摘要:
A photorefractive composition that is photorefractive upon irradiation by a near infrared (NIR) laser. The photorefractive composition comprises a sensitizer and a polymer comprising a repeating unit including at least a moiety selected from the group consisting of the formulae (Ia), (Ib) and (Ic), as defined herein. The photorefractive composition can be used in optical devices.
摘要:
A non-linear optical device composition includes a trifluorovinyl group containing poly(meth)acrylate that is crosslinkable and thermally stable after crosslinking. The poly(meth)acrylate composition may provide passive or active wave-guide optical capabilities. The composition may be used for an active wave guide material, such as modulator or switching device compositions. Furthermore, the composition may include a trifluorovinyl containing chromophore and poly(meth)acrylate which provides non-linear optical ability in the matrix polymer system.
摘要:
A composition comprising a polymer represented by the following formula (i), wherein the composition exhibits photorefractive ability: wherein R is selected from the group consisting of a linear alkyl group with up to 10 carbons, a branched alkyl group with up to 10 carbons, and an aromatic group with up to 10 carbons; n is an integer of 10 to 10,000; Z is a group which contains at least a tri-aromatic amine moiety shown in the structure (ii): wherein Ra1-Ra14 are independently selected from the group consisting of a hydrogen atom, a linear alkyl group with up to 10 carbons, a branched alkyl group with up to 10 carbons, and an aromatic group with up to 10 carbons.
摘要:
The object of the present invention is to produce a polymer, which is free from the troubles of the coloration and the decrease in the mechanical properties of molded articles (films, etc.), crosslinkage failure, migration (stain) or the like, by the living radical polymerization method wherein the content of impurities consisting of a transition metal and its ligand employed as a polymerization activator is reduced. A process for producing a polymer is described, comprising: a) the step of performing a polymerization reaction by using a monomer, a transition metal and its ligand and a polymerization initiator to form a polymer; and b) the step of eliminating the transition metal and its ligand contained in the polymer under the condition of a viscosity of 100 Pa·s or below, wherein the step b comprises: b1) the former step of eliminating the transition metal and its ligand insoluble in the polymer; and b2) the latter step of eliminating the transition metal and its ligand dissolved in the polymer.
摘要:
A pressure-sensitive adhesive composition having well-balanced pressure-sensitive adhesive force and cohesive force without causing any safety or economy problems, a process for the preparation of the same and pressure-sensitive adhesive sheets using the same are disclosed. The pressure-sensitive adhesive composition comprises a crosslinked polymer obtained by crosslinking a block copolymer comprising at least two of a styrene-based polymer block A and an acrylic polymer block B having a structural unit represented by the general formula (1):—[CH2═C(R1)COOR2]— wherein R1 represents a hydrogen atom or methyl group, and R2 represents a C2-14 alkyl group, bonded each other, such as A-B or B-A type block copolymer and A-B-A type block copolymer.
摘要:
Described herein are novel azo-benzene type chromophores. The chromophores are useful in photochromic compositions comprising a polymer matrix and a chromophore, wherein the chromophore is a novel azo-benzene type structure. The photochromic composition is photoresponsive upon irradiation by at least one wavelength of laser light across the visible light spectrum. Photochromic devices which comprise the novel azo-benzene type chromophore compound show significantly higher photoinduced birefringence, higher diffraction efficiency, and brighter images than devices that comprise well known azo-benzene chromophores. The photochromic composition may include a liquid crystal.
摘要:
Compounds derived from aromatic tetracarboxyl bisbenzoimidazoles are disclosed. These compounds are capable of forming liquid crystal systems that can produce optically isotropic or anisotropic films with desirable optical properties. Formulae (I) or (II), or a salt thereof; wherein y is an integer in the range from 0 to about 4.
摘要:
Described herein are photo-patternable sol-gel precursors and their methods of preparation. The sol-gel precursors are thermally stable and form compositions that have high refractive indices and low optical loss values. The precursors can be used to make sol-gel compositions that are ideally suited toward optical waveguide applications in the realm of telecommunications wavelengths.
摘要:
Embodiments of the present disclosure provide non-linear optical compounds and compositions comprising a silole-derivative. In an embodiment, the silole derivative comprises a chromophore including a structure represented by Formula (A): wherein each Of R1, R2, R3, and R4 are independently selected from the group consisting of a hydrogen atom, a C1-10 linear alkyl group, a C1-10 branched alkyl group, a C5-10 aryl group, a heteroaryl group, an alkene group, an alkyne group, a cycloalkene, a cycloalkyne, and a substituted or unsubstituted heteroatom and X1 and X2 are each independently selected from the group consisting of O, S, and Se. Compositions formed from embodiments of the silole derivative may be used in non-linear optical devices, particularly passive and active optical waveguides.
摘要:
An optical device comprising a photorefractive composition configured to be photorefractive upon irradiation by a blue laser. The photorefractive composition comprises a polymer comprising a repeating unit including at least a moiety selected from the group consisting of the formulas (Ia), (Ib) and (Ic), as defined herein.