公开(公告)号：US4101387A

公开(公告)日：1978-07-18

申请号：US603563

申请日：1975-08-11

申请人： Hans-Gerhard Creutz ,  Roy Wilbur Herr ,  Richard Marshall Stevenson

发明人： Hans-Gerhard Creutz ,  Roy Wilbur Herr ,  Richard Marshall Stevenson

IPC分类号： C25D3/02 ,  C25D3/14 ,  C25D3/18 ,  C25D3/22 ,  C25D3/56 ,  C25D3/12 ,  C25D3/20

CPC分类号： C25D3/22 ,  C25D3/02 ,  C25D3/14 ,  C25D3/562

摘要： The instant invention is directed to an aqueous bath for the electrodeposition of bright metal deposits, and more particularly to a bath composition which provides upon the basis metal an electrodeposit having improved brightness, particularly in low current density areas, and as well, a condition of ductility markedly better than that which characterizes certain prior art baths. The electroplating bath composition of this invention embodies a polyethylenimine having the general empirical formula --[C.sub.2 H.sub.5 N].sub.x --, and a sulfonating agent for the polyethylenimine, whereby there is obtained a reaction product which contains nitrogen substituted sulfamate groups as an integral part of the polymer chain. The nitrogen substituted sulfamate unit of the reaction product is represented by the formula: ##STR1## where, M = H, Li, Na, K, or, NH.sub.4. The ratio of these nitrogen substituted sulfamate units to amino units, --[CH.sub.2 CH.sub.2 NH]--, in the reaction product is determined by the molar ratio of the polymer repeat unit, --[C.sub.2 H.sub.5 N]--, to sulfonating agent in the reaction.

摘要翻译： 本发明涉及一种用于电沉积光亮金属沉积物的水浴，更具体地涉及一种浴组合物，其在基础金属上提供具有改善的亮度的电沉积物，特别是在低电流密度区域，以及条件 延展性明显优于某些现有技术浴的特征。 本发明的电镀浴组合物体现了具有一般经验式 - [C 2 H 5 N] x - 的聚乙烯亚胺和用于聚乙烯亚胺的磺化剂，由此得到含有氮取代的氨基磺酸酯基作为聚合物的组成部分的反应产物 链。 反应产物的氮取代的氨基磺酸酯单元由下式表示：其中，M = H，Li，Na，K或NH 4。 反应产物中这些氮取代的氨基磺酸酯单元与氨基单元 - [CH 2 CH 2 NH] - 的比例由聚合物重复单元 - [C 2 H 5 N] - 与反应中的磺化剂的摩尔比确定。

公开(公告)号：US4092347A

公开(公告)日：1978-05-30

申请号：US725846

申请日：1976-09-23

申请人： Walter Schenk ,  Helmut Schlecht ,  Guenther Gotsmann

发明人： Walter Schenk ,  Helmut Schlecht ,  Guenther Gotsmann

IPC分类号： C25D3/12 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/32 ,  C07C309/20 ,  C25D3/02 ,  C25D3/14 ,  C07C143/16 ,  C07F3/06 ,  C07F3/10

CPC分类号： C25D3/14 ,  C07C309/00

摘要： The new 1-monochloro- and 1,1-dichloro-prop-2,3-ene-3-sulfonic acids and their metal salts, and a process for their manufacture by reacting chloropropanesulfonic acid compounds with alkali metal carbonates, alkali metal bicarbonates and/or alkaline earth metal hydroxides at from 5.degree. to 100.degree. C to give 1-chloro-prop-2,3-ene-3-sulfonates which may then be reacted with acid compounds in a second step.The products are starting materials for the manufacture of pesticides, plasticizers, solvents, leather greases, detergents, lubricating oils, synthetic resins and slip agents. They are also assistants in electroplating processes and starting materials for the manufacture of such assistants.

摘要翻译： 新的1-单氯和1,1-二氯 - 丙-2,3-烯-3-磺酸及其金属盐，以及它们通过氯丙磺酸化合物与碱金属碳酸盐，碱金属碳酸氢盐和 /或碱土金属氢氧化物在5至100℃下反应，得到1-氯 - 丙-2-基-3-烯-3-磺酸盐，然后在第二步中与酸化合物反应。

