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公开(公告)号：US4658498A
公开(公告)日：1987-04-21
申请号：US681848
申请日：1984-12-04
CPC分类号： H01M10/05 , H01M4/40 , H01M4/66 , Y10T29/49108
摘要： An alloy capable of reversibly absorbing and desorbing lithium ions in a non-aqueous electrolyte containing lithium ions on charging and discharging has excellent applicability to anode for rechargeable electrochemical devices. However, such alloy, when absorbed with lithium, loses its flexibility, so that when it is incorporated in a device in a charged state, it is subject to trouble such as cracking and can not display its properties. This invention adopts a method in which anode alloy is combined with lithium by connecting them so as to be electronically conductive to each other and this combination is fitted into the device, and then the electrolyte is supplied into the device to have lithium absorbed in anode alloy in the device. According to this method, cracking of cathode can be prevented.
摘要翻译： PCT No.PCT / JP84 / 00171 Sec。 371日期1984年12月4日第 102（e）日期1984年12月4日PCT提交1984年4月5日PCT公布。 WO94 / 04001 PCT出版物 日期：1984年10月11日。在充电和放电的含有锂离子的非水电解质中能够可逆吸收和解吸锂离子的合金对于可再充电电化学装置的阳极具有极好的适用性。 然而，当用锂吸收时，这种合金失去其柔性，使得当其以带电状态并入设备时，其遭受诸如破裂的故障，并且不能显示其性能。 本发明采用一种方法，其中将阳极合金与锂组合以使其彼此电子导电，并将该组合装配到装置中，然后将电解质供应到装置中以将锂吸收在阳极合金中 在设备中。 根据该方法，可以防止阴极开裂。
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公开(公告)号：US4851309A
公开(公告)日：1989-07-25
申请号：US935169
申请日：1986-11-24
摘要： A rechargeable negative electrode for an electrochemical apparatus using nonaqueous electrolytes, said electrode comprising an alloy comprising (1) at least one metal selected from the group consisting of Sn, Pn, In and Bi and (2) Zn or Zn and Cd, as well as a rechargeable electrochemical apparatus comprising a combination of said negative electrode with a positive electrode having reversibility in charging and discharging. The above-mentioned negative electrode reversibly absorbs and desorbs alkali metal ions, as the result of charge and discharge, in nonaqueous electrolyte containing alkali metal ions. It undergoes no pulverization even after repeated charge and discharge, and maintains its shape stably, so that it has a long charge-and-discharge cycle life. Further, since it can absorb a large quantity of alkali metal per unit volume, it is of high energy density.
摘要翻译： PCT No.PCT / JP84 / 00088 Sec。 371日期1984年11月5日 102（e）日期1984年11月5日PCT提交1984年3月6日PCT公布。 出版物WO84 / 03591 日本9月13日，1984年。一种用于使用非水电解质的电化学装置的可再充电负极，所述电极包括合金，其包含（1）选自Sn，Pn，In和Bi中的至少一种金属和（2）Zn 或Zn和Cd，以及可充电电化学装置，其包括所述负极与正电极的组合，其具有充电和放电的可逆性。 在含有碱金属离子的非水电解质中，上述负极作为充放电的结果可逆地吸收和解吸碱金属离子。 即使重复进行充放电，也不会发生粉碎，并且保持其形状稳定，因此其充放电循环寿命长。 此外，由于每单位体积吸收大量碱金属，所以能量密度高。
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公开(公告)号：US4668594A
公开(公告)日：1987-05-26
申请号：US812889
申请日：1985-12-05
IPC分类号： H01M10/052 , H01M4/485 , H01M10/0566 , H01M4/48 , H01M10/40
CPC分类号： H01M10/052 , H01M4/485
摘要： A rechargeable electrochemical device composed of a negative electrode (4) which comprises an alkali metal as an active material, a non-aqueous electrolyte (6), and a positive electrode (1). The positive electrode (1) is composed of an oxide of chromium and vanadium represented by the general formula:Cr.sub.x V.sub.2(1-x) O.sub.5-(2+y)x(wherein 0.2.ltoreq.x.ltoreq.0.9, 0.1.ltoreq.y.ltoreq.1.0). The rechargeable electrochemical device offers a high discharge voltage, a large discharge capacity, linear discharge voltage, and the capacity to withstand over-charging.
