法确保了正极和负极之间的容量容限的广泛的自由度。

    Rechargeable electrochemical apparatus and negative electrode thereof
    47.
    发明授权
    Rechargeable electrochemical apparatus and negative electrode thereof 失效
    可充电电化学装置及其负极

    公开(公告)号:US4851309A

    公开(公告)日:1989-07-25

    申请号:US935169

    申请日:1986-11-24

    摘要: A rechargeable negative electrode for an electrochemical apparatus using nonaqueous electrolytes, said electrode comprising an alloy comprising (1) at least one metal selected from the group consisting of Sn, Pn, In and Bi and (2) Zn or Zn and Cd, as well as a rechargeable electrochemical apparatus comprising a combination of said negative electrode with a positive electrode having reversibility in charging and discharging. The above-mentioned negative electrode reversibly absorbs and desorbs alkali metal ions, as the result of charge and discharge, in nonaqueous electrolyte containing alkali metal ions. It undergoes no pulverization even after repeated charge and discharge, and maintains its shape stably, so that it has a long charge-and-discharge cycle life. Further, since it can absorb a large quantity of alkali metal per unit volume, it is of high energy density.

    摘要翻译: PCT No.PCT / JP84 / 00088 Sec。 371日期1984年11月5日 102(e)日期1984年11月5日PCT提交1984年3月6日PCT公布。 出版物WO84 / 03591 日本9月13日,1984年。一种用于使用非水电解质的电化学装置的可再充电负极,所述电极包括合金,其包含(1)选自Sn,Pn,In和Bi中的至少一种金属和(2)Zn 或Zn和Cd,以及可充电电化学装置,其包括所述负极与正电极的组合,其具有充电和放电的可逆性。 在含有碱金属离子的非水电解质中,上述负极作为充放电的结果可逆地吸收和解吸碱金属离子。 即使重复进行充放电,也不会发生粉碎,并且保持其形状稳定,因此其充放电循环寿命长。 此外,由于每单位体积吸收大量碱金属,所以能量密度高。