摘要:
A non-aqueous electrolyte secondary cell comprises a negative electrode composed of at least one selected from the group consisting of lithium and lithium compounds, a non-aqueous electrolyte containing a lithium salt, and a positive electrode active material having a composition represented by the general formula, Li.sub.x M.sub.y Mn.sub.(2-y) O.sub.4, wherein M is at least one selected from the group consisting of Co, Cr, Fe and the like, 0.85.ltoreq.x
摘要:
An alloy capable of reversibly absorbing and desorbing lithium ions in a non-aqueous electrolyte containing lithium ions on charging and discharging has excellent applicability to anode for rechargeable electrochemical devices. However, such alloy, when absorbed with lithium, loses its flexibility, so that when it is incorporated in a device in a charged state, it is subject to trouble such as cracking and can not display its properties. This invention adopts a method in which anode alloy is combined with lithium by connecting them so as to be electronically conductive to each other and this combination is fitted into the device, and then the electrolyte is supplied into the device to have lithium absorbed in anode alloy in the device. According to this method, cracking of cathode can be prevented.
摘要:
The present invention provides a non-aqueous electrolyte secondary battery having an anode active material with a high capacity and excellent cycle characteristics. The active material comprises a salt of a metal or a semi-metal and a compound selected from the group consisting of oxo-acids, thiocyanic acid, cyanogen, and cyanic acid, wherein each said oxo-acid comprises an element selected from the group consisting of nitrogen, sulfur, carbon, boron, phosphorus, selenium, tellurium, tungsten, molybdenum, titanium, chromium, zirconium, niobium, tantalum, manganese, and vanadium, salts of said oxo-acids of phosphorus and boron being restricted to hydrogenphosphates and hydrogenborates.
摘要:
A process for the production of LiNi.sub.1-x Mn.sub.x O.sub.2 (0.005.ltoreq..times..ltoreq.0.45) as a positive electrode active material for a nonaqueous lithium secondary cell comprising a) mixing aqueous solutions of a lithium salt, a nickel salt and manganese nitrate, b) heating with stirring the solution to dryness and c) pre-calcining from 250.degree. C. to 400.degree. C., grinding and mixing the product and finally calcining from 600.degree. C. to 900.degree. C.
摘要:
There is provided a secondary battery comprising a positive and a negative electrode and a nonaqueous electrolyte. The positive electrode is made by dipping an electrode comprising a positive active material such as LiMn.sub.2 O.sub.4, LiMnO.sub.2, LiCoO.sub.2, LiNiO.sub.2, LiFeO.sub.2 or .gamma.LiV.sub.2 O.sub.5, in a solution containing butyllithium, phenyllithium, or naphthyllithium. The negative electrode of the battery absorbs and desorbs lithium by charging and discharging, and the nonaqueous electrolyte contains a lithium salt. Also provided is a method of manufacturing a secondary battery comprising a nonaqueous electrolyte. The method comprises the steps of preparing an electrode group containing a positive electrode of LiMn.sub.2 O.sub.4, LiMnO.sub.2, LiCoO.sub.2, LiNiO.sub.2, LiFeO.sub.2 or .gamma.-LiV.sub.2 O.sub.5, as the active material, and a negative electrode which absorbs and desorbs lithium by charging and discharging, with a separator therebetween. The group is placed in a battery case, and to the case is added a solution containing butyllithium etc. The solution is removed and an organic electrolyte as a nonaqueous electrolyte is added to the battery case.
摘要翻译:提供一种包含正极和负极和非水电解质的二次电池。 正极通过在包含丁基锂,苯基锂或萘基锂的溶液中浸渍包含LiMn 2 O 4,LiMnO 2,LiCoO 2,LiNiO 2,LiFeO 2或γLiV 2 O 5等正极活性物质的电极。 电池的负极通过充放电吸收和解吸锂,非水电解质含有锂盐。 还提供了一种制造包含非水电解质的二次电池的方法。 该方法包括以下步骤:制备含有LiMn 2 O 4,LiMnO 2,LiCoO 2,LiNiO 2,LiFeO 2或γ-LiV 2 O 5的正极作为活性材料的电极组,以及通过充电和放电吸收和解吸锂的负极, 分离器之间。 将该组放置在电池壳体中,并且向壳体中加入含有丁基锂等的溶液。除去溶液,并将电解质的有机电解质添加到电池壳体中。
摘要:
The invention relates to a new method of manufacturing a sealed rechargeable alkaline battery including metal oxides as positive electrode active materials and a hydrogen absorbing alloy as a negative electrode material. The basic principle of the method is that, instead of the conventional electrochemical formation, the property of a hydrogen absorbing alloy is utilized to cause the negative electrode to absorb hydrogen to thereby achieve precharged portions within the negative electrode having a relatively larger capacity as compared with the positive electrode. Regardless of the kind of positive electrode, the method of the invention insures a broad freedom in the capacity appropriation between the positive and negative electrodes.
摘要:
A rechargeable negative electrode for an electrochemical apparatus using nonaqueous electrolytes, said electrode comprising an alloy comprising (1) at least one metal selected from the group consisting of Sn, Pn, In and Bi and (2) Zn or Zn and Cd, as well as a rechargeable electrochemical apparatus comprising a combination of said negative electrode with a positive electrode having reversibility in charging and discharging. The above-mentioned negative electrode reversibly absorbs and desorbs alkali metal ions, as the result of charge and discharge, in nonaqueous electrolyte containing alkali metal ions. It undergoes no pulverization even after repeated charge and discharge, and maintains its shape stably, so that it has a long charge-and-discharge cycle life. Further, since it can absorb a large quantity of alkali metal per unit volume, it is of high energy density.