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公开(公告)号:US20180179371A1
公开(公告)日:2018-06-28
申请号:US15736248
申请日:2016-06-22
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CLAUDIO CAVALIERI , MICHELE GRAZZI , ROBERTO PANTALEONI
IPC: C08L23/16
CPC classification number: C08L23/16 , C08F210/16 , C08L23/12 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L2308/00 , C08L2310/00 , C08L2314/02 , C08L23/06 , C08F110/06 , C08F4/6492 , C08F2/001 , C08F210/06 , C08F2500/08 , C08F2500/12 , C08F2500/17
Abstract: Polyolefin composition made from or containing:(A) about 5 to about 35% by weight of a propylene-based polymer containing about 90% by weight or more of propylene units and containing about 10% by weight or less of a fraction soluble in xylene at 25° C. (XSA); (B) about 25 to about 50% by weight, of an ethylene homopolymer containing about 5% by weight or less of a fraction soluble in xylene at 25° C. (XSB) referred to the weight of (B); and (C) about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 25% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XSC). Following progressive fractionation having first, second, and third dissolution temperatures, the composition has about 20% by weight or less collected at second dissolution temperature.
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公开(公告)号:US20170066855A1
公开(公告)日:2017-03-09
申请号:US15309138
申请日:2015-04-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , FABRIZIO PIEMONTESI , GIANNI VITALE , CAROLINE CATHELIN , GIAMPIERO MORINI , MARCO CIARAFONI , CLAUDIO CAVALIERI , TIZIANA CAPUTO
IPC: C08F210/06 , C08J5/18
CPC classification number: C08F210/06 , C08F210/02 , C08F2800/20 , C08J5/18 , C08J2323/14 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F10/00 , C08F4/6492 , C08F4/6574
Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS
Abstract translation: 一种丙烯乙烯共聚物,其特征在于以下特征:乙烯含量在1.8至10.0重量%之间; 分子量分布(MWD),以Mw / Mn表示,大于4.0; 二甲苯可溶成分(XS)和乙烯含量(C2)的含量满足下列关系:XS <(C2x2.1)-2.4其中:XS =在25℃下可溶于二甲苯的馏分的重量% C2 =通过NMR确定的共聚物中乙烯单元的重量%。
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53.
公开(公告)号:US20160257809A1
公开(公告)日:2016-09-08
申请号:US15029470
申请日:2014-10-01
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GISELLA BIONDINI , MICHELE GRAZZI , LUCA LUNGHI , CLAUDIO CAVALIERI
CPC classification number: C08L23/16 , C08K3/016 , C08K3/20 , C08L23/142 , C08L23/20 , C08L2201/02 , C08L2205/025 , C08L2205/03 , C08L2207/02 , E04B1/942 , E04D5/06 , H01B3/441
Abstract: The present disclosure relates to highly filled polyolefin compositions with improved balance of properties particularly for applications where puncture and tear resistance is requested comprising a flexible heterophasic polyolefin composition (I), consisting of a crystalline polymer fraction (A) consisting of a copolymer of propylene with ethylene having a fraction insoluble in xylene at 25° C. of at least 90% by weight, and an elastomeric fraction (B) consisting of a copolymer or blend of copolymers of ethylene with propylene; the copolymer or blend containing units derived from ethylene in a quantity lower than 40% by weight. The fraction soluble in xylene at 25° C. of the polyolefin composition having an IVgpc lower than 2.5 dl/g, a broad molecular weight distribution Mw/Mn (GPC) equal to or higher than 4, and a Mz/Mw (GPC) equal to or higher than 2.5. The filled polyolefin composition further comprises inorganic filler (II) and a butene-1 copolymer having: a flexural modulus (ISO 178) lower than 60 MPa, a Shore A (ISO 868) lower than 90 and a Tg (DMTA) lower than −20° C.
Abstract translation: 本发明涉及高度填充的聚烯烃组合物,其具有改善的性能平衡,特别是对于要求穿刺和抗撕裂性的应用,包括柔性多相聚烯烃组合物(I),其由由丙烯与丙烯共聚物组成的结晶聚合物部分(A) 乙烯在25℃下不溶于二甲苯的份数为至少90重量%,和由乙烯与丙烯的共聚物或共聚物的共聚物或共混物组成的弹性体组分(B) 含有低于40重量%乙烯衍生的单元的共聚物或共混物。 具有IVgpc低于2.5dl / g,宽分子量分布Mw / Mn(GPC)等于或高于4的聚烯烃组合物在25℃下可溶于二甲苯的部分和Mz / Mw(GPC) 等于或高于2.5。 填充的聚烯烃组合物还包含无机填料(II)和丁烯-1共聚物,其弯曲模量(ISO 178)低于60MPa,肖氏A(ISO 868)低于90,Tg(DMTA)低于 - 20°C
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