摘要翻译： PCT No.PCT / JP85 / 00162 Sec。 371日期1985年12月5日第 102（e）1985年12月5日日期PCT提交1985年4月3日PCT公布。 公开号WO85 / 04763 日期：1985年10月24日。一种由负极（4）构成的可充电电化学装置，其包含作为活性物质的碱金属，非水电解质（6）和正极（1）。 正极（1）由以下通式表示的铬和钒的氧化物构成：CrxV2（1-x）O5-（2 + y）x（其中0.2
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4.发明授权Organic electrolyte cell with manganese dioxide cathode and a light metal anode 失效有机电解质电池与二氧化锰阴极和轻金属阳极
公开(公告)号：US4336315A
公开(公告)日：1982-06-22
申请号：US227785
申请日：1981-01-21
申请人： Nobuo Eda , Takashi Iijima , Yoshinori Toyoguchi
发明人： Nobuo Eda , Takashi Iijima , Yoshinori Toyoguchi
摘要： A cell composed of an anode with a light metal as an active material, a cathode with manganese dioxide as an active material, and an organic electrolyte. The cathode contains an alkaline earth metal oxide. The cell is superior in storage with the swelling of the cell and the increase of the cell impedance is little during the preservation.
摘要翻译： 由具有轻金属的阳极作为活性材料构成的电池，具有二氧化锰作为活性材料的阴极和有机电解质。 阴极含有碱土金属氧化物。 该细胞在储存中优于细胞肿胀，并且在保存期间细胞阻抗的增加很小。
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公开(公告)号：US4271242A
公开(公告)日：1981-06-02
申请号：US103475
申请日：1979-12-14
CPC分类号： H01M4/5835 , C01B31/005
摘要： An improved active material for the positive electrode of a battery comprising carbon fluoride obtained by fluorinating carbon having a lattice constant of 3.40-3.50 A in its (002) plane. The carbon is selected from among petroleum cokes and coal cokes. The resulting battery has excellent discharge and shelf life characteristics.
摘要翻译： 一种用于电池正极的改进的活性材料，其包括通过在其（002）面中氟化晶格常数为3.40-3.50A的碳而获得的氟化碳。 碳选自石油焦炭和煤焦炭。 所得电池具有优异的放电和保质期特性。
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公开(公告)号：US4172927A
公开(公告)日：1979-10-30
申请号：US949380
申请日：1978-10-06
申请人： Yoshinori Toyoguchi , Nobuo Eda , Takashi Iijima
发明人： Yoshinori Toyoguchi , Nobuo Eda , Takashi Iijima
摘要： This invention relates to improvement in an organic electrolyte battery employing a light metal as an anodic material; organic electrolyte; and CuO as a cathodic material.By using, as the cathodic material, the solid solution of alkali metal oxide and CuO as a mother substance, the delivered volumetric energy density of the battery is fairly increased.
摘要翻译： 本发明涉及使用轻金属作为阳极材料的有机电解质电池的改进; 有机电解液 和CuO作为阴极材料。
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7.发明授权Method for detecting fully charged condition of secondary battery and detector using the same 失效用于检测二次电池的完全充电状态的方法及使用其的检测器
公开(公告)号：US6144188A
公开(公告)日：2000-11-07
申请号：US304689
申请日：1999-05-04
CPC分类号： H02J7/0088
摘要： The present invention provides a method for detecting a fully charged condition of a secondary battery by which the fully charged condition of a secondary battery can be detected accurately and deterioration in battery characteristic due to overcharging can be restrained irrespective of the charging mode and the surroundings, without the need for a special battery structure. In the method, pulse vibrations generated inside a secondary battery being charged are detected, and when the obtained characteristic value of the pulse vibrations, for example, incidence of generation of the vibrations reaches a predetermined value, the secondary battery is determined to be in fully charged condition.
摘要翻译： 本发明提供一种用于检测二次电池的完全充电状态的方法，通过该二次电池的充满电状态可以精确地检测二次电池的充满电状态，并且可以抑制由于过充电导致的电池特性的劣化，而与充电模式和周围环境无关， 而不需要特殊的电池结构。 在该方法中，检测在正在充电的二次电池内产生的脉冲振动，并且当获得的脉冲振动的特征值例如振动的产生的发生率达到预定值时，二次电池被确定为完全 充电状态。
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8.发明授权
公开(公告)号：US6066416A
公开(公告)日：2000-05-23
申请号：US120544
申请日：1998-07-22
CPC分类号： C01G53/00 , C01G53/04 , H01M4/52 , C01P2002/50 , C01P2004/45 , C01P2006/40 , H01M2300/0014
摘要： A positive electrode active material and a positive electrode for an alkaline storage battery are disclosed which exhibit high charge efficiency at a high temperature. The positive electrode active material comprises particles formed by agglomeration of crystals of nickel hydroxide active material, at least the surface layer of the particles containing a solid solution nickel hydroxide with manganese incorporated therein. The solid solution is present as crystals growing on the crystal surface of said nickel hydroxide active material and/or crystals independent of crystals of the nickel hydroxide active material. The content of manganese in the solid solution is at least one mole percent on the whole metal ions in the solid solution and not higher than 10 mole percent on the combined total amount of the metal ions in the nickel hydroxide active material and the solid solution. The positive electrode for an alkaline storage battery contains the above-mentioned active material and a compound of at least one element selected from the group consisting of Ca, Sr, Ba, Cu, Ag, Cd, Y and Yb.