公开(公告)号：US4069112A

公开(公告)日：1978-01-17

申请号：US729074

申请日：1976-10-04

申请人： Edward P. Harbulak

发明人： Edward P. Harbulak

IPC分类号： C25D3/14 ,  C25D3/56 ,  C25D3/12

CPC分类号： C25D3/562 ,  C25D3/14

摘要： This invention relates to a process and composition for the preparation of an electro-deposit which contains; at least one metal selected from the group consisting of nickel and cobalt or; binary or ternary alloys of the metals selected from nickel, iron, and cobalt; which comprises passing current from an anode to a cathode through an aqueous acidic electroplating solution containing at least one member selected from nickel compounds and cobalt compounds and which may additionally contain iron compounds providing nickel, cobalt and iron ions for electrodepositing nickel, cobalt, nickel-cobalt alloys, nickel-iron alloys, cobalt-iron alloys or nickel-iron-cobalt alloys; the improvement comprising the presence of 5 .times. 10.sup.-6 moles per liter to 0.5 mole per liter of an unsaturated cyclosulfone exhibiting the following generalized structural formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, lower alkyl, or hydroxyl;For a time period sufficient to form a metal electroplate upon said cathode.

摘要翻译： 本发明涉及一种用于制备电沉积物的方法和组合物，其包含： 至少一种选自镍和钴的金属;或 选自镍，铁和钴的金属的二元或三元合金; 其包括将电流从阳极通过含有选自镍化合物和钴化合物中的至少一种的酸性电镀溶液，并且还可以含有提供镍，钴和铁离子的铁化合物，用于电沉积镍，钴，镍 - 钴合金，镍 - 铁合金，钴 - 铁合金或镍 - 铁 - 钴合金; 该改进包括存在5×10 -6摩尔/升至0.5摩尔/升不饱和环砜，其表现出以下通用结构式：其中R 1，R 2，R 3和R 4独立地为氢，低级烷基或羟基 ; 对于形成一个金属电极的时间段，可以使用这样的阴极。

公开(公告)号：US3844906A

公开(公告)日：1974-10-29

申请号：US36259273

申请日：1973-05-21

申请人： XEROX CORP

发明人： BAILEY R ,  KRECKEL D

IPC分类号： C25D3/14 ,  C25D21/00 ,  C23B7/02 ,  B01K3/00

CPC分类号： C25D1/10 ,  C25D3/14 ,  C25D5/08 ,  C25D21/02 ,  Y10S204/13

摘要： A process for maintaining a continuous and stable aqueous nickel sulfamate electroforming solution adapted to form a relatively thin, ductile, seamless nickel belt by electrolytically depositing nickel from said solution onto a support mandrel and thereafter recovering said nickel belt by cooling said nickel coated mandrel effecting a parting of the nickel belt from the mandrel due to different respective coefficients of thermal expansion comprising: establishing an electroforming zone comprising a nickel anode and a cathode comprising said support mandrel, said anode and cathode being separated by said nickel sulfamate solution maintained at a temperature of about 140* to 160* F and having a current density therein ranging from about 200 to about 500 amps/ft2; imparting sufficient agitation to said solution to continuously expose said cathode to fresh solution; maintaining said solution within said zone at a stable equilibrium composition: Total Nickel 12.0 to 15.0 oz/gal Halide as NiX2.6H2O 0.11 to 0.23 moles/gal H3BO3 4.5 to 6.0 oz/gal ELECTROLYTICALLY REMOVING METALLIC AND ORGANIC IMPURITIES FROM SAID SOLUTION UPON EGRESS THEREOF FROM SAID ELECTROFORMING ZONE: CONTINUOUSLY CHARGING TO SAID SOLUTION ABOUT 1.0 TO 2.0 X 10 4 MOLES OF A STRESS REDUCING AGENT PER MOLE OF NICKEL ELECTROLYTICALLY DEPOSITED FROM SAID SOLUTION; PASSING SAID SOLUTION THROUGH A FILTERING ZONE TO REMOVE ANY SOLID IMPURITIES THEREFROM; COOLING SAID SOLUTION SUFFICIENTLY TO MAINTAIN THE TEMPERATURE WITHIN THE ELECTROFORMING ZONE UPON RECYCLE THERETO AT ABOUT 140* TO 160* F. at the current density in said electroforming zone; and recycling said solution to said electroforming zone.

