公开(公告)号：US4391903A

公开(公告)日：1983-07-05

申请号：US346738

申请日：1982-02-08

Applicant: Peter K. Sysak

Inventor： Peter K. Sysak

IPC: G03C1/053 ,  G03C1/72

CPC classification number: G03C1/053

Abstract: Ionic copolymers of styrene sulfonic acid and maleic acid improve covering power when added to the gelatin binder employed in medical silver halide X-ray emulsions.

Abstract translation: 苯乙烯磺酸和马来酸的离子共聚物当加入医用卤化银X射线乳剂中使用的明胶粘合剂时，提高了覆盖力。

公开(公告)号：US4358533A

公开(公告)日：1982-11-09

申请号：US242490

申请日：1981-03-11

Applicant: Kouji Tokitou ,  Tsuneo Wada

Inventor： Kouji Tokitou ,  Tsuneo Wada

IPC: G03C1/06 ,  G03C1/04 ,  G03C1/053 ,  G03C7/26 ,  G03C7/388 ,  G03C1/72 ,  G03C5/26

CPC classification number: G03C7/3882 ,  G03C1/053 ,  Y10S430/158

Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.

Abstract translation: 具有亲水胶体层的卤化银照相材料，其包含负载在载体上的疏水照相附加物的聚合物微粒，其中所述聚合物具有由非离子疏水单体形成的重复单元。 非离子疏水性单体具有下式：R1和R2分别为氢原子或甲基，R3为氢原子，烷基或芳基，m和n为2〜100的整数 单独。

公开(公告)号：US4287293A

公开(公告)日：1981-09-01

申请号：US110751

申请日：1980-01-08

Applicant: Tamotsu Iwata ,  Shigeru Iguchi

Inventor： Tamotsu Iwata ,  Shigeru Iguchi

IPC: G03C1/04 ,  B32B27/30 ,  G03C1/053 ,  G03C8/00 ,  G03C5/54 ,  G03C1/72

CPC classification number: G03C1/053 ,  G03C8/00 ,  Y10S430/162 ,  Y10T428/31855

Abstract: A photographic element having a photographic layer such as silver halide emulsion layer, protective layer, intermediate layer, subcoat layer, diffusion transfer image-receiving layer, antihalation layer and backing layer, can be improved in the adhesion between the layer and support, little curling on drying, and flexibility of the layer, by incorporating into the photographic layer a conversion mixture of a polyvinyl alcohol having a saponification degree of 96% or more and an ethylene-maleic anhydride copolymer.

Abstract translation: 具有照相层的照相元件，例如卤化银乳剂层，保护层，中间层，底涂层，扩散转移图像接收层，防晕层和背衬层可以改善层与载体之间的粘附性，少量卷曲 通过将照相层中的皂化度为96％以上的聚乙烯醇和乙烯 - 马来酸酐共聚物的转化混合物结合到层的干燥和柔软性上。

公开(公告)号：US4284718A

公开(公告)日：1981-08-18

申请号：US175898

申请日：1980-08-06

Applicant: Peter Bergthaller ,  Wilhelm Saleck ,  Gunter Helling

Inventor： Peter Bergthaller ,  Wilhelm Saleck ,  Gunter Helling

IPC: C08F2/38 ,  C08F220/12 ,  C08F220/52 ,  G03C1/053 ,  G03C1/72

CPC classification number: G03C1/053 ,  C08F220/12 ,  C08F220/52

Abstract: Polymers, containing polymerized units of at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## are useful for the preparation of silver halide emulsions.

Abstract translation: 包含至少一种下式化合物（A）和至少一种式（B）化合物的聚合单元的聚合物可用于制备卤化银乳剂。

公开(公告)号：US4247673A

公开(公告)日：1981-01-27

申请号：US85138

申请日：1979-10-15

Applicant: Ignazio S. Ponticello ,  Kenneth R. Hollister ,  Richard C. Tuites

Inventor： Ignazio S. Ponticello ,  Kenneth R. Hollister ,  Richard C. Tuites

IPC: C08F20/36 ,  C08F20/60 ,  G03C1/053 ,  G03C7/327 ,  G03F7/033 ,  G03G5/05 ,  C08F26/08

CPC classification number: C08F20/60 ,  C08F20/36 ,  G03C1/053 ,  G03C7/3275 ,  G03F7/033 ,  G03G5/0546 ,  G03G5/0592

Abstract: Compounds useful in making crosslinkable polymers having the formula (I): ##STR1## wherein R is hydrogen or methyl; R.sup.1 is cyano or ##STR2## wherein R.sup.2 is alkyl; Z is --X--R.sup.3 --X-- or ##STR3## wherein each --X-- is --O-- or --NR.sup.4 --, provided at least one --X-- is --NR.sup.4 -- wherein R.sup.4 is hydrogen or alkyl, R.sup.3 is divalent hydrocarbon and D.sub.1 and D.sub.2 together are the carbon atoms necessary to complete a 5 to 7 membered ring. These compounds can be homopolymerized or copolymerized with each other or with other polymerizable ethylenically unsaturated monomers to give crosslinkable polymers. Such polymers can be purified by conventional purification techniques such as dialysis, diafiltration, ultrafiltration without losing their capability of crosslinking. The resulting purified polymers are particularly useful in photographic materials as gelatin extenders, binders or polymeric color couplers.

Abstract translation: 可用于制备具有式（I）的交联聚合物的化合物：其中R是氢或甲基; R 1是氰基或者其中R 2是烷基; Z是-X-R3-X-或，其中每个-X-是-O-或-NR4-，提供至少一个-X-是-NR4-，其中R4是氢或烷基，R3是二价烃和 D1和D2一起是完成5至7元环所必需的碳原子。 这些化合物可以彼此均聚或共聚，或与其它可聚合的烯属不饱和单体共聚以产生可交联的聚合物。 这样的聚合物可以通过常规的纯化技术如透析，渗滤，超滤而不失去其交联能力而被纯化。 所得到的纯化聚合物特别可用于照相材料，如明胶增量剂，粘合剂或聚合物色素。

公开(公告)号：US4198478A

公开(公告)日：1980-04-15

申请号：US904664

申请日：1978-05-10

Applicant: Masakazu Yoneyama ,  Jiro Yamaguchi ,  Takeshi Mikami

Inventor： Masakazu Yoneyama ,  Jiro Yamaguchi ,  Takeshi Mikami

IPC: G03C1/06 ,  G03C1/005 ,  G03C1/04 ,  G03C1/053 ,  G03C1/38 ,  G03C7/388 ,  G03C1/40 ,  G03C1/10 ,  G03C1/48 ,  G03C1/84

CPC classification number: G03C1/38 ,  G03C1/005 ,  G03C1/053 ,  G03C7/3882 ,  Y10S516/03 ,  Y10S516/05

Abstract: A method for dispersing an oil-soluble photographic additive which comprises dissolving the additive in an organic solvent and dispersing the resulting solution of the photographic additive in water or a hydrophilic colloid composition in the presence of a surface active polymer comprising (a) a homopolymer of units represented by the formula (I): ##STR1## wherein R is an aliphatic hydrocarbon group having 4 to 22 carbon atoms; m.sub.1 and m.sub.2 each is 0 or 1; B is --O-- or --NH--; A is a divalent aliphatic group having 1 to 50 carbon atoms; and M is a hydrogen atom or a cation group capable of forming a salt with a sulfonic acid group, or (b) a copolymer containing at least 5 mol% of units represented by the formula (I) above and the balance of divalent units copolymerizable therewith and comprising at least one of a benzene ring having a methylene group attached thereto and a naphthalene ring having a methylene group attached thereto.

Abstract translation: 一种用于分散油溶性照相添加剂的方法，其包括将添加剂溶解在有机溶剂中，并将所得的照相添加剂溶液在表面活性聚合物存在下分散在水或亲水胶体组合物中，所述表面活性聚合物包含（a） 由式（I）表示的单元：其中R是具有4至22个碳原子的脂族烃基; m1和m2分别为0或1; B是-O-或-NH-; A是碳原子数为1〜50的二价脂肪族基团; M是氢原子或能够与磺酸基形成盐的阳离子基团，或者（b）含有上述式（I）表示的至少5摩尔％的单元的共聚物，其余的可共聚二价单元 并且包括其上连接有亚甲基的苯环和与其连接的具有亚甲基的萘环中的至少一个。

公开(公告)号：US4197127A

公开(公告)日：1980-04-08

申请号：US936996

申请日：1978-08-25

Applicant: Thomas G. Mecca

Inventor： Thomas G. Mecca

IPC: C08F220/12 ,  G03C1/053 ,  G03C1/835 ,  G03C8/52 ,  G03C1/72 ,  G03C1/76

CPC classification number: G03C1/835 ,  C08F220/12 ,  G03C1/053 ,  G03C8/52

Abstract: Disclosed herein are compositions useful for the preparation of flexible coatings, particularly to photographic materials, which have improved stability to organic solvents and dissolved salts. The compositions comprise an aqueous dispersion of a hydrophilic colloid and a copolymer having a glass transition temperature less than or equal to 60.degree. C. comprising: from about 50 to about 70 percent by weight of an ester of an ethylenically unsaturated carboxylic acid; from about 2 to about 18 percent by weight of an amide of an ethylenically unsaturated carboxylic acid; from about 10 to about 30 percent by weight of a vinyl benzene; and from about 2 to about 18 percent by weight of a sulfonate monomer having the formula ##STR1## wherein R is hydrogen or alkyl; R.sup.1 is selected from the group consisting of alkylene and ##STR2## R.sup.2 is amino substituted with alkyl or hydrogen, or --CH.sub.2).sub.n O-- wherein n is an integer from 0 to 5; m is either 0 or 1; and X is hydrogen or a monovalent cation.