摘要翻译： 公开了一种在高温下表现出高充电效率的正极活性物质和碱性蓄电池用正极。 正极活性物质包括由氢氧化镍活性物质的晶体聚集形成的颗粒，至少含有其中掺入锰的固溶体氢氧化镍的颗粒的表面层。 固体溶液以不依赖于氢氧化镍活性物质晶体的氢氧化镍活性物质和/或晶体的晶体表面生长的晶体存在。 固溶体中的锰含量相对于固溶体中的全部金属离子为至少1摩尔％，并且不高于氢氧化镍活性物质和固溶体中的金属离子总量的10摩尔％。 碱性蓄电池用正极含有上述活性物质和选自Ca，Sr，Ba，Cu，Ag，Cd，Y和Yb中的至少一种元素的化合物。
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公开(公告)号：US5939224A
公开(公告)日：1999-08-17
申请号：US864941
申请日：1997-05-29
IPC分类号： H01M4/58
摘要： The invention provides a nonaqueous electrolyte secondary battery which employs, as a negative electrode active material, a carbide containing an alkali metal in a charged stage. The carbide used is an ionic bond type carbide, a covalent bond type carbide, or an intermetallic compound type carbide. The ionic bond type carbide is exemplified as Na.sub.2 C.sub.2, K.sub.2 C.sub.2, Cu.sub.2 C.sub.2, VC.sub.2, and the like. The covalent bond type carbide is exemplified as Cr.sub.4 C, and the like. The intermetallic compound type carbide is exemplified as Mn.sub.3 C, Mn.sub.23 C.sub.6, Mn.sub.7 C.sub.3, Fe.sub.2 C, FeC, Ni.sub.3 C, and the like. A highly reliable nonaqueous electrolyte secondary battery with a high energy density and excellent cycle life characteristics can be obtained.
摘要翻译： 本发明提供一种非水电解质二次电池，其在带电阶段中使用含有碱金属的碳化物作为负极活性物质。 所使用的碳化物是离子键型碳化物，共价键型碳化物或金属间化合物型碳化物。 离子键型碳化物示例为Na 2 C 2，K 2 C 2，Cu 2 C 2，VC 2等。 共价键式碳化物例如为Cr 4 C等。 作为Mn3C，Mn23C6，Mn7C3，Fe2C，FeC，Ni3C等，可列举出金属间化合物型碳化物。 可以获得具有高能量密度和优异的循环寿命特性的高度可靠的非水电解质二次电池。
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公开(公告)号：US5738736A
公开(公告)日：1998-04-14
申请号：US683559
申请日：1996-07-15
CPC分类号： H01M4/383 , C01B3/0031 , C01B3/0057 , Y02E60/327 , Y10S420/90
摘要： The present invention provides an improved hydrogen storage alloy of Ti--V--Ni system having a body-centered cubic structure. The alloy is of the general formula Ti.sub.x (V.sub.a Cr.sub.1-a).sub.1-x M.sub.b Ni.sub.c, wherein M represents at least one element of La and Ce or a mischmetal, and wherein 0.5.ltoreq.a.ltoreq.0.95, 0.01.ltoreq.b.ltoreq.0.1, 0.1.ltoreq.c.ltoreq.0.6, and 0.2.ltoreq.x.ltoreq.0.4; or Ti.sub.x V.sub.y M.sub.z Ni.sub.1-x-y-z, wherein M represents at least one element selected from the group consisting of Co, Fe, Cu, and Ag, and wherein 0.2.ltoreq.x.ltoreq.0.4, 0.3.ltoreq.y.ltoreq.0.7, 0.1.ltoreq.z.ltoreq.0.3, and 0.6.ltoreq.x+y+z.ltoreq.0.95.
摘要翻译： 本发明提供了具有体心立方结构的Ti-V-Ni体系的改进的储氢合金。 该合金具有通式Tix（VaCr1-a）1-xMbNic，其中M表示La和Ce中的至少一种元素或混合稀土金属，并且其中0.5≤a≤0.95,0.01≤b< /=0.1,0.1≤n≤0.6，0.2≤x≤0.4; 或TixVyMzNi1-xyz，其中M表示选自Co，Fe，Cu和Ag中的至少一种元素，其中0.2≤x≤0.4,0.3≤y≤0.7,0.1
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