Abstract:
The NMR device with a magnet utilizes a composition exhibiting a desired value of magnetic susceptibility, wherein the composition comprises a metal ion selected from the group consisting of Gd+3, Fe+3 and Mn+2 and an amorphous material using a ligand or chelating agent to solubilize the metal ion throughout the amorphous material, wherein the magnetic susceptibility of the composition exhibits a desired value at cryogenic temperatures such as nearly zero susceptibility at temperatures at or below 77 K.
Abstract:
A process of preparing magnetic graphitic materials from graphite in a second container (3) that reacts with one of more transition metal oxide and in a first container (2) at a volume ratio of 1:1, in a closed reactor (1), heated up to a temperature between 600° C. and the melting temperature of the transition oxide (s) for 6 to 36 hours, under a pressure of 10 atmospheres with the help of a transfer inert gas through an inlet (5) and vacuum between 10−2 torr to 10−7 torr through an outlet (6), obtaining at the end of the process a graphitic material with long-lasting magnetic properties at room temperature. The material obtained exhibits a complex structure, with pores, bunches, pilings and edges of exposed graphenes and finds application in nanotechnology, magnetic images in medical science, applications in communication, electronics, sensors, even biosensors, catalysis or separation of magnetic materials.
Abstract:
A thin-film magnet formed from a gas-phase reaction of tetracyanoetheylene (TCNE) OR (TCNQ), 7,7,8,8-tetracyano-P-quinodimethane, and a vanadium-containing compound such as vanadium hexcarbonyl (V(CO)6) and bis(benzene)vanalium (V(C6H6)2) and a process of forming a magnetic thin film upon at least one substrate by chemical vapor deposition (CVD) at a process temperature not exceeding approximately 90° C. and in the absence of a solvent. The magnetic thin film is particularly suitable for being disposed upon rigid or flexible substrates at temperatures in the range of 40° C. and 70° C. The present invention exhibits air-stable characteristics and qualities and is particularly suitable for providing being disposed upon a wide variety of substrates.
Abstract translation:由四氰基亚乙基(TCNE)OR(TCNQ),7,7,8,8-四氰基-P-醌二甲烷和含钒化合物如六羰基钒(V(CO))的气相反应形成的薄膜磁体 )6)和双(苯)钒(V(C 6 H 6)2)的方法,以及在不超过约90℃的工艺温度下通过化学气相沉积(CVD)在至少一个基板上形成磁性薄膜的工艺, 没有溶剂。 磁性薄膜特别适合于在40℃和70℃的温度范围内设置在刚性或柔性基底上。本发明显示出空气稳定的特性和品质,并且特别适于提供设置在 各种基材。
Abstract:
This invention relates to organic based spintronic devices, and electronic devices comprising them, including spin valves, spin tunnel junctions, spin transistors and spin light-emitting devices. New polymer-, organic- and molecular-based electronic devices in which the electron spin degree of freedom controls the electric current to enhance device performance. Polymer-, organic-, and molecular-based spintronic devices have enhanced functionality, ease of manufacture, are less costly than inorganic ones. The long spin coherence times due to the weak spin-orbit interaction of carbon and other low atomic number atoms that comprise organic materials make them ideal for exploiting the concepts of spin quantum devices. The hopping mechanism of charge transport that dominates in semiconducting polymers (vs. band transport in crystalline inorganic semiconductors) enhances spin-magneto sensitivity and reduces the expected power loss.
Abstract:
There is disclosed a chiral molecular magnet having characteristics exhibiting a monocrystal, a magnetic property, an optical activity, a transparent color and a relatively high transition temperature. This chiral molecular magnet is formed of a monocrystal represented by a general formula [Mn(L)]3[Cr(CN)6]2.4H2O (wherein L is optically active (R or S)-1,2-diamines and derivatives thereof or optically active (R or S)-1,3-diamines and derivatives thereof).
Abstract:
The invention provides a method of manufacturing polyaniline having magnetic properties and improved non-linear electrical properties, starting from neutral polyaniline, the method comprising the following steps: the neutral polyaniline is dissolved at a concentration of 0.1 to 3 parts per hundred by weight in a solution of fuming sulfuric acid including, at a concentration lying in the range 0.1 to 10 parts per hundred by weight, a magnetic metal, a magnetic metal salt, or any mixture of such metals and/or metal salts that is soluble in fuming sulfuric acid; the solution is maintained under stirring for a length of time lying in the range 10 minutes to 72 hours; the solution is poured slowly into methanol or distilled water to obtain a precipitate of magnetic self-doped polyaniline; and the precipitation cake is washed until the washing solution has neutral pH, and said precipitation cake is dried.
Abstract:
New molecules having the general formula A:N—B, where A:N— is .alpha.-substituted conjugated cyclic amine, with N being the N atom; and B is an .alpha.-substituted cyclic radical. These materials have ferromagnetic properties and may be use in a variety of fields and particularly in any electromagnetooptical or magnetoresistive system.
Abstract:
The invention is drawn to organic compounds of the general formulae L--A--Z or L--A'--L' as defined in the specification. The compounds are readily crystallizable and can be used for their ferromagnetic properties.
Abstract:
The present invention concerns a magnetic copolymer having a structural unit comprising a first multivalent radical and a second multivalent radical derived from an aminoaromatic compound selected from a substituted amine containing at least two condensed benzene nuclei, a substituted polycyclic compound containing at least one aniline unit in its structure, and an aniline derivative substituted on the ring by an ethynylidene or paraphenylene side chain, these compounds being in their reduced or oxidized forms, said first and said second radical being coupled together by a carbon-nitrogen bond and the nitrogen atoms being separated by a single aromatic ring, characterized in that said first radical is derived from a compound selected from 1-naphthylamine, which may be substituted, in its reduced or oxidized form.
Abstract:
An organic magnetic member comprises repetition units represented by the following general formula [I]: ##STR1## having at least one of R.sub.1 and R.sub.2 which is a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted heterocyclic ring, and being spontaneously magnetized.