Abstract translation: 本文公开了可用于制备柔性涂层，特别是对具有改善的有机溶剂和溶解盐的稳定性的照相材料的组合物。 所述组合物包含亲水胶体的水性分散体和玻璃化转变温度低于或等于60℃的共聚物，其包含：约50重量％至约70重量％的烯键式不饱和羧酸酯; 约2至约18重量％的烯属不饱和羧酸的酰胺; 约10至约30重量％的乙烯基苯; 和约2至约18重量％的具有式“IMAGE”的磺酸酯单体，其中R是氢或烷基; R1选自亚烷基，R2为被烷基或氢取代的氨基，或-CH2）nO-，其中n为0至5的整数; m为0或1; X是氢或一价阳离子。

公开(公告)号：US4133687A

公开(公告)日：1979-01-09

申请号：US814015

申请日：1977-07-08

Applicant: Tsang J. Chen ,  Donald F. McLaen

Inventor： Tsang J. Chen ,  Donald F. McLaen

IPC: G03C1/053 ,  G03C1/42 ,  G03C5/30 ,  G03C1/48 ,  G03C1/02 ,  G03C1/06 ,  G03C1/72

CPC classification number: G03C1/42 ,  G03C1/053 ,  G03C5/30 ,  Y10S430/156 ,  Y10S430/16

Abstract: A photographic element is disclosed having coated on a support a hydrophilic colloid layer containing an activator precursor and loaded polymer particles of from 0.02 to 0.2 micron in average diameter. The polymer particles consist essentially of a hydrophobic polymer of which at least 2 percent by weight is comprised of ionizable repeating units, at least half being cationically ionizable, and a hydrophobic developing agent present in a weight ratio to the polymer of from about 1:4 to 3:1. Silver halide is present in the hydrophilic colloid layer or in an adjacent layer, and the activator precursor is present in a concentration of from 1 to 4 equivalent for each mole of silver halide. The photographic element is capable of being thermally processed.

Abstract translation: 公开了一种照相元件，其在载体上涂覆含有活化剂前体和平均直径为0.02至0.2微米的负载聚合物颗粒的亲水胶体层。 聚合物颗粒基本上由疏水性聚合物组成，其中至少2重量％由可离子化的重复单元组成，至少一半是阳离子可离子化的，疏水性显影剂以与聚合物重量比为约1:4 至3：1。 卤化银存在于亲水胶体层或相邻层中，并且活化剂前体以每摩尔卤化银的1至4当量的浓度存在。 照相元件能够被热处理。

公开(公告)号：US4119463A

公开(公告)日：1978-10-10

申请号：US678715

申请日：1976-04-20

Applicant: Shigeru Iguchi ,  Tamotu Iwata ,  Tetsuo Yano

Inventor： Shigeru Iguchi ,  Tamotu Iwata ,  Tetsuo Yano

IPC: G03C1/04 ,  G03C1/053 ,  G03C1/76 ,  G03C3/00

CPC classification number: G03C1/053

Abstract: A photographic binder prepared by heating a mixed aqueous solution of styrene-maleic anhydride copolymer, isobutylene-maleic anhydride copolymer and polyvinyl alcohol in acidic state makes it possible to coat a photographic coating liquid for forming photographic layers in the same manner as in the case of using gelatin and furthermore gives excellent physical properties to the resultant photographic layers.

Abstract translation: 通过在酸性状态下加热苯乙烯 - 马来酸酐共聚物，异丁烯 - 马来酸酐共聚物和聚乙烯醇的混合水溶液制备的照相粘合剂使得可以以与以下相同的方式涂覆用于形成照相层的照相涂布液： 使用明胶，并且还对所得照相层提供优异的物理性能。

公开(公告)号：US4033772A

公开(公告)日：1977-07-05

申请号：US639075

申请日：1975-12-09

Applicant: Joseph A. Sprung ,  Theodore Panasik ,  James J. Holmes

Inventor： Joseph A. Sprung ,  Theodore Panasik ,  James J. Holmes

IPC: G03C1/04 ,  C08F8/00 ,  C08F8/32 ,  C08F8/34 ,  G03C1/053 ,  G03C1/72 ,  G03C1/02

CPC classification number: G03C1/053

Abstract: A photographic silver halide emulsion wherein the emulsion binder comprises the reaction product of 1) a reactant having an amino, mercapto or hydroxy functionality and a cationic active group with 2) a copolymer of maleic anhydride and an ethylenically unsaturated copolymerizable monomer.

Abstract translation: 一种照相卤化银乳剂，其中乳液粘合剂包括1）具有氨基，巯基或羟基官能团的反应物和阳离子活性基团的反应产物，以及2）马来酸酐和烯属不饱和可共聚单体的共聚物。