摘要翻译： 一种维持连续和稳定的氨基磺酸氨基水合电解液的方法，其适于通过从所述溶液中将镍电解沉积到支撑心轴上而形成相对薄的延性无缝的镍带，然后通过冷却所述镍镀层心轴来回收所述镍带， 由于不同的相应的热膨胀系数，从芯轴分离镍带的步骤包括：建立包括镍阳极和包括所述支撑心轴的阴极的电铸区，所述阳极和阴极由所述氨基磺酸镍溶液分离，所述氨基磺酸镍溶液保持在 约140°F至160°F，其电流密度范围为约200至约500安培/平方英尺; 使所述溶液充分搅拌以将所述阴极连续暴露于新鲜溶液; 在所述区域内将所述溶液保持在稳定的平衡组成：

公开(公告)号：US3804727A

公开(公告)日：1974-04-16

申请号：US20385071

申请日：1971-12-01

申请人： ALBRIGHT & WILSON

发明人： LYDE D

IPC分类号： C25D3/14 ,  C25D3/16 ,  C23B5/08 ,  C23B5/46

CPC分类号： C25D3/14 ,  C25D3/16

摘要： A WATTS BRIGHT NICKEL ELECTROPLATING BATH CONSISTING OF FROM 0.1 TO 1 G./L. OF A MIXTURE OF ACETYLENIC COMPOUNDS INCLUDING BOTH AN A-HYDROXY-ACETYLENIC COMPOUND AND AN ALKYLENE OXIDE CONDENSATION PRODUCT OF AN A-HYDROXY-ACETYLENIC COMPOUND IN A WEIGHT RATIO OF THE SAID CONDENSATION PRODUCT TO THE A-HYDROXY-ACETYLENIC COMPOUNDS OF FROM 1.5:1 TO 7:1, AND 0.2 OR 0.5 G./L. OR SACCHARIN.

公开(公告)号：US3711384A

公开(公告)日：1973-01-16

申请号：US3711384D

申请日：1971-01-20

申请人： LYDE D

发明人： LYDE D

IPC分类号： C25D3/14 ,  C23B5/08 ,  C23B5/46

CPC分类号： C25D3/14

摘要： AN AQUEOUS NICKEL PLATING ELECTROLYTE COMPRISES (A) AT LEAST 30 GM. PER LITER OF A NICKEL-II SALT; (B) 0.1-1.0 GM. PER LITER OF A MIXTURE OF ACETYLENIC COMPOUNDS INCLUDING BOTH AN ALFA-HYDROXY-ACETYLENIC COMPOUND AND AN ALKYLENE OXIDE CONDENSATION PRODUCT OF AN ALFA-HYDROXY-ACETYLENIC COMPOUND IN A WEIGHT RATIO OF THE SAID CONDENSATION PRODUCTS TO THE ALFA-HYDROXY-ACETYLENIC COMPOUNDS OF FROM 1.5:1 TO 7:1; AND (C) FROM 1.0 TO 5.0 GM. PER LITRE OF SACCHARIN OR A SUBSTITUTED SACCHARIN.

公开(公告)号：US3677913A

公开(公告)日：1972-07-18

申请号：US3677913D

申请日：1971-04-01

申请人： M & T CHEMICALS INC

发明人： PASSAL FRANK

IPC分类号： C25D3/14 ,  C23B5/08 ,  C23B5/46

CPC分类号： C25D3/14

摘要： THE NOVEL PROCESS OF THIS INVENTION FOR ELECTROPLATING A SEMI-BRIGHT SUFLUR-FREE, NICKEL PLATE ONTO A BASIS METAL COMPRISING PASSING FROM AN ANODE TO A BASIS METAL CATHODE THROUGH AN AQUEOUS ACIDIC NICKEL PLATING SOLUTION CONTAINING AT LEAST ONE NICKEL COMPOUND PROVIDING NICKEL IONS FOR ELECTROPLATING OF NICKEL, AND INCLUDING AS COOPERATING SEMI-BRIGHT ADDITIVES: (A) THE ALIPHATIC ACETYLENIC COMPOUND 3-HEXYNE-2,5-DIOL, AND (B) A COMPOUND CONTAINING AN OXYAMEGASULFOHYDROCARBON-DI-YL COUMARIN ANION WHEREIN THE HYDROCARBON-DI-YL MOIETY CONTAINS AT LEAST TWO CARBON ATOMS AND WHEREIN THE OXYOMEGASULFOHYDROCARBON-DI-YL GROUP IS SUBSTITUTED ON THE CARBOCYLIC NUCLEUS OF THE COUMARIN GROUP.

公开(公告)号：US3421986A

公开(公告)日：1969-01-14

申请号：US3421986D

申请日：1965-07-23

申请人： TEVES KG ALFRED

发明人： RUFF WOLFRAM ,  BOUCHER HEINZ

IPC分类号： C25D3/14 ,  C25D5/14 ,  C23B5/50

CPC分类号： C25D3/14 ,  C25D